A review on recent developments in N-methylation using CO2

doi:10.1016/j.jcou.2021.101759

GIEC OpenIR

	A review on recent developments in N-methylation using CO2
	Lin, Shanshan 1,2; Liu, Jianguo 3; Ma, Longlong1,3
	2021-12-01
发表期刊	JOURNAL OF CO2 UTILIZATION
ISSN	2212-9820
卷号	54 页码:18
通讯作者	Liu, Jianguo(liujg@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn)
摘要	Owing to the increasing emissions of carbon dioxide (CO2) in recent years, people's interest in the use of CO2, especially the synthesis of value-added chemicals with CO2 as a C1 blocking, has also increased year by year. In particular, the N-methylation reaction of CO2 to synthesize amines has attracted widespread attention. As an important raw material for chemical synthesis, methylation products have a wide range of uses in industry and even in nature. Using CO2 to replace traditional methylation reagents is not only green and environmentally friendly but also reduces costs. To overcome the thermodynamic and kinetic stability of CO2 and improve the selectivity and conversion rate of the N-methylation reaction, researchers are committed to the development of high-efficiency catalysts such as noble metal-supported or homogeneous catalysts, non-noble metals such as Cu, Ni, Zn, and some new metal-free catalysts. This paper summarizes and reviews the research progress and applications in the high-efficiency catalyst systems and catalytic reaction process conditions of CO2 and H-2 (or organosilane) and amines to form N-methylamine and N, N-dimethylamine compounds in recent years. It is expected to provide a reference for the development of new processes for the catalytic conversion of CO2 into high value-added chemicals.
关键词	CO2 N-methylation N-methylamine N, N-dimethylamine Catalyst DNA methylation
DOI	10.1016/j.jcou.2021.101759
关键词[WOS]	METAL-FREE CATALYST ; CARBON-DIOXIDE ; REDUCTIVE FUNCTIONALIZATION ; IONIC LIQUIDS ; AMINES ; HYDROGENATION ; FORMYLATION ; METHANOL ; HYDROSILANES ; EFFICIENT
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51976225]
WOS研究方向	Chemistry ; Engineering
项目资助者	National Natural Science Foundation of China
WOS类目	Chemistry, Multidisciplinary ; Engineering, Chemical
WOS记录号	WOS:000711394500002
出版者	ELSEVIER SCI LTD
引用统计	被引频次：18[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/35172
专题	中国科学院广州能源研究所
通讯作者	Liu, Jianguo; Ma, Longlong
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Lin, Shanshan,Liu, Jianguo,Ma, Longlong. A review on recent developments in N-methylation using CO2[J]. JOURNAL OF CO2 UTILIZATION,2021,54:18.
APA	Lin, Shanshan,Liu, Jianguo,&Ma, Longlong.(2021).A review on recent developments in N-methylation using CO2.JOURNAL OF CO2 UTILIZATION,54,18.
MLA	Lin, Shanshan,et al."A review on recent developments in N-methylation using CO2".JOURNAL OF CO2 UTILIZATION 54(2021):18.