Recent advances in selective catalytic hydrogenation of nitriles to primary amines

doi:10.1016/j.jcat.2021.10.028

GIEC OpenIR

	Recent advances in selective catalytic hydrogenation of nitriles to primary amines
	Lu, Qiqi 1,2; Liu, Jianguo 3; Ma, Longlong2,3
	2021-12-01
发表期刊	JOURNAL OF CATALYSIS
ISSN	0021-9517
卷号	404 页码:475-492
通讯作者	Liu, Jianguo(liujg@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn)
摘要	Hydrogenation of nitriles into primary amines is a crucial chemical reaction due to the importance of pri-mary amines in the plastic, pharmaceutical, and agrochemical industry. However, the control of the selec-tivity during the reaction is a major issue, which is greatly affected by the used catalysts. Therefore, to show the existing arts and trends of catalytic systems, progress made for the selective catalytic hydro-genation of nitriles into primary amines and the reaction parameters on benzonitrile of each catalytic sys-tem in the last decade are reviewed. This review also briefly discusses the effect of different substrate structures on the selectivity and the substrate scope of each catalytic system, especially the nitriles con-taining functional groups and aliphatic nitriles, which aren't mentioned in the previous reported reviews. The best results for the various chemoselectivity problems are compiled and evaluated. This review aims to critically assess the development, performance, and versatility of various catalytic systems, as well as provide new perspectives to design and apply catalysts on conditions variables and substrate structures. (c) 2021 Elsevier Inc. All rights reserved.
关键词	Nitriles Primary amines Selective hydrogenation Catalytic systems Functional groups
DOI	10.1016/j.jcat.2021.10.028
关键词[WOS]	ALKYL-ARYL KETONES ; CARBON-DIOXIDE ; REDUCTIVE AMINATION ; EFFICIENT HYDROGENATION ; AMMONIA BORANE ; COBALT NANOPARTICLES ; GENERAL-SYNTHESIS ; RUTHENIUM ; BENZONITRILE ; WATER
收录类别	SCI
语种	英语
资助项目	National Key R&D Program of China[2018YFB1501500] ; National Natural Science Foundation of China[51976225]
WOS研究方向	Chemistry ; Engineering
项目资助者	National Key R&D Program of China ; National Natural Science Foundation of China
WOS类目	Chemistry, Physical ; Engineering, Chemical
WOS记录号	WOS:000720356400014
出版者	ACADEMIC PRESS INC ELSEVIER SCIENCE
引用统计	被引频次：35[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/35256
专题	中国科学院广州能源研究所
通讯作者	Liu, Jianguo; Ma, Longlong
作者单位	1.Guangzhou Inst Energy Convers, Chinese Acad Sci, Guangdong Prov Key Lab New & Renewable Energy Res, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Jiangsu, Peoples R China
推荐引用方式 GB/T 7714	Lu, Qiqi,Liu, Jianguo,Ma, Longlong. Recent advances in selective catalytic hydrogenation of nitriles to primary amines[J]. JOURNAL OF CATALYSIS,2021,404:475-492.
APA	Lu, Qiqi,Liu, Jianguo,&Ma, Longlong.(2021).Recent advances in selective catalytic hydrogenation of nitriles to primary amines.JOURNAL OF CATALYSIS,404,475-492.
MLA	Lu, Qiqi,et al."Recent advances in selective catalytic hydrogenation of nitriles to primary amines".JOURNAL OF CATALYSIS 404(2021):475-492.