Highly Effective Production of 5-Hydroxymethylfurfural from Fructose with a Slow-Release Effect of Proton of a Heterogeneous Catalyst

doi:10.1021/acs.energyfuels.1c02693

GIEC OpenIR

	Highly Effective Production of 5-Hydroxymethylfurfural from Fructose with a Slow-Release Effect of Proton of a Heterogeneous Catalyst
	Song, Xiangbo 1,2,3; Liao, Yuhe 1; Zhu, Yuting 1,3; Sun, Pengyao 1,3; Chen, Lungang 1; Ma, Longlong1 ; Yang, Hongwei 4; Wang, Chenguang 1
	2021-10-21
发表期刊	ENERGY & FUELS
ISSN	0887-0624
卷号	35 期号:20 页码:16665-16676
通讯作者	Yang, Hongwei(hyang@eri.org.cn) ; Wang, Chenguang(wangcg@ms.giec.ac.cn)
摘要	Highly effective production of 5-hydroxymethylfurfural (HMF) from biobased sugar is one of the vital steps for the synthesis of a fuel precursor. In this work, a slow-release effect of proton from a heterogeneous catalyst induced by 1-butyl-3methylimidazole chloride ([Bmim]Cl) ionic liquids was found and employed to effectively convert biobased fructose to HMF. Under mild conditions of 100 degrees C and 60 min, a promising HMF yield of 94.6% with a fructose conversion of 99.1% could be achieved in a tetrahydrofuran solvent over the synergy of Amberlyst-15 with [Bmim]Cl, owing to the slow-release effect. Based on extensive control experiments and characterizations, a mechanism of slow release of proton induced by [Bmim]Cl was proposed to better understand the catalytic performance, mainly involving that proton in the -SO3H group of Amberlyst-15 was gradually replaced by the [Bmim]+ of the [Bmim]Cl additive. Additionally, the effect of various parameters (e.g., different ionic liquids and solvents, the loading of the ionic liquid and catalyst, and reaction temperature and time) was systematically investigated. Meanwhile, the stability of Amberlyst-15 and [Bmim]Cl was tested; both could be reused four times. This work provides a novel and highly effective strategy for conversion of biomass-based feedstock toward fuel precursors.
DOI	10.1021/acs.energyfuels.1c02693
关键词[WOS]	ION-EXCHANGE-RESIN ; HYDROXYMETHYLFURFURAL HMF ; EFFICIENT CONVERSION ; ASSISTED DEHYDRATION ; FORMIC ACIDS ; LIQUIDS ; GLUCOSE ; SYSTEM ; HYDROLYSIS ; BIOMASS
收录类别	SCI
语种	英语
资助项目	National Key R&D Program of China[2019YFD1100601] ; National Key R&D Program of China[2018YFB1501504] ; National Natural Science Foundation of China[51776206] ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N092]
WOS研究方向	Energy & Fuels ; Engineering
项目资助者	National Key R&D Program of China ; National Natural Science Foundation of China ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program
WOS类目	Energy & Fuels ; Engineering, Chemical
WOS记录号	WOS:000711024500027
出版者	AMER CHEMICAL SOC
引用统计	被引频次：6[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/35178
专题	中国科学院广州能源研究所
通讯作者	Yang, Hongwei; Wang, Chenguang
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 2.Chuxiong Normal Univ, Sch Phys & Elect Sci, Chuxiong 675099, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Natl Dev & Reform Commiss, Energy Res Inst, Acad Macroecon, Beijing 100038, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Song, Xiangbo,Liao, Yuhe,Zhu, Yuting,et al. Highly Effective Production of 5-Hydroxymethylfurfural from Fructose with a Slow-Release Effect of Proton of a Heterogeneous Catalyst[J]. ENERGY & FUELS,2021,35(20):16665-16676.
APA	Song, Xiangbo.,Liao, Yuhe.,Zhu, Yuting.,Sun, Pengyao.,Chen, Lungang.,...&Wang, Chenguang.(2021).Highly Effective Production of 5-Hydroxymethylfurfural from Fructose with a Slow-Release Effect of Proton of a Heterogeneous Catalyst.ENERGY & FUELS,35(20),16665-16676.
MLA	Song, Xiangbo,et al."Highly Effective Production of 5-Hydroxymethylfurfural from Fructose with a Slow-Release Effect of Proton of a Heterogeneous Catalyst".ENERGY & FUELS 35.20(2021):16665-16676.