Facile Synthesis of COF-Supported Reduced Pd-Based Catalyst for One-Pot Reductive Amination of Aldehydes

doi:10.3390/catal11020287

GIEC OpenIR

	Facile Synthesis of COF-Supported Reduced Pd-Based Catalyst for One-Pot Reductive Amination of Aldehydes
	Liu, Jianguo 1,2; Zhang, Mingyue 1,3; Ma, Longlong1
	2021-02-01
Source Publication	CATALYSTS
Volume	11 Issue:2 Pages:13
Corresponding Author	Liu, Jianguo(liujg@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn)
Abstract	Dibenzylamine motifs are an important class of crucial organic compounds and are widely used in fine chemical and pharmaceutical industries. The development of the efficient, economical, and environmentally friendly synthesis of amines using transition metal-based heterogeneous catalysts remains both desirable and challenging. Herein, we prepared the covalent organic framework (COF)-supported heterogeneous reduced COF-supported Pd-based catalyst and used it for the one-pot reductive amination of aldehydes. There are both Pd metallic state and oxidated Pd sigma+ in the catalysts. Furthermore, in the presence of the reduced COF-supported Pd-based catalyst, many aromatic, aliphatic, and heterocyclic aldehydes with various functional groups substituted were converted to their corresponding amines products in good to excellent selectivity (up to 91%) under mild reaction conditions (70 degrees C, 2 h, NH3, 20 bar H-2). This work expands the covalent organic frameworks for the material family and its support catalyst, opening up new catalytic applications in the economical, practical, and effective synthesis of secondary amines.
Keyword	COF reduced COF-supported Pd-based catalyst reductive amination secondary amines
DOI	10.3390/catal11020287
Indexed By	SCI
Language	英语
Funding Project	National Key R&D Program of China[2018YFB1501502] ; National Natural Science Foundation of China[2018YFB1501502] ; Dalian National Laboratory Cooperation Foundation[DNL201916]
WOS Research Area	Chemistry
Funding Organization	National Key R&D Program of China ; National Natural Science Foundation of China ; Dalian National Laboratory Cooperation Foundation
WOS Subject	Chemistry, Physical
WOS ID	WOS:000622293700001
Publisher	MDPI
Citation statistics	Cited Times:3[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.giec.ac.cn/handle/344007/32648
Collection	中国科学院广州能源研究所
Corresponding Author	Liu, Jianguo; Ma, Longlong
Affiliation	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangdong Key Lab New & Renewable Energy Res & De, Key Lab Renewable Energy,CAS, Guangzhou 510640, Peoples R China 2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
First Author Affilication	GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation GB/T 7714	Liu, Jianguo,Zhang, Mingyue,Ma, Longlong. Facile Synthesis of COF-Supported Reduced Pd-Based Catalyst for One-Pot Reductive Amination of Aldehydes[J]. CATALYSTS,2021,11(2):13.
APA	Liu, Jianguo,Zhang, Mingyue,&Ma, Longlong.(2021).Facile Synthesis of COF-Supported Reduced Pd-Based Catalyst for One-Pot Reductive Amination of Aldehydes.CATALYSTS,11(2),13.
MLA	Liu, Jianguo,et al."Facile Synthesis of COF-Supported Reduced Pd-Based Catalyst for One-Pot Reductive Amination of Aldehydes".CATALYSTS 11.2(2021):13.

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