Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC-MS/MS

doi:10.1021/acsomega.0c03169

GIEC OpenIR

	Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC-MS/MS
	Shi, Ning 1,2,3; Liu, Qiying1,2 ; Liu, Ying 3; Chen, Lijun 3; Zhang, Hongyan 3; Huang, Hongsheng 3; Ma, Longlong1,2
	2020-09-15
发表期刊	ACS OMEGA
ISSN	2470-1343
卷号	5 期号:36 页码:23322-23333
通讯作者	Shi, Ning(shining@git.edu.cn)
摘要	To reveal the hydrothermal conversion routes of the biomass-derived furanic compounds, the soluble products formed during the hydrothermal conversion of 5-hydroxymethylfurfural (HMF), furfural, and furfuryl alcohol were analyzed by liquid chromatography-mass spectrometry (LC-MS) and LC-MS/MS. Multiple carbocyclic compounds containing hydroxy group and carbonyl group were detected, with a molecular mass in the range of 154-272 Da and carbon chain of the length 8-15. The formation of these soluble carbocyclic compounds was proposed to involve hydrolytic ring-opening of the furanic ring, intermolecular aldol condensation, intramolecular aldol condensation, and C-C cleavage reaction. The C-C cleavage reaction was proposed to occur on the dicarbonyl structure of the formed primary polymers.
DOI	10.1021/acsomega.0c03169
关键词[WOS]	MAILLARD REACTION CASCADE ; CARBOXYLIC-ACIDS ; SUGAR FRAGMENTATION ; LEVULINIC ACID ; LACTIC-ACID ; HUMINS ; DEGRADATION ; CELLULOSE ; CATALYST ; MECHANISM
收录类别	SCI
语种	英语
资助项目	Natural Science Foundation of Guizhou Province[QiankeheJichu [2020] 1Y239] ; High Level Scientific Research Funding Project of Guizhou Institute of Technology[XJGC20190636] ; Academic New Seedling Plan Project of Guizhou Institute of Technology[QianKeHe [2017]5789-08] ; Natural Science Foundation of Guizhou Provincial Department of Education[Qianjiaohe KY Zi [2016]014]
WOS研究方向	Chemistry
项目资助者	Natural Science Foundation of Guizhou Province ; High Level Scientific Research Funding Project of Guizhou Institute of Technology ; Academic New Seedling Plan Project of Guizhou Institute of Technology ; Natural Science Foundation of Guizhou Provincial Department of Education
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000572832600069
出版者	AMER CHEMICAL SOC
引用统计	被引频次：8[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/32066
专题	中国科学院广州能源研究所
通讯作者	Shi, Ning
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 3.Guizhou Inst Technol, Sch Chem Engn, Guiyang 550003, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Shi, Ning,Liu, Qiying,Liu, Ying,et al. Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC-MS/MS[J]. ACS OMEGA,2020,5(36):23322-23333.
APA	Shi, Ning.,Liu, Qiying.,Liu, Ying.,Chen, Lijun.,Zhang, Hongyan.,...&Ma, Longlong.(2020).Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC-MS/MS.ACS OMEGA,5(36),23322-23333.
MLA	Shi, Ning,et al."Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC-MS/MS".ACS OMEGA 5.36(2020):23322-23333.