Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Partial oxidation reforming of biomass fuel gas over nickel-based monolithic catalyst with naphthalene as model compound | |
| Wang, Chen Guang1,3; Wang, Tie Jun1,2; Ma, Long Long1,2; Gao, Yan1,3; Wu, Chuang Zhi1,2 | |
| 2008-07-01 | |
| 发表期刊 | KOREAN JOURNAL OF CHEMICAL ENGINEERING
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| 卷号 | 25期号:4页码:738-743 |
| 通讯作者 | Wangtj@ms.giec.ac.cn |
| 摘要 | With naphthalene as biomass tar model compound, partial oxidation reforming (with addition of O-2) and dry reforming of biomass fuel gas were investigated over nickel-based monoliths at the same conditions. The results showed that both processes had excellent performance in upgrading biomass raw fuel gas. Above 99% of naphthalene was converted into synthesis gases (H-2+CO). About 2.8 wt% of coke deposition was detected on the catalyst surface for dry reforming process at 750 degrees C during 108 h lifetime test. However, no Coke deposition was detected for partial oxidation reforming process, which indicated that addition of O-2 can effectively prohibit the coke formation. O-2 Can also increase the CH4 conversion and H-2/CO ratio of the producer gas. The average conversion of CH4 in dry and partial oxidation reforming process was 92% and 95%, respectively. The average H-2/CO ratio increased from 0.95 to 1.1 with the addition of O-2, which was suitable to be used as synthesis gas for dimethyl ether (DME) synthesis. |
| 文章类型 | Article |
| 其他摘要 | With naphthalene as biomass tar model compound, partial oxidation reforming (with addition of O-2) and dry reforming of biomass fuel gas were investigated over nickel-based monoliths at the same conditions. The results showed that both processes had excellent performance in upgrading biomass raw fuel gas. Above 99% of naphthalene was converted into synthesis gases (H-2+CO). About 2.8 wt% of coke deposition was detected on the catalyst surface for dry reforming process at 750 degrees C during 108 h lifetime test. However, no Coke deposition was detected for partial oxidation reforming process, which indicated that addition of O-2 can effectively prohibit the coke formation. O-2 Can also increase the CH4 conversion and H-2/CO ratio of the producer gas. The average conversion of CH4 in dry and partial oxidation reforming process was 92% and 95%, respectively. The average H-2/CO ratio increased from 0.95 to 1.1 with the addition of O-2, which was suitable to be used as synthesis gas for dimethyl ether (DME) synthesis. |
| 关键词 | Biomass Fuel Gas Monolithic Catalyst Partial Oxidation Reforming Tar Elimination |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 研究领域[WOS] | Chemistry ; Engineering |
| 关键词[WOS] | FLUIDIZED-BEDS ; NATURAL-GAS ; GASIFICATION ; METHANE ; COMBUSTION ; PERFORMANCE ; ELIMINATION ; NI/AL2O3 ; REACTOR ; SYNGAS |
| 收录类别 | SCI |
| 语种 | 英语 |
| 项目资助者 | Natural Science Foundation of China [50506030]; Natural Science Foundation of Guangdong Province, China [06020449] |
| WOS类目 | Chemistry, Multidisciplinary ; Engineering, Chemical |
| WOS记录号 | WOS:000258549600019 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.giec.ac.cn/handle/344007/3384 |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China |
| 第一作者单位 | 中国科学院广州能源研究所 |
| 推荐引用方式 GB/T 7714 | Wang, Chen Guang,Wang, Tie Jun,Ma, Long Long,et al. Partial oxidation reforming of biomass fuel gas over nickel-based monolithic catalyst with naphthalene as model compound[J]. KOREAN JOURNAL OF CHEMICAL ENGINEERING,2008,25(4):738-743. |
| APA | Wang, Chen Guang,Wang, Tie Jun,Ma, Long Long,Gao, Yan,&Wu, Chuang Zhi.(2008).Partial oxidation reforming of biomass fuel gas over nickel-based monolithic catalyst with naphthalene as model compound.KOREAN JOURNAL OF CHEMICAL ENGINEERING,25(4),738-743. |
| MLA | Wang, Chen Guang,et al."Partial oxidation reforming of biomass fuel gas over nickel-based monolithic catalyst with naphthalene as model compound".KOREAN JOURNAL OF CHEMICAL ENGINEERING 25.4(2008):738-743. |
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