5-Hydroxymethylfurfural Hydrodeoxygenation Coupled with Water-Gas Shift Reaction for 2,5-Dimethylfuran Production over Au/ZrO2 Catalysts

doi:10.1021/acssuschemeng.1c00616

GIEC OpenIR

	5-Hydroxymethylfurfural Hydrodeoxygenation Coupled with Water-Gas Shift Reaction for 2,5-Dimethylfuran Production over Au/ZrO2 Catalysts
	Li, Zhijian 1,2,3,4; Zhu, Changhui 1,3,4; Wang, Haiyong 1,3,4; Liang, Yuan 1,3,4; Xin, Haosheng 1,3,4; Li, Song 1,3,4; Hu, Xiaohong 1,3,4; Wang, Chenguang 1,3,4; Zhang, Qi1,3,4 ; Liu, Qiying1,3,4,5 ; Ma, Longlong1,3,4
	2021-05-10
发表期刊	ACS SUSTAINABLE CHEMISTRY & ENGINEERING
ISSN	2168-0485
卷号	9 期号:18 页码:6355-6369
通讯作者	Liu, Qiying(liuqy@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn)
摘要	For the biomass catalytic valorization in the presence of a H-2 atmosphere, large amounts of H2O and H-2 are necessary to improve the processing efficiency, which resulted in the waste of such generous inputs. As a model reaction, the traditional hydrodeoxygenation of 5-hydroxymethylfurfural (5-HMF) selectively produces 2,5-dimethylfuran (2,5-DMF) under high pressure H-2. Meanwhile, the water-gas shift reaction (WGSR) can counteract the harmful CO by simultaneously producing H-2 from H2O. The hydrogenolysis of 5-HMF to 2,5-DMF produces H2O because of the hydroxyl group removal. Therefore, adding a trace amount of H2O to initiate 5-HMF hydrodeoxygenation coupled with WGSR to achieve H2O recycling in the reaction process is of great significance but extremely challenging. Herein, we reported a new process for the selective hydrodeoxygenation of 5-HMF to 2,5-DMF coupled with WGSR using a single catalyst, Au/ZrO2. A detailed study showed that the hydrogen species produced in situ by WGSR was used for 5-HMF hydrodeoxygenation to obtain 78.5% of 2,5-DMF yield. The H/H2O cycle in the coupling reactions exhibited a H-2 utilization efficiency of 88.2%. Without using external H-2, this work provided a new method for 5-HMF hydrodeoxygenation to 2,5-DMF triggered by WGSR and also showed the potential for application in H2O-saving conversion of cellulosic biomass with C-OH or C=O groups to value-added chemicals and fuels.
关键词	Au/ZrO2 H/H2O cycling WGSR 5-HMF hydrodeoxygenation 2,5-DMF
DOI	10.1021/acssuschemeng.1c00616
关键词[WOS]	LIQUID FUEL 2,5-DIMETHYLFURAN ; SELECTIVE HYDRODEOXYGENATION ; EFFICIENT PRODUCTION ; DIRECT CONVERSION ; TRANSITION-METAL ; OXYGEN VACANCIES ; GOLD CATALYSTS ; SURFACE SITES ; TEMPERATURE ; HYDROGENATION
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51976220] ; National Key R&D Program of China[2019YFC1905303] ; National Key R&D Program of China[2018YFB1501402] ; Natural Science Foundation of Guangdong Province[2017A030308010] ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N092]
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Engineering
项目资助者	National Natural Science Foundation of China ; National Key R&D Program of China ; Natural Science Foundation of Guangdong Province ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program
WOS类目	Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical
WOS记录号	WOS:000651053000021
出版者	AMER CHEMICAL SOC
引用统计	被引频次：11[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/33302
专题	中国科学院广州能源研究所
通讯作者	Liu, Qiying; Ma, Longlong
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China 3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Peoples R China 4.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 5.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Li, Zhijian,Zhu, Changhui,Wang, Haiyong,et al. 5-Hydroxymethylfurfural Hydrodeoxygenation Coupled with Water-Gas Shift Reaction for 2,5-Dimethylfuran Production over Au/ZrO2 Catalysts[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2021,9(18):6355-6369.
APA	Li, Zhijian.,Zhu, Changhui.,Wang, Haiyong.,Liang, Yuan.,Xin, Haosheng.,...&Ma, Longlong.(2021).5-Hydroxymethylfurfural Hydrodeoxygenation Coupled with Water-Gas Shift Reaction for 2,5-Dimethylfuran Production over Au/ZrO2 Catalysts.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,9(18),6355-6369.
MLA	Li, Zhijian,et al."5-Hydroxymethylfurfural Hydrodeoxygenation Coupled with Water-Gas Shift Reaction for 2,5-Dimethylfuran Production over Au/ZrO2 Catalysts".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 9.18(2021):6355-6369.