Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Synthesis of High-Density Components of Jet Fuel from Lignin-Derived Aromatics via Alkylation and Subsequent Hydrodeoxygenation | |
Bai, Jing1,2; Zhang, Yang1,3; Zhang, Xinghua3,4 ; Wang, Chenguang3; Ma, Longlong3
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| 2021-05-24 | |
| Source Publication | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
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| ISSN | 2168-0485 |
| Volume | 9Issue:20Pages:7112-7119 |
| Corresponding Author | Zhang, Xinghua(zhangxh@ms.giec.ac.cn) ; Wang, Chenguang(wangcg@ms.giec.ac.cn) |
| Abstract | High-density polycyclic alkanes prepared from lignocellulose biomass are an important substitute for fossil fuels. Here, we reported a synthesis strategy in that lignin-derived phenol and benzyl acetate were used to synthesize jet fuel-range high-density alkanes. Benzylphenols (C13-oxygenated compounds) were synthesized through the alkylation reaction of phenol and benzyl acetate over a montmorillonite (MMT) catalyst. The lewis acid site of MMT is favorable for the formation of the benzyl cation, promoting the alkylation reaction. Under the conditions of 140 degrees C and 2 h, the yield of alkylation products reaches 70%. Subsequently, the hydrodeoxygenation (HDO) of alkylation products was conducted over a 5 wt % Pd/C catalyst, and the yield of 85% hydrocarbons was obtained. Perhydrofluorene and dicyclohexylmethane were the dominant components in the HDO products. The density and heating values of HDO products were 0.956 g/cm(3) and 38.9 MJ/L, respectively. |
| Keyword | biomass alkylation hydrodeoxygenation dicyclohexylmethane perhydrofluorene high-density jet fuel |
| DOI | 10.1021/acssuschemeng.1c01339 |
| WOS Keyword | RANGE ALKANES ; ACID SITES ; BENZYLATION ; AVIATION ; PYROLYSIS ; CATALYST ; BENZENE ; BIOFUEL ; BIOMASS ; PHENOL |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[51876210] ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences[XDA21060102] ; local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N092] ; Special Support Program of Guangdong Province for Top Young Talents[2019TQ05L238] |
| WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Engineering |
| Funding Organization | National Natural Science Foundation of China ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences ; local Innovative and Research Teams Project of Guangdong Pearl River Talents Program ; Special Support Program of Guangdong Province for Top Young Talents |
| WOS Subject | Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical |
| WOS ID | WOS:000656120600019 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/33308 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Zhang, Xinghua; Wang, Chenguang |
| Affiliation | 1.Zhengzhou Univ, Sch Chem Engn & Energy, Zhengzhou 450001, Henan, Peoples R China 2.Henan Outstanding Foreign Scientists Workroom, Zhengzhou 450001, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 4.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
| Recommended Citation GB/T 7714 | Bai, Jing,Zhang, Yang,Zhang, Xinghua,et al. Synthesis of High-Density Components of Jet Fuel from Lignin-Derived Aromatics via Alkylation and Subsequent Hydrodeoxygenation[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2021,9(20):7112-7119. |
| APA | Bai, Jing,Zhang, Yang,Zhang, Xinghua,Wang, Chenguang,&Ma, Longlong.(2021).Synthesis of High-Density Components of Jet Fuel from Lignin-Derived Aromatics via Alkylation and Subsequent Hydrodeoxygenation.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,9(20),7112-7119. |
| MLA | Bai, Jing,et al."Synthesis of High-Density Components of Jet Fuel from Lignin-Derived Aromatics via Alkylation and Subsequent Hydrodeoxygenation".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 9.20(2021):7112-7119. |
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