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Structural evolution during corn stalk acidic and alkaline hydrogen peroxide pretreatment
Xia, Ying1,2,3; Liu, Qiying2; Hu, Xiaohong1,2; Li, Xu1,2,3; Huang, Yongwang1,2; Li, Wenzhi3; Ma, Longlong2
2022-02-01
Source PublicationINDUSTRIAL CROPS AND PRODUCTS
ISSN0926-6690
Volume176Pages:11
Corresponding AuthorLiu, Qiying(liuqy@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn)
AbstractOxidative pretreatment is a promising strategy for biomass utilization due to its excellent performance and economic costs. Insights into lignocellulose recalcitrance are essential to further develop biomass manufacture. To understand structural recalcitrance, we performed systematic characterizations after mild hydrogen peroxide pretreatment in alkali or Lewis acid environments, followed by enzymatic hydrolysis to obtain higher glucose yields than raw materials. Results indicated that hydrogen peroxide pretreatment in saturated calcium hydroxide solution effectively removed lignin through cleavage of the lignin-carbohydrate complex and part C-C linkages in the middle lamella. The ferrous sulfate solution induced hemicellulose solubility, and the partially oxidized lignin was depolymerized under hydrogen peroxide pretreatment. The solvent could then be used for subsequent hydrolysis and cellulose conversion. It was demonstrated that hydrogen peroxide pretreatment is an effective and promising method for refining lignocellulose under an alkaline environment and is suitable for subsequent cellulose conversion in ferrous sulfate solution.
KeywordLignocellulose Hydrogen peroxide pretreatment Depolymerization Lignin refinery Structural evolution
DOI10.1016/j.indcrop.2021.114386
WOS KeywordDILUTE HYDROCHLORIC-ACID ; ENZYMATIC-HYDROLYSIS ; LIGNIN ; DELIGNIFICATION ; DECONSTRUCTION ; WOOD
Indexed BySCI
Language英语
Funding ProjectNational Key Research and Development Program of China[2018YFB1501402] ; National Key Research and Development Program of China[2019YFC1905301] ; National Natural Science Foundation of China[51976220] ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences[XDA21060101]
WOS Research AreaAgriculture
Funding OrganizationNational Key Research and Development Program of China ; National Natural Science Foundation of China ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences
WOS SubjectAgricultural Engineering ; Agronomy
WOS IDWOS:000736964600003
PublisherELSEVIER
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/35602
Collection中国科学院广州能源研究所
Corresponding AuthorLiu, Qiying; Ma, Longlong
Affiliation1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
3.Univ Sci & Technol China, Lab Basic Res Biomass Convers & Utilizat, Hefei 230026, Peoples R China
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Xia, Ying,Liu, Qiying,Hu, Xiaohong,et al. Structural evolution during corn stalk acidic and alkaline hydrogen peroxide pretreatment[J]. INDUSTRIAL CROPS AND PRODUCTS,2022,176:11.
APA Xia, Ying.,Liu, Qiying.,Hu, Xiaohong.,Li, Xu.,Huang, Yongwang.,...&Ma, Longlong.(2022).Structural evolution during corn stalk acidic and alkaline hydrogen peroxide pretreatment.INDUSTRIAL CROPS AND PRODUCTS,176,11.
MLA Xia, Ying,et al."Structural evolution during corn stalk acidic and alkaline hydrogen peroxide pretreatment".INDUSTRIAL CROPS AND PRODUCTS 176(2022):11.
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