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Hydrocarbon Distribution of Cellulose Hydrogenolysis over Ru- MoOx/C Combined with HZSM-5
Zhu, Changhui1,2,3,4; Xin, Haosheng1,2,3; Hong, Jiajun5; Wang, Haiyong1,2,3,4; Wang, Chenguang1,2,3; Ma, Longlong1,2,3; Liu, Qiying1,2,3
2021-11-08
发表期刊ACS SUSTAINABLE CHEMISTRY & ENGINEERING
ISSN2168-0485
卷号9期号:44页码:14704-14721
通讯作者Liu, Qiying(liuqy@ms.giec.ac.cn)
摘要In this paper, acidic HZSM-5 coupled with the hydrodeoxygenation catalyst Ru-MoOx/C was applied for cellulose conversion to chain-mediated small-molecule alkanes in a water-containing biphasic solvent. The physicochemical properties of the binary catalyst Ru-MoOx/C were studied by an array of characterization methods. Meanwhile, the factors (such as the HZSM-5/Ru/MoOx ratio, reaction temperature, H-2 pressure, and volume ratio of the aqueous phase and organic phase) that influenced the yield of natural gas (CH4), liquefied petroleum gas (C-2-C-4 alkanes), and gasoline (C-3-C-6 alkanes) were thoroughly investigated, obtaining the highest CH4 yield of 56.1% and the highest C-5-C-6 alkane yield of 66.1% by adjusting the volume ratio of the aqueous phase and organic phase, respectively. Especially, a promising yield of C-2-C-4 alkanes (43.7%) was obtained via precisely tailoring C-C bond splitting. HZSM-5 in water was proved as the solid acid for hydrolyzing cellulose to glucose, followed by transferring to Ru-MoOx/C located at the water-oil interface for further hydrogenolysis to alkanes. The fact that small-molecule alkane distribution can be controlled by Lewis acid density over Ru-MoOx/C was clarified: the lower Lewis acid density proved C-1-C-4 alkane production, while a higher Lewis acid density favored C-5-C-6 alkane production.
关键词cellulose small-molecule alkanes Ru-MoOx/C HZSM-5 water-oil interface
DOI10.1021/acssuschemeng.1c03978
关键词[WOS]MO/HZSM-5 CATALYST ; BIOMASS ENERGY ; SURFACE-AREA ; LACTIC-ACID ; CARBON ; PERFORMANCE ; CONVERSION ; SORBITOL ; TRANSFORMATION ; HYDROLYSIS
收录类别SCI
语种英语
资助项目National Key R&D Program of China[2018YFB1501402] ; National Science Foundation of China[51976220] ; Local Innovative and Research Teams Project of the Guangdong Pearl River Talents Program[2017BT01N092]
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Engineering
项目资助者National Key R&D Program of China ; National Science Foundation of China ; Local Innovative and Research Teams Project of the Guangdong Pearl River Talents Program
WOS类目Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical
WOS记录号WOS:000717346600008
出版者AMER CHEMICAL SOC
引用统计
被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/35334
专题中国科学院广州能源研究所
通讯作者Liu, Qiying
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China
3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
5.South China Agr Univ, Coll Mat & Energy, Guangzhou 510642, Peoples R China
第一作者单位中国科学院广州能源研究所
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GB/T 7714
Zhu, Changhui,Xin, Haosheng,Hong, Jiajun,et al. Hydrocarbon Distribution of Cellulose Hydrogenolysis over Ru- MoOx/C Combined with HZSM-5[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2021,9(44):14704-14721.
APA Zhu, Changhui.,Xin, Haosheng.,Hong, Jiajun.,Wang, Haiyong.,Wang, Chenguang.,...&Liu, Qiying.(2021).Hydrocarbon Distribution of Cellulose Hydrogenolysis over Ru- MoOx/C Combined with HZSM-5.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,9(44),14704-14721.
MLA Zhu, Changhui,et al."Hydrocarbon Distribution of Cellulose Hydrogenolysis over Ru- MoOx/C Combined with HZSM-5".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 9.44(2021):14704-14721.
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