The role of CeO2-ZrO2 as support in the ZnO-ZnCr2O4 catalysts for autothermal reforming of methanol

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	The role of CeO2-ZrO2 as support in the ZnO-ZnCr2O4 catalysts for autothermal reforming of methanol
	Liu, N; Yuan, ZS; Wang, CW; Wang, SD; Zhang, CX; Wang, SJ
	2008
发表期刊	FUEL PROCESSING TECHNOLOGY
ISSN	0378-3820
卷号	89 期号:6 页码:574-581
通讯作者	wangsd@dicp.ac.cn
其他摘要	Autothermal reforming of methanol for hydrogen production was investigated over ZnO-ZnCr2O4 supported on a series of metal oxides (Al2O3, CeO2, ZrO2 and CeO2-ZrO2)CeO2-ZrO2 mixed oxides with Ce /Zr molar ratio of 4/1 was found to be the optimal support which showed significant effect on the catalytic activity and selectivity. The ZnO-ZnCr2O4/CeO2-ZrO2 and ZnO-ZnCr2O4 catalysts were characterized by XRD, TEM, H-2-TPR and XPS. The results show that CeO2-ZrO2 mixed oxides have significant effect on the catalytic performance and the supported catalyst shows more uniform temperature distribution in the catalyst bed which was mainly due to its reasonable redox properties.
关键词	Hydrogen Production Methanol Autothermal Reforming Zno Ceo2-zro2 Alcohol Synthesis Catalysts Fuel-cell Applications Hydrogen-production Surface Characterization Cuo/ceo2 Catalysts Redox Behavior Zn/cr Spinel Mixed Oxides Pd/zno Performance
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收录类别	SCI
语种	英语
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/3424
专题	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Liu, N,Yuan, ZS,Wang, CW,et al. The role of CeO2-ZrO2 as support in the ZnO-ZnCr2O4 catalysts for autothermal reforming of methanol[J]. FUEL PROCESSING TECHNOLOGY,2008,89(6):574-581.
APA	Liu, N,Yuan, ZS,Wang, CW,Wang, SD,Zhang, CX,&Wang, SJ.(2008).The role of CeO2-ZrO2 as support in the ZnO-ZnCr2O4 catalysts for autothermal reforming of methanol.FUEL PROCESSING TECHNOLOGY,89(6),574-581.
MLA	Liu, N,et al."The role of CeO2-ZrO2 as support in the ZnO-ZnCr2O4 catalysts for autothermal reforming of methanol".FUEL PROCESSING TECHNOLOGY 89.6(2008):574-581.

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