Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Boron doped magnetic catalysts for selective transfer hydrogenation of furfural into furfuryl alcohol | |
Li, Danni1,2,4,5; Zhang, Jun2,3,4,5; Liu, Ying1; Yuan, Haoran2,3,4,5 ; Chen, Yong2,3,4,5
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| 2021-01-16 | |
| Source Publication | CHEMICAL ENGINEERING SCIENCE
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| ISSN | 0009-2509 |
| Volume | 229Pages:12 |
| Corresponding Author | Liu, Ying(amyliu@scut.edu.cn) ; Yuan, Haoran(yuanhr@ms.giec.ac.cn) |
| Abstract | A series of boron doped magnetic zirconium catalysts were developed for the selective transfer hydrogenation of biomass-derived furfural (FFR) into furfuryl alcohol (FA) using 2-propanol as hydrogen source and solvent. Full characterizations with XRD, SEM, TG, Py-IR, NH3-TPD, and CO2-TPD techniques were undertaken to uncover structural properties of magnetic catalysts. Boron doped magnetic zirconium catalysts endowing with adjustable acid-base sites exhibited excellent performance as well as good regenerability in the transfer hydrogenation of FFR, where almost 100% FA yield was achieved in the presence of 2-propanol and the catalyst still sustained good activity after being used five times. Suitable acidity/ basicity ratio of 3.8 similar to 4.0 apparently benefited the selective production of FA. Gratifyingly, the activation energy for FA formation over Zr1B3FeO was as low as 48.3 kJ/mol. In addition, plausible reaction mechanism involving two H-transfer paths for transfer hydrogenation of FFR into FA under the catalysis of active Zr/B species was proposed. (c) 2020 Elsevier Ltd. All rights reserved. |
| Keyword | Magnetic catalysts Transfer hydrogenation Furfural Furfuryl alcohol Activation energy |
| DOI | 10.1016/j.ces.2020.116075 |
| WOS Keyword | PONNDORF-VERLEY REDUCTION ; EFFICIENT SYNTHESIS ; BIOMASS ; ACID ; CONVERSION ; ZIRCONIA ; COPPER ; VALEROLACTONE ; NANOPARTICLES ; MECHANISM |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Key R&D Program of China[2018YFC1901200] ; National Natural Science Foundation of China[51976222] ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou)[GML2019ZD0101] ; Natural Science Foundation of Guangdong Province, China[2018A030313856] |
| WOS Research Area | Engineering |
| Funding Organization | National Key R&D Program of China ; National Natural Science Foundation of China ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) ; Natural Science Foundation of Guangdong Province, China |
| WOS Subject | Engineering, Chemical |
| WOS ID | WOS:000583263000008 |
| Publisher | PERGAMON-ELSEVIER SCIENCE LTD |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/34860 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Liu, Ying; Yuan, Haoran |
| Affiliation | 1.South China Univ Technol, State Key Lab Pulp & Paper Engn, Sch Light Ind & Engn, Guangzhou 510640, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 3.Southern Marine Sci & Engn Guangdong Lab, Guangzhou 511458, Peoples R China 4.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 5.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Li, Danni,Zhang, Jun,Liu, Ying,et al. Boron doped magnetic catalysts for selective transfer hydrogenation of furfural into furfuryl alcohol[J]. CHEMICAL ENGINEERING SCIENCE,2021,229:12. |
| APA | Li, Danni,Zhang, Jun,Liu, Ying,Yuan, Haoran,&Chen, Yong.(2021).Boron doped magnetic catalysts for selective transfer hydrogenation of furfural into furfuryl alcohol.CHEMICAL ENGINEERING SCIENCE,229,12. |
| MLA | Li, Danni,et al."Boron doped magnetic catalysts for selective transfer hydrogenation of furfural into furfuryl alcohol".CHEMICAL ENGINEERING SCIENCE 229(2021):12. |
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