Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Exploration of Highly Porous Biochar Derived from Dead Leaves to Immobilize LiOH center dot H2O Nanoparticles for Efficient Thermochemical Heat Storage Applications | |
Zhang, Jichuan1; Zhang, Yuyuan1,2; Huang, Hongyu3; Huang, Kanzai1; Deng, Lisheng3; Hu, Huawen1,2; Chang, Menglei1,2; Chen, Dongchu1,2; Wang, Yazhuo4 | |
2022-03-25 | |
发表期刊 | ENERGY TECHNOLOGY |
ISSN | 2194-4288 |
页码 | 9 |
通讯作者 | Zhang, Yuyuan(zhangyuyuan@fosu.edu.cn) ; Hu, Huawen(huawenhu@fosu.edu.cn) |
摘要 | The inadequate utilization of low-grade energy from industrial waste heat and solar energy calls for an efficient thermochemical heat storage material. The fabrication of a low-cost but highly efficient composite comprising highly porous biochar and LiOH center dot H2O nanoparticles for heat storage applications is reported. The biochar is prepared by the KOH-assisted pyrolysis of dead banyan leaves, and its microstructure and surface properties can be finely tuned by varying the KOH-to-biomass ratio. Such biochar can be mediated to possess a large specific surface area and total pore volume reaching as high as 1255.03 m(2) g(-1) and 3.65 cm(3) g(-1), respectively, superior to most previously reported biochar/biocarbon derived from different kinds of waste biomass. Besides, adequate functional groups and a hierarchical porous structure consisting of micropores and mesopores are demonstrated in the prepared biochar. The subsequent hydrothermal reaction with a short duration yields a biochar-LiOH center dot H2O composite, where LiOH center dot H2O can be homogeneously immobilized with a nanoscale size within the porous biochar matrix. Thus, an enormous biochar/LiOH center dot H2O nanoparticles interface can be obtained, resulting in fast hydration reactions with water molecules. Consequently, a significant heat storage density of as high as 3089.6 kJ kg(-1) is achieved within only 10 min, outstripping some recently reported thermochemical heat storage systems. |
关键词 | hierarchical pores highly porous biochar LiOH H2O nanoparticles thermochemical heat storage waste biomass conversion |
DOI | 10.1002/ente.202101127 |
关键词[WOS] | THERMAL-ENERGY STORAGE ; CARBON NANOADDITIVES ; COMPOSITE-MATERIALS ; PERFORMANCE ; ENHANCEMENT ; SORPTION ; BIOMASS ; LATENT |
收录类别 | SCI |
语种 | 英语 |
资助项目 | Key-Area Research and Development Program of Guangdong Province[2019B1102109003] ; National Natural Science Foundation of China[51906045] ; National Natural Science Foundation of China[52176091] ; Guangdong Provincial Education Department Special Project of Key Research Areas[2020ZDZX2066] ; Key Project of Guangdong Basic and Applied Basic Research Foundation[2020B1515120081] ; Guangdong Key Laboratory for Hydrogen Energy Technologies[2018B030322005] |
WOS研究方向 | Energy & Fuels |
项目资助者 | Key-Area Research and Development Program of Guangdong Province ; National Natural Science Foundation of China ; Guangdong Provincial Education Department Special Project of Key Research Areas ; Key Project of Guangdong Basic and Applied Basic Research Foundation ; Guangdong Key Laboratory for Hydrogen Energy Technologies |
WOS类目 | Energy & Fuels |
WOS记录号 | WOS:000772783400001 |
出版者 | WILEY-V C H VERLAG GMBH |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/36003 |
专题 | 中国科学院广州能源研究所 |
通讯作者 | Zhang, Yuyuan; Hu, Huawen |
作者单位 | 1.Foshan Univ, Sch Mat Sci & Hydrogen Energy, Foshan 528000, Guangdong, Peoples R China 2.Guangdong Key Lab Hydrogen Energy Technol, Foshan 528000, Guangdong, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 4.Qingyuan Kebo Environm Protect Technol Co Ltd, High Tech Ind Dev Zone, 18 Chuangxing Ave, Qingyuan 511500, Guangdong, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Jichuan,Zhang, Yuyuan,Huang, Hongyu,et al. Exploration of Highly Porous Biochar Derived from Dead Leaves to Immobilize LiOH center dot H2O Nanoparticles for Efficient Thermochemical Heat Storage Applications[J]. ENERGY TECHNOLOGY,2022:9. |
APA | Zhang, Jichuan.,Zhang, Yuyuan.,Huang, Hongyu.,Huang, Kanzai.,Deng, Lisheng.,...&Wang, Yazhuo.(2022).Exploration of Highly Porous Biochar Derived from Dead Leaves to Immobilize LiOH center dot H2O Nanoparticles for Efficient Thermochemical Heat Storage Applications.ENERGY TECHNOLOGY,9. |
MLA | Zhang, Jichuan,et al."Exploration of Highly Porous Biochar Derived from Dead Leaves to Immobilize LiOH center dot H2O Nanoparticles for Efficient Thermochemical Heat Storage Applications".ENERGY TECHNOLOGY (2022):9. |
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