Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
The Relationship between Thermal Characteristics and Microstructure/Composition of Carbon Dioxide Hydrate in the Presence of Cyclopentane | |
Xu, Chun-Gang1,2,3,4,5; Wang, Min1,6; Xu, Gang1,5; Li, Xiao-Sen1,2,3,4,5; Zhang, Wei1,5; Cai, Jing1,2,3,4; Chen, Zhao-Yang1,2,3,4,5 | |
2021-02-01 | |
Source Publication | ENERGIES |
Volume | 14Issue:4Pages:17 |
Corresponding Author | Xu, Chun-Gang(xucg@ms.giec.ac.cn) ; Li, Xiao-Sen(lixs@ms.giec.ac.cn) |
Abstract | Hydrate-based carbon dioxide (CO2) separation and capture is a new technology for achieving CO2 emission reduction. However, it is still not commercially applied for the ambiguity of microscopic hydrate formation mechanism. In a constant volume experiment of hydrate formation, there are two or more pressure platforms, indicating that there might be two or more different hydrates formation in succession. In order to reveal the relationship between the microscopic process and the gas consumption in the process of hydrate formation, hydrate composition and formation mechanism of cyclopentane-CO2 (CP-CO2) system was investigated using a differential scanning calorimeter (DSC) and Raman spectroscopy. The results indicated CO2-CP binary hydrate and CO2 hydrate are formed successively, and they coexist in the final hydrate. CP-CO2 binary hydrates forms preferentially, and as crystal seeds, inducing the formation of CO2 hydrates. The two hydrates formation processes cause the two pressure-drops. The results provide a scientific basis for increasing the gas consumption in different stages of gas hydrate formation in the presence of hydrate formation promoter. |
Keyword | carbon emission reduction hydrate microscopic mechanism binary hydrate DSC |
DOI | 10.3390/en14040870 |
Indexed By | SCI |
Language | 英语 |
Funding Project | National Natural Science Foundation of China[51736009] ; National Natural Science Foundation of China[51879254] ; Natural Science Fund of Guangdong Province, China[2019A1515011490] ; Special project for marine economy development of Guangdong Province[GDME-2018D002] ; Key Research Program of Frontier Sciences, CAS[ZDBS-LY-SLH041] |
WOS Research Area | Energy & Fuels |
Funding Organization | National Natural Science Foundation of China ; Natural Science Fund of Guangdong Province, China ; Special project for marine economy development of Guangdong Province ; Key Research Program of Frontier Sciences, CAS |
WOS Subject | Energy & Fuels |
WOS ID | WOS:000623474000001 |
Publisher | MDPI |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.giec.ac.cn/handle/344007/32734 |
Collection | 中国科学院广州能源研究所 |
Corresponding Author | Xu, Chun-Gang; Li, Xiao-Sen |
Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.CAS Key Lab Gas Hydrate, Guangzhou 510640, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 4.Chinese Acad Sci, Guangzhou Ctr Gas Hydrate Res, Guangzhou 510640, Peoples R China 5.Univ Sci & Technol China, Sch Engneering Sci, Hefei 230023, Peoples R China 6.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China |
First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
Recommended Citation GB/T 7714 | Xu, Chun-Gang,Wang, Min,Xu, Gang,et al. The Relationship between Thermal Characteristics and Microstructure/Composition of Carbon Dioxide Hydrate in the Presence of Cyclopentane[J]. ENERGIES,2021,14(4):17. |
APA | Xu, Chun-Gang.,Wang, Min.,Xu, Gang.,Li, Xiao-Sen.,Zhang, Wei.,...&Chen, Zhao-Yang.(2021).The Relationship between Thermal Characteristics and Microstructure/Composition of Carbon Dioxide Hydrate in the Presence of Cyclopentane.ENERGIES,14(4),17. |
MLA | Xu, Chun-Gang,et al."The Relationship between Thermal Characteristics and Microstructure/Composition of Carbon Dioxide Hydrate in the Presence of Cyclopentane".ENERGIES 14.4(2021):17. |
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