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BIODIESEL PRODUCTION FROM DIFFERENT FEEDSTOCKS IN PILOT SCALE SYSTEM
Ma Longlong; Lu Pengmei; Li Lianhua; Luo Wen; Kong Xiaoying; Yuan Zhenhong
2008-10-01
发表期刊JOURNAL OF OIL PALM RESEARCH
ISSN1511-2780
期号Sp. Iss. SI页码:16-21
通讯作者lvpm@ms.giec.ac.cn
摘要In this study, the preparations of biodiesel from three different feedstocks, including rapeseed oil, high acidified Chinese wood oil and trap grease, were carried out in a pilot scale of 200 t yr(-1) biodiesel production system. The optimum operating conditions for transesterification of rapeseed oil in plug flow reactor were found to be as follows: the catalyst dosage is 1.2 wt%; the retention time is about 17 min; the bed temperature is 65 degrees C; the oil/methanol ratio is 1:6; the content of methyl ester is 96.33% under these conditions. A kind of ion exchange resin, a solid acid catalyst, filled in the fixed bed reactor was used as the esterification catalyst for the pretreating of high acidified oil. The acid value of Chinese wood oil could be reduced from 7 to 0.8 mg KOH.g(-1) after 88 min, the optimum operating conditions were obtained as follow: molar ratio of methanol to oil is about 6:1, the temperature of the fixed bed, 65 degrees C and the retention time, about 88 min. Also a kind of acidified oil, namely trap grease, with the acid value being 114 mg KOH.g(-1) could be equally converted to a good biodiesel product through this system. Generally, the refined biodiesel product generated through this system could meet China #0 Biodiesel Standard, as well as Germany Biodiesel Standard for most indexes. It indicates that the designed process in this system has a good adaptability for different kinds of oil.
文章类型Article
其他摘要In this study, the preparations of biodiesel from three different feedstocks, including rapeseed oil, high acidified Chinese wood oil and trap grease, were carried out in a pilot scale of 200 t yr(-1) biodiesel production system. The optimum operating conditions for transesterification of rapeseed oil in plug flow reactor were found to be as follows: the catalyst dosage is 1.2 wt%; the retention time is about 17 min; the bed temperature is 65 degrees C; the oil/methanol ratio is 1:6; the content of methyl ester is 96.33% under these conditions. A kind of ion exchange resin, a solid acid catalyst, filled in the fixed bed reactor was used as the esterification catalyst for the pretreating of high acidified oil. The acid value of Chinese wood oil could be reduced from 7 to 0.8 mg KOH.g(-1) after 88 min, the optimum operating conditions were obtained as follow: molar ratio of methanol to oil is about 6:1, the temperature of the fixed bed, 65 degrees C and the retention time, about 88 min. Also a kind of acidified oil, namely trap grease, with the acid value being 114 mg KOH.g(-1) could be equally converted to a good biodiesel product through this system. Generally, the refined biodiesel product generated through this system could meet China #0 Biodiesel Standard, as well as Germany Biodiesel Standard for most indexes. It indicates that the designed process in this system has a good adaptability for different kinds of oil.
关键词High Acidified Oil Solid Acid Catalyst Plug Flow Reactor Biodiesel
WOS标题词Science & Technology ; Life Sciences & Biomedicine
研究领域[WOS]Food Science & Technology
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收录类别SCI
语种英语
WOS类目Food Science & Technology
WOS记录号WOS:000207538400005
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被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/3404
专题中国科学院广州能源研究所
作者单位Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
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GB/T 7714
Ma Longlong,Lu Pengmei,Li Lianhua,et al. BIODIESEL PRODUCTION FROM DIFFERENT FEEDSTOCKS IN PILOT SCALE SYSTEM[J]. JOURNAL OF OIL PALM RESEARCH,2008(Sp. Iss. SI):16-21.
APA Ma Longlong,Lu Pengmei,Li Lianhua,Luo Wen,Kong Xiaoying,&Yuan Zhenhong.(2008).BIODIESEL PRODUCTION FROM DIFFERENT FEEDSTOCKS IN PILOT SCALE SYSTEM.JOURNAL OF OIL PALM RESEARCH(Sp. Iss. SI),16-21.
MLA Ma Longlong,et al."BIODIESEL PRODUCTION FROM DIFFERENT FEEDSTOCKS IN PILOT SCALE SYSTEM".JOURNAL OF OIL PALM RESEARCH .Sp. Iss. SI(2008):16-21.
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