Facile Synthesis of COF-Supported Reduced Pd-Based Catalyst for One-Pot Reductive Amination of Aldehydes

doi:10.3390/catal11020287

GIEC OpenIR

	Facile Synthesis of COF-Supported Reduced Pd-Based Catalyst for One-Pot Reductive Amination of Aldehydes
	Liu, Jianguo 1,2; Zhang, Mingyue 1,3; Ma, Longlong1
	2021-02-01
发表期刊	CATALYSTS
卷号	11 期号:2 页码:13
通讯作者	Liu, Jianguo(liujg@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn)
摘要	Dibenzylamine motifs are an important class of crucial organic compounds and are widely used in fine chemical and pharmaceutical industries. The development of the efficient, economical, and environmentally friendly synthesis of amines using transition metal-based heterogeneous catalysts remains both desirable and challenging. Herein, we prepared the covalent organic framework (COF)-supported heterogeneous reduced COF-supported Pd-based catalyst and used it for the one-pot reductive amination of aldehydes. There are both Pd metallic state and oxidated Pd sigma+ in the catalysts. Furthermore, in the presence of the reduced COF-supported Pd-based catalyst, many aromatic, aliphatic, and heterocyclic aldehydes with various functional groups substituted were converted to their corresponding amines products in good to excellent selectivity (up to 91%) under mild reaction conditions (70 degrees C, 2 h, NH3, 20 bar H-2). This work expands the covalent organic frameworks for the material family and its support catalyst, opening up new catalytic applications in the economical, practical, and effective synthesis of secondary amines.
关键词	COF reduced COF-supported Pd-based catalyst reductive amination secondary amines
DOI	10.3390/catal11020287
收录类别	SCI
语种	英语
资助项目	National Key R&D Program of China[2018YFB1501502] ; National Natural Science Foundation of China[2018YFB1501502] ; Dalian National Laboratory Cooperation Foundation[DNL201916]
WOS研究方向	Chemistry
项目资助者	National Key R&D Program of China ; National Natural Science Foundation of China ; Dalian National Laboratory Cooperation Foundation
WOS类目	Chemistry, Physical
WOS记录号	WOS:000622293700001
出版者	MDPI
引用统计	被引频次：3[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/32648
专题	中国科学院广州能源研究所
通讯作者	Liu, Jianguo; Ma, Longlong
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangdong Key Lab New & Renewable Energy Res & De, Key Lab Renewable Energy,CAS, Guangzhou 510640, Peoples R China 2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Liu, Jianguo,Zhang, Mingyue,Ma, Longlong. Facile Synthesis of COF-Supported Reduced Pd-Based Catalyst for One-Pot Reductive Amination of Aldehydes[J]. CATALYSTS,2021,11(2):13.
APA	Liu, Jianguo,Zhang, Mingyue,&Ma, Longlong.(2021).Facile Synthesis of COF-Supported Reduced Pd-Based Catalyst for One-Pot Reductive Amination of Aldehydes.CATALYSTS,11(2),13.
MLA	Liu, Jianguo,et al."Facile Synthesis of COF-Supported Reduced Pd-Based Catalyst for One-Pot Reductive Amination of Aldehydes".CATALYSTS 11.2(2021):13.