ZSM-5-Supported Graphene-Encapsulated Nickel Nanoparticles: Formation, Properties, and Exceptional Performance in Lipid Hydrogenation

doi:10.1021/acssuschemeng.0c03559

GIEC OpenIR

	ZSM-5-Supported Graphene-Encapsulated Nickel Nanoparticles: Formation, Properties, and Exceptional Performance in Lipid Hydrogenation
	Li, Ming 1,2,3; Fu, Junying 1,2,3; Lv, Pengmei1,2,3,5 ; Zhang, Xufeng 1,2,3; Liu, Xiaochun 1,2,3,4; Zeng, Qiongyao 1,2,3,4; Yang, Lingmei1,2,3 ; Wang, Zhongming1,2,3 ; Yuan, Zhenhong1,2,3
	2020-10-19
发表期刊	ACS SUSTAINABLE CHEMISTRY & ENGINEERING
ISSN	2168-0485
卷号	8 期号:41 页码:15484-15495
通讯作者	Fu, Junying(fujy@ms.giec.ac.cn) ; Lv, Pengmei(lvpm@ms.giec.ac.cn)
摘要	Graphene-encapsulated nickel nanoparticles (Ni@C) were loaded on Zeolite Socony Mobil (ZSM)-5 for lipid hydrogenation to produce biojet fuel. Ni@C and ZSM-5 exhibit an efficient and synergistic catalytic activity, and the strong chemical interaction between graphene and nickel significantly improves the hydrogenation capacity of the catalyst. The graphene layers strengthened the dispersion of nickel, reduced the size of Ni@C to similar to 3.6 nm, and kept the valence state of nickel at 0. According to the hydrogenation tests, the conversion of oleic acid to jet fuel could reach 98.59% with only 3 wt % nickel loading amount. Furthermore, Ni@C/ZSM-5 shows excellent resistance to nickel agglomeration and loss.
关键词	graphene hydrogenation jet fuel nickel loss nickel agglomeration
DOI	10.1021/acssuschemeng.0c03559
关键词[WOS]	BIO-JET FUEL ; CARBON NANOTUBES ; FATTY-ACIDS ; OLEIC-ACID ; RANGE HYDROCARBONS ; VEGETABLE-OILS ; NONEDIBLE OIL ; FOSSIL-FUELS ; METAL ; CATALYSTS
收录类别	SCI
语种	英语
资助项目	Guangdong Special Support Program[2017TX04Z109] ; National Key RD Program[2019YFB1504003] ; Natural Science Foundation of Guangdong Province[2016A030308004] ; Natural Science Foundation of Guangdong Province[2018A030310078] ; National Natural Science Foundation of China[51861145103] ; National Natural Science Foundation of China Youth[51903236]
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Engineering
项目资助者	Guangdong Special Support Program ; National Key RD Program ; Natural Science Foundation of Guangdong Province ; National Natural Science Foundation of China ; National Natural Science Foundation of China Youth
WOS类目	Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical
WOS记录号	WOS:000584349900008
出版者	AMER CHEMICAL SOC
引用统计	被引频次：8[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/34857
专题	中国科学院广州能源研究所
通讯作者	Fu, Junying; Lv, Pengmei
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 5.Collaborat Innovat Ctr Biomass Energy, Zhengzhou 450002, Henan, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Li, Ming,Fu, Junying,Lv, Pengmei,et al. ZSM-5-Supported Graphene-Encapsulated Nickel Nanoparticles: Formation, Properties, and Exceptional Performance in Lipid Hydrogenation[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2020,8(41):15484-15495.
APA	Li, Ming.,Fu, Junying.,Lv, Pengmei.,Zhang, Xufeng.,Liu, Xiaochun.,...&Yuan, Zhenhong.(2020).ZSM-5-Supported Graphene-Encapsulated Nickel Nanoparticles: Formation, Properties, and Exceptional Performance in Lipid Hydrogenation.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,8(41),15484-15495.
MLA	Li, Ming,et al."ZSM-5-Supported Graphene-Encapsulated Nickel Nanoparticles: Formation, Properties, and Exceptional Performance in Lipid Hydrogenation".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 8.41(2020):15484-15495.