Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| 5-Hydroxymethylfurfural Hydrodeoxygenation Coupled with Water-Gas Shift Reaction for 2,5-Dimethylfuran Production over Au/ZrO2 Catalysts | |
Li, Zhijian1,2,3,4; Zhu, Changhui1,3,4; Wang, Haiyong1,3,4; Liang, Yuan1,3,4; Xin, Haosheng1,3,4; Li, Song1,3,4; Hu, Xiaohong1,3,4; Wang, Chenguang1,3,4; Zhang, Qi1,3,4 ; Liu, Qiying1,3,4,5; Ma, Longlong1,3,4
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| 2021-05-10 | |
| Source Publication | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
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| ISSN | 2168-0485 |
| Volume | 9Issue:18Pages:6355-6369 |
| Corresponding Author | Liu, Qiying(liuqy@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn) |
| Abstract | For the biomass catalytic valorization in the presence of a H-2 atmosphere, large amounts of H2O and H-2 are necessary to improve the processing efficiency, which resulted in the waste of such generous inputs. As a model reaction, the traditional hydrodeoxygenation of 5-hydroxymethylfurfural (5-HMF) selectively produces 2,5-dimethylfuran (2,5-DMF) under high pressure H-2. Meanwhile, the water-gas shift reaction (WGSR) can counteract the harmful CO by simultaneously producing H-2 from H2O. The hydrogenolysis of 5-HMF to 2,5-DMF produces H2O because of the hydroxyl group removal. Therefore, adding a trace amount of H2O to initiate 5-HMF hydrodeoxygenation coupled with WGSR to achieve H2O recycling in the reaction process is of great significance but extremely challenging. Herein, we reported a new process for the selective hydrodeoxygenation of 5-HMF to 2,5-DMF coupled with WGSR using a single catalyst, Au/ZrO2. A detailed study showed that the hydrogen species produced in situ by WGSR was used for 5-HMF hydrodeoxygenation to obtain 78.5% of 2,5-DMF yield. The H/H2O cycle in the coupling reactions exhibited a H-2 utilization efficiency of 88.2%. Without using external H-2, this work provided a new method for 5-HMF hydrodeoxygenation to 2,5-DMF triggered by WGSR and also showed the potential for application in H2O-saving conversion of cellulosic biomass with C-OH or C=O groups to value-added chemicals and fuels. |
| Keyword | Au/ZrO2 H/H2O cycling WGSR 5-HMF hydrodeoxygenation 2,5-DMF |
| DOI | 10.1021/acssuschemeng.1c00616 |
| WOS Keyword | LIQUID FUEL 2,5-DIMETHYLFURAN ; SELECTIVE HYDRODEOXYGENATION ; EFFICIENT PRODUCTION ; DIRECT CONVERSION ; TRANSITION-METAL ; OXYGEN VACANCIES ; GOLD CATALYSTS ; SURFACE SITES ; TEMPERATURE ; HYDROGENATION |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[51976220] ; National Key R&D Program of China[2019YFC1905303] ; National Key R&D Program of China[2018YFB1501402] ; Natural Science Foundation of Guangdong Province[2017A030308010] ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N092] |
| WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Engineering |
| Funding Organization | National Natural Science Foundation of China ; National Key R&D Program of China ; Natural Science Foundation of Guangdong Province ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program |
| WOS Subject | Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical |
| WOS ID | WOS:000651053000021 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/33302 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Liu, Qiying; Ma, Longlong |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China 3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Peoples R China 4.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 5.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Li, Zhijian,Zhu, Changhui,Wang, Haiyong,et al. 5-Hydroxymethylfurfural Hydrodeoxygenation Coupled with Water-Gas Shift Reaction for 2,5-Dimethylfuran Production over Au/ZrO2 Catalysts[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2021,9(18):6355-6369. |
| APA | Li, Zhijian.,Zhu, Changhui.,Wang, Haiyong.,Liang, Yuan.,Xin, Haosheng.,...&Ma, Longlong.(2021).5-Hydroxymethylfurfural Hydrodeoxygenation Coupled with Water-Gas Shift Reaction for 2,5-Dimethylfuran Production over Au/ZrO2 Catalysts.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,9(18),6355-6369. |
| MLA | Li, Zhijian,et al."5-Hydroxymethylfurfural Hydrodeoxygenation Coupled with Water-Gas Shift Reaction for 2,5-Dimethylfuran Production over Au/ZrO2 Catalysts".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 9.18(2021):6355-6369. |
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