Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Effects of metal catalysts on CO2 gasification reactivity of biomass char | |
| Huang, Yanqin1,2; Yin, Xiuli1; Wu, Chuangzhi1; Wang, Congwei1; Xie, Jianjun1; Zhou, Zhaoqiu1; Ma, Longlong1; Li, Haibin1 | |
| 2009-09-01 | |
| 发表期刊 | BIOTECHNOLOGY ADVANCES
 |
| ISSN | 0734-9750 |
| 卷号 | 27期号:5页码:568-572 |
| 通讯作者 | xlyin@ms.giec.ac.cn ; wucz@ms.giec.ac.cn |
| 摘要 | The effects of five metal catalysts (K, Na, Ca, Mg, and Fe) on CO2 gasification reactivity of fir char were studied using thermal gravimetric analysis. The degree of carbonization, crystal structure and morphology of char samples was characterized by X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The CO2 gasification reactivity of fir char was improved through the addition of metal catalysts, in the order K>Na>Ca>Fe>Mg. XRD analysis indicated that Na and Ca improved the formation of crystal structure and that, Mg enhanced the degree of carbon structure ordering. SEM analysis showed that spotted activation centers were distributed on the surface of char samples impregnated with catalysts. Moreover, a loose flake structure was observed on the surface of both K-char and Na-char. Finally, the kinetic parameters of CO2 gasification of char samples were calculated mathematically. (C) 2009 Elsevier Inc. All rights reserved. |
| 文章类型 | Article |
| 其他摘要 | The effects of five metal catalysts (K, Na, Ca, Mg, and Fe) on CO2 gasification reactivity of fir char were studied using thermal gravimetric analysis. The degree of carbonization, crystal structure and morphology of char samples was characterized by X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The CO2 gasification reactivity of fir char was improved through the addition of metal catalysts, in the order K>Na>Ca>Fe>Mg. XRD analysis indicated that Na and Ca improved the formation of crystal structure, and that Mg enhanced the degree of carbon structure ordering. SEM analysis showed that spotted activation centers were distributed on the surface of char samples impregnated with catalysts. Moreover, a loose flake structure was observed on the surface of both K-char and Na-char. Finally, the kinetic parameters of CO2 gasification of char samples were calculated mathematically. |
| 关键词 | Fir Chars Co2 Gasification Metal Catalysts Xrd Sem Kinetic Parameters |
| WOS标题词 | Science & Technology ; Life Sciences & Biomedicine |
| DOI | 10.1016/j.biotechadv.2009.04.013 |
| 研究领域[WOS] | Biotechnology & Applied Microbiology |
| URL | 查看原文 |
| 关键词[WOS] | COAL ; CARBON ; GASIFIER ; GAS |
| 收录类别 | SCI ; ISTP |
| 语种 | 英语 |
| WOS类目 | Biotechnology & Applied Microbiology |
| WOS记录号 | WOS:000267741300006 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.giec.ac.cn/handle/344007/3324 |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Renewable Energy & Gas Hydrate Key Lab, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Yanqin,Yin, Xiuli,Wu, Chuangzhi,et al. Effects of metal catalysts on CO2 gasification reactivity of biomass char[J]. BIOTECHNOLOGY ADVANCES,2009,27(5):568-572. |
| APA | Huang, Yanqin.,Yin, Xiuli.,Wu, Chuangzhi.,Wang, Congwei.,Xie, Jianjun.,...&Li, Haibin.(2009).Effects of metal catalysts on CO2 gasification reactivity of biomass char.BIOTECHNOLOGY ADVANCES,27(5),568-572. |
| MLA | Huang, Yanqin,et al."Effects of metal catalysts on CO2 gasification reactivity of biomass char".BIOTECHNOLOGY ADVANCES 27.5(2009):568-572. |
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