Boron doped magnetic catalysts for selective transfer hydrogenation of furfural into furfuryl alcohol

doi:10.1016/j.ces.2020.116075

GIEC OpenIR

	Boron doped magnetic catalysts for selective transfer hydrogenation of furfural into furfuryl alcohol
	Li, Danni 1,2,4,5; Zhang, Jun 2,3,4,5; Liu, Ying 1; Yuan, Haoran2,3,4,5 ; Chen, Yong2,3,4,5
	2021-01-16
发表期刊	CHEMICAL ENGINEERING SCIENCE
ISSN	0009-2509
卷号	229 页码:12
通讯作者	Liu, Ying(amyliu@scut.edu.cn) ; Yuan, Haoran(yuanhr@ms.giec.ac.cn)
摘要	A series of boron doped magnetic zirconium catalysts were developed for the selective transfer hydrogenation of biomass-derived furfural (FFR) into furfuryl alcohol (FA) using 2-propanol as hydrogen source and solvent. Full characterizations with XRD, SEM, TG, Py-IR, NH3-TPD, and CO2-TPD techniques were undertaken to uncover structural properties of magnetic catalysts. Boron doped magnetic zirconium catalysts endowing with adjustable acid-base sites exhibited excellent performance as well as good regenerability in the transfer hydrogenation of FFR, where almost 100% FA yield was achieved in the presence of 2-propanol and the catalyst still sustained good activity after being used five times. Suitable acidity/ basicity ratio of 3.8 similar to 4.0 apparently benefited the selective production of FA. Gratifyingly, the activation energy for FA formation over Zr1B3FeO was as low as 48.3 kJ/mol. In addition, plausible reaction mechanism involving two H-transfer paths for transfer hydrogenation of FFR into FA under the catalysis of active Zr/B species was proposed. (c) 2020 Elsevier Ltd. All rights reserved.
关键词	Magnetic catalysts Transfer hydrogenation Furfural Furfuryl alcohol Activation energy
DOI	10.1016/j.ces.2020.116075
关键词[WOS]	PONNDORF-VERLEY REDUCTION ; EFFICIENT SYNTHESIS ; BIOMASS ; ACID ; CONVERSION ; ZIRCONIA ; COPPER ; VALEROLACTONE ; NANOPARTICLES ; MECHANISM
收录类别	SCI
语种	英语
资助项目	National Key R&D Program of China[2018YFC1901200] ; National Natural Science Foundation of China[51976222] ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou)[GML2019ZD0101] ; Natural Science Foundation of Guangdong Province, China[2018A030313856]
WOS研究方向	Engineering
项目资助者	National Key R&D Program of China ; National Natural Science Foundation of China ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) ; Natural Science Foundation of Guangdong Province, China
WOS类目	Engineering, Chemical
WOS记录号	WOS:000583263000008
出版者	PERGAMON-ELSEVIER SCIENCE LTD
引用统计	被引频次：23[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/34860
专题	中国科学院广州能源研究所
通讯作者	Liu, Ying; Yuan, Haoran
作者单位	1.South China Univ Technol, State Key Lab Pulp & Paper Engn, Sch Light Ind & Engn, Guangzhou 510640, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 3.Southern Marine Sci & Engn Guangdong Lab, Guangzhou 511458, Peoples R China 4.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 5.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Li, Danni,Zhang, Jun,Liu, Ying,et al. Boron doped magnetic catalysts for selective transfer hydrogenation of furfural into furfuryl alcohol[J]. CHEMICAL ENGINEERING SCIENCE,2021,229:12.
APA	Li, Danni,Zhang, Jun,Liu, Ying,Yuan, Haoran,&Chen, Yong.(2021).Boron doped magnetic catalysts for selective transfer hydrogenation of furfural into furfuryl alcohol.CHEMICAL ENGINEERING SCIENCE,229,12.
MLA	Li, Danni,et al."Boron doped magnetic catalysts for selective transfer hydrogenation of furfural into furfuryl alcohol".CHEMICAL ENGINEERING SCIENCE 229(2021):12.