Investigation of the nitrogen migration characteristics in sewage sludge during chemical looping gasification

doi:10.1016/j.energy.2020.119247

GIEC OpenIR

	Investigation of the nitrogen migration characteristics in sewage sludge during chemical looping gasification
	Fang, Shiwen 1,2; Deng, Zhengbing 6; Lin, Yan 2,4,5; Huang, Zhen 2,4,5; Ding, Lixing 1; Deng, Lisheng 2,3,4,5; Huang, Hongyu 2,3,4,5
	2021-02-01
发表期刊	ENERGY
ISSN	0360-5442
卷号	216 页码:11
通讯作者	Huang, Zhen(huangzhen@ms.giec.ac.cn)
摘要	Increasing attention has been given to the control of nitrogen pollutants during the process of using sewage sludge. In this paper, the gasification characteristics and the law of nitrogen migration in the process of chemical looping gasification (CLG) of sewage sludge were explored. Copper slag calcined at 1100 degrees C (1100CS), FeAl (Fe2O3+Al2O3), NiFeAl (NiFe2O4+Al2O3), and NiAl (NiO + Al2O3) were used as oxygen carrier. The addition of an oxygen carrier could increase the carbon conversion rate and decrease the low heating value. NOx precursors (HCN and NH3) were the main nitrogen-containing gas pollutants (similar to 40%). The sum yield of char nitrogen and tar nitrogen was only similar to 10%. Nitrile nitrogen, heterocyclic nitrogen and amide nitrogen were the main nitrogenous compounds in tar nitrogen. Increasing the oxidative activity of the oxygen carrier could significantly promote the oxidative transformation of N-2 from the NOx precursors, tar nitrogen, char nitrogen. Additionally, the migration of fuel nitrogen includes synchronous autothermal pyrolysis (stage I) and oxidative pyrolysis of the three-phase product under the action of [O] (stage II). Finally, this research realizes the energy utilization of sludge and reduces the release of nitrogen pollutants. (C) 2020 Elsevier Ltd. All rights reserved.
关键词	Chemical looping gasification Nitrogen migration Oxygen carrier Sewage sludge Copper slag
DOI	10.1016/j.energy.2020.119247
关键词[WOS]	COPPER SLAG ; CO-PYROLYSIS ; OXYGEN CARRIER ; FUEL-N ; BIOMASS ; CONVERSION ; STEAM ; PERFORMANCE ; COMBUSTION ; BAGASSE
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51776210] ; National Key Research and Development Program of China[2018YFB0605405] ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou)[GML2019ZD0108] ; Youth Innovation Promotion Association, CAS[2018384] ; CAS Key Laboratory of Renewable Energy[E029kf0801] ; CAS Key Laboratory of Renewable Energy[2020000022] ; Foundation and Applied Foundation Research of Guangdong Province[2019B1515120022] ; Foundation and Applied Foundation Research of Guangdong Province[2019A1515110828]
WOS研究方向	Thermodynamics ; Energy & Fuels
项目资助者	National Natural Science Foundation of China ; National Key Research and Development Program of China ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) ; Youth Innovation Promotion Association, CAS ; CAS Key Laboratory of Renewable Energy ; Foundation and Applied Foundation Research of Guangdong Province
WOS类目	Thermodynamics ; Energy & Fuels
WOS记录号	WOS:000603310100009
出版者	PERGAMON-ELSEVIER SCIENCE LTD
引用统计	被引频次：22[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/32481
专题	中国科学院广州能源研究所
通讯作者	Huang, Zhen
作者单位	1.Zhongkai Univ Agr & Engn, Coll Mech & Elect Engn, Guangzhou 510225, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 3.Southern Marine Sci & Engn Guangdong Lab Guangzho, 1119 Haibin Rd,Nansha St, Guangzhou 511458, Peoples R China 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 5.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 6.China United Engn Corp Ltd, 1060 Binan Rd, Hangzhou 310052, Peoples R China
推荐引用方式 GB/T 7714	Fang, Shiwen,Deng, Zhengbing,Lin, Yan,et al. Investigation of the nitrogen migration characteristics in sewage sludge during chemical looping gasification[J]. ENERGY,2021,216:11.
APA	Fang, Shiwen.,Deng, Zhengbing.,Lin, Yan.,Huang, Zhen.,Ding, Lixing.,...&Huang, Hongyu.(2021).Investigation of the nitrogen migration characteristics in sewage sludge during chemical looping gasification.ENERGY,216,11.
MLA	Fang, Shiwen,et al."Investigation of the nitrogen migration characteristics in sewage sludge during chemical looping gasification".ENERGY 216(2021):11.