Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC-MS/MS

doi:10.1021/acsomega.0c03169

GIEC OpenIR

	Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC-MS/MS
	Shi, Ning 1,2,3; Liu, Qiying1,2 ; Liu, Ying 3; Chen, Lijun 3; Zhang, Hongyan 3; Huang, Hongsheng 3; Ma, Longlong1,2
	2020-09-15
Source Publication	ACS OMEGA
ISSN	2470-1343
Volume	5 Issue:36 Pages:23322-23333
Corresponding Author	Shi, Ning(shining@git.edu.cn)
Abstract	To reveal the hydrothermal conversion routes of the biomass-derived furanic compounds, the soluble products formed during the hydrothermal conversion of 5-hydroxymethylfurfural (HMF), furfural, and furfuryl alcohol were analyzed by liquid chromatography-mass spectrometry (LC-MS) and LC-MS/MS. Multiple carbocyclic compounds containing hydroxy group and carbonyl group were detected, with a molecular mass in the range of 154-272 Da and carbon chain of the length 8-15. The formation of these soluble carbocyclic compounds was proposed to involve hydrolytic ring-opening of the furanic ring, intermolecular aldol condensation, intramolecular aldol condensation, and C-C cleavage reaction. The C-C cleavage reaction was proposed to occur on the dicarbonyl structure of the formed primary polymers.
DOI	10.1021/acsomega.0c03169
WOS Keyword	MAILLARD REACTION CASCADE ; CARBOXYLIC-ACIDS ; SUGAR FRAGMENTATION ; LEVULINIC ACID ; LACTIC-ACID ; HUMINS ; DEGRADATION ; CELLULOSE ; CATALYST ; MECHANISM
Indexed By	SCI
Language	英语
Funding Project	Natural Science Foundation of Guizhou Province[QiankeheJichu [2020] 1Y239] ; High Level Scientific Research Funding Project of Guizhou Institute of Technology[XJGC20190636] ; Academic New Seedling Plan Project of Guizhou Institute of Technology[QianKeHe [2017]5789-08] ; Natural Science Foundation of Guizhou Provincial Department of Education[Qianjiaohe KY Zi [2016]014]
WOS Research Area	Chemistry
Funding Organization	Natural Science Foundation of Guizhou Province ; High Level Scientific Research Funding Project of Guizhou Institute of Technology ; Academic New Seedling Plan Project of Guizhou Institute of Technology ; Natural Science Foundation of Guizhou Provincial Department of Education
WOS Subject	Chemistry, Multidisciplinary
WOS ID	WOS:000572832600069
Publisher	AMER CHEMICAL SOC
Citation statistics	Cited Times:9[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.giec.ac.cn/handle/344007/32066
Collection	中国科学院广州能源研究所
Corresponding Author	Shi, Ning
Affiliation	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 3.Guizhou Inst Technol, Sch Chem Engn, Guiyang 550003, Peoples R China
First Author Affilication	GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation GB/T 7714	Shi, Ning,Liu, Qiying,Liu, Ying,et al. Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC-MS/MS[J]. ACS OMEGA,2020,5(36):23322-23333.
APA	Shi, Ning.,Liu, Qiying.,Liu, Ying.,Chen, Lijun.,Zhang, Hongyan.,...&Ma, Longlong.(2020).Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC-MS/MS.ACS OMEGA,5(36),23322-23333.
MLA	Shi, Ning,et al."Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC-MS/MS".ACS OMEGA 5.36(2020):23322-23333.

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