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Production of biodiesel from soapstock using an ion-exchange resin catalyst
Park, JY; Kim, DK; Wang, ZM; Lee, JP; Park, SC; Lee, JS
2008
Source PublicationKOREAN JOURNAL OF CHEMICAL ENGINEERING
ISSN0256-1115
Volume25Issue:6Pages:1350-1354
Corresponding Authorbmjslee@kier.re.kr
Other AbstractThe feasibility of biodiesel production from soapstock containing high water content and fatty matters by a solid acid catalyst was investigated. Soapstock was converted to high-acid acid oil (HAAO) by the hydrolysis by KOH and the acidulation by sulfuric acid. The acid value of soapstock-HAAO increased to 199.1 mg KOH/g but a large amount of potassium sulfate was produced. To resolve the formation of potassium sulfate, acid oil was extracted from soapstock and was converted to HAAO by using sodium dodecyl benzene sulfonate (SDBS). The maximum acid value of acid oil-HAAO was 194.2 mg KOH/g when the mass ratio of acid oil, sulfuric acid, and water was 10:4:10 at 2% of SDBS. In the esterification of HAAO using Amberylst-15, fatty acid methyl ester (FAME) concentration was 91.7 and 81.3% for soapstock and acid oil, respectively. After the distillation, FAME concentration became 98.1% and 96.7% for soapstock and acid oil. The distillation process decreased the total glycerin and the acid value of FAME produced a little.
KeywordBiodiesel Soapstock Acid Oil Anionic Surfactant High-Acid Acid Oil Solid Acid Catalyst Diesel Fuel Oil Acid Transesterification Microemulsions Methanol
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Indexed BySCI
Language英语
Funding OrganizationResource Recycling RD Center ; 21C Frontier RD Program
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/3402
Collection中国科学院广州能源研究所
Recommended Citation
GB/T 7714
Park, JY,Kim, DK,Wang, ZM,et al. Production of biodiesel from soapstock using an ion-exchange resin catalyst[J]. KOREAN JOURNAL OF CHEMICAL ENGINEERING,2008,25(6):1350-1354.
APA Park, JY,Kim, DK,Wang, ZM,Lee, JP,Park, SC,&Lee, JS.(2008).Production of biodiesel from soapstock using an ion-exchange resin catalyst.KOREAN JOURNAL OF CHEMICAL ENGINEERING,25(6),1350-1354.
MLA Park, JY,et al."Production of biodiesel from soapstock using an ion-exchange resin catalyst".KOREAN JOURNAL OF CHEMICAL ENGINEERING 25.6(2008):1350-1354.
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