Palladium Nanoparticles on Covalent Organic Framework Supports as Catalysts for Suzuki-Miyaura Cross-Coupling Reactions

doi:10.1021/acsanm.1c01038

GIEC OpenIR

	Palladium Nanoparticles on Covalent Organic Framework Supports as Catalysts for Suzuki-Miyaura Cross-Coupling Reactions
	Liu, Jianguo 3; Zhan, Hao 1; Wang, Nan 2; Song, Yanpei 3; Wang, Chenguang 3; Wang, Xinming 1; Ma, Longlong2,3 ; Chen, Lungang 3
	2021-06-25
发表期刊	ACS APPLIED NANO MATERIALS
ISSN	2574-0970
卷号	4 期号:6 页码:6239-6249
通讯作者	Liu, Jianguo(Liujg@ms.giec.ac.cn) ; Ma, Longlong(Mall@ms.giec.ac.cn)
摘要	Suzuki-Miyaura cross-coupling (SMC) reaction by palladium (Pd) catalysis is widely used in cross-coupling chemistry synthesis for C-C bond formation, yet the biaryl products are generally lacking halo substituents due to highly active palladium species. Suitable catalysts according to this property for the regionselective SMC synthesis of biaryl derivatives with halo substituents did not receive due and sufficient attention. Here, we report the facile synthesis of a covalent organic frameworks (COFs)supported nanoparticles Pd catalyst that can region-selectively catalyze the SMC reaction of aryl boronic acids and aryl halides, especially with halogenated aryl boronic acids. The methodology exhibits mild operating conditions, broad functional group tolerance, and environmental friendliness and can be strategically applied for cross-coupling scenarios governed by sequential transition metal catalysts to build with or without a halo-substituted moiety. The Pd/COF-SMC nanoparticles catalysts are stable and reusable and succeed in synthesizing halo-substituted biaryl products in excellent yield, which avoids the homocoupling of halogenated aryl boronic acid. The most outstanding advantage is the precise regulation of nanoparticles Pd activity with the well-designed COF ligand.
关键词	covalent organic framework precise regulation palladium catalysis Suzuki-Miyaura cross-coupling reaction halo-substituted biaryl compounds
DOI	10.1021/acsanm.1c01038
关键词[WOS]	PD NANOPARTICLES ; C-C ; CONSTRUCTION ; CRYSTALLINE ; HYDROGEN ; COF
收录类别	SCI
语种	英语
资助项目	National Key R&D Program of China[2019YFD1100601] ; National Natural Science Foundation of China[51976225] ; DNL Cooperation Fund, CAS[DNL201916]
WOS研究方向	Science & Technology - Other Topics ; Materials Science
项目资助者	National Key R&D Program of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS
WOS类目	Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:000668366800066
出版者	AMER CHEMICAL SOC
引用统计	被引频次：26[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/33440
专题	中国科学院广州能源研究所
通讯作者	Liu, Jianguo; Ma, Longlong
作者单位	1.Chinese Acad Sci, Guangzhou Inst Geochem, State Key Lab Organ Geochem, Guangdong Key Lab Environm Protect & Resources Ut, Guangzhou 510640, Peoples R China 2.Tianjin Univ, Sch Environm Sci & Engn, Tianjin 300350, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy,CAS, Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Liu, Jianguo,Zhan, Hao,Wang, Nan,et al. Palladium Nanoparticles on Covalent Organic Framework Supports as Catalysts for Suzuki-Miyaura Cross-Coupling Reactions[J]. ACS APPLIED NANO MATERIALS,2021,4(6):6239-6249.
APA	Liu, Jianguo.,Zhan, Hao.,Wang, Nan.,Song, Yanpei.,Wang, Chenguang.,...&Chen, Lungang.(2021).Palladium Nanoparticles on Covalent Organic Framework Supports as Catalysts for Suzuki-Miyaura Cross-Coupling Reactions.ACS APPLIED NANO MATERIALS,4(6),6239-6249.
MLA	Liu, Jianguo,et al."Palladium Nanoparticles on Covalent Organic Framework Supports as Catalysts for Suzuki-Miyaura Cross-Coupling Reactions".ACS APPLIED NANO MATERIALS 4.6(2021):6239-6249.