Conversion of Glucose into 5-Hydroxymethylfurfural and Levulinic Acid Catalyzed by SO42-/ZrO2 in a Biphasic Solvent System

doi:10.1021/acs.energyfuels.0c01823

GIEC OpenIR

	Conversion of Glucose into 5-Hydroxymethylfurfural and Levulinic Acid Catalyzed by SO42-/ZrO2 in a Biphasic Solvent System
	Qu, Yang 1; Zhao, Yuan 2; Xiong, Shanshan 1; Wang, Chenguang 3; Wang, Shurong 1; Zhu, Lingjun 1; Ma, Longlong3
	2020-09-17
发表期刊	ENERGY & FUELS
ISSN	0887-0624
卷号	34 期号:9 页码:11041-11049
通讯作者	Wang, Chenguang(wangcg@ms.giec.ac.cn) ; Wang, Shurong(srwang@zju.edu.cn) ; Ma, Longlong(mall@ms.giec.ac.cn)
摘要	5-Hydroxymethylfurfural (HMF) and levulinic acid (LA) are two important platform compounds that can be produced by the dehydration of hexoses from hydrolysis of cellulose. In this study, glucose dehydration was catalyzed by the SO42-/ZrO2 catalyst in the NaCl-THF/H2O biphasic solvent system. Complete conversion of glucose was achieved at 160 degrees C. The highest HMF yield and LA yield were 61.84% and 29.68%, respectively. The results showed that the conversion and product distribution were influenced by catalyst acidity, solvent composition, temperature, and time. The SO42- load greatly changed the acidity of the catalyst, thus affecting the product distribution. By changing the composition of the catalyst and the biphasic solvent system, different yields of HMF and LA could be obtained, so as to realize directional synthesis of the target products.
DOI	10.1021/acs.energyfuels.0c01823
关键词[WOS]	HOT COMPRESSED WATER ; FURAN-DERIVATIVES ; BIOMASS ; FRUCTOSE ; LEWIS ; DEHYDRATION ; CELLULOSE ; ROUTES ; SUGARS ; OXIDE
收录类别	SCI
语种	英语
资助项目	National Key R&D Program of China[2018YFB1501500]
WOS研究方向	Energy & Fuels ; Engineering
项目资助者	National Key R&D Program of China
WOS类目	Energy & Fuels ; Engineering, Chemical
WOS记录号	WOS:000574904900052
出版者	AMER CHEMICAL SOC
引用统计	被引频次：44[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/32129
专题	中国科学院广州能源研究所
通讯作者	Wang, Chenguang; Wang, Shurong; Ma, Longlong
作者单位	1.Zhejiang Univ, State Key Lab Clean Energy Utilizat, Hangzhou 310027, Peoples R China 2.Powerchina HuaDong Engn Corp Ltd, Hangzhou 311122, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China
推荐引用方式 GB/T 7714	Qu, Yang,Zhao, Yuan,Xiong, Shanshan,et al. Conversion of Glucose into 5-Hydroxymethylfurfural and Levulinic Acid Catalyzed by SO42-/ZrO2 in a Biphasic Solvent System[J]. ENERGY & FUELS,2020,34(9):11041-11049.
APA	Qu, Yang.,Zhao, Yuan.,Xiong, Shanshan.,Wang, Chenguang.,Wang, Shurong.,...&Ma, Longlong.(2020).Conversion of Glucose into 5-Hydroxymethylfurfural and Levulinic Acid Catalyzed by SO42-/ZrO2 in a Biphasic Solvent System.ENERGY & FUELS,34(9),11041-11049.
MLA	Qu, Yang,et al."Conversion of Glucose into 5-Hydroxymethylfurfural and Levulinic Acid Catalyzed by SO42-/ZrO2 in a Biphasic Solvent System".ENERGY & FUELS 34.9(2020):11041-11049.