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In Situ Synthesis of Cu Nanoparticles on Carbon for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol by Using Pomelo Peel as the Carbon Source
Wang, Chenguang1,2; Liu, Yong3; Cui, Zhibing4; Yu, Xiaohu5; Zhang, Xinghua1,2; Li, Yuping1,2; Zhang, Qi1,2; Chen, Lungang1,2; Ma, Longlong1,2
2020-08-31
发表期刊ACS SUSTAINABLE CHEMISTRY & ENGINEERING
ISSN2168-0485
卷号8期号:34页码:12944-12955
通讯作者Chen, Lungang(chenlg1981@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn)
摘要A facile approach was developed to directly synthesize carbon-supported metal nanoparticles with pomelo peel as the carbon source and metal nitrate solution as the metal source. Fe/C, Co/C, Ni/C, and Cu/C catalysts were prepared after calcination in N-2 without further reduction. The metal nanoparticles and formation mechanism were investigated by multiple techniques such as XRD, HRTEM, XPS, FTIR spectra, SEM, and TG-MS thermal analysis. In the case of furfural hydrogenation, Cu/C catalyst exhibited the best activity and exclusive selectivity to produce furfuryl alcohol with complete conversion, and excellent selectivity can be maintained at a higher temperature of 240 degrees C. The particle size of Cu nanoparticles can be tuned by the calcination temperature and metal loading for improving catalytic activity. The excellent performance of Cu nanoparticles was also studied by density functional theory calculation, agreeing well with the experiments.
关键词furfural hydrogenation Cu nanoparticles furfuryl alcohol pomelo peel DFT
DOI10.1021/acssuschemeng.0c03505
关键词[WOS]LIQUID-PHASE HYDROGENATION ; CATALYTIC TRANSFER HYDROGENATION ; BIOMASS ; NI ; CONVERSION ; TRANSFORMATION ; 2-METHYLFURAN ; ACTIVATION ; ROUTES ; METAL
收录类别SCI
语种英语
资助项目National Key R&D Program of China[2019YFD1100601] ; National Natural Science Foundation of China[21878290] ; Natural Science Foundation of Guangdong Province[2017A030313073]
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Engineering
项目资助者National Key R&D Program of China ; National Natural Science Foundation of China ; Natural Science Foundation of Guangdong Province
WOS类目Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical
WOS记录号WOS:000567778600023
出版者AMER CHEMICAL SOC
引用统计
被引频次:54[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/32015
专题中国科学院广州能源研究所
通讯作者Chen, Lungang; Ma, Longlong
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China
2.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China
3.Univ New Hampshire, Dept Chem Engn, Durham, NH 03824 USA
4.Zhengzhou Univ, Sch Chem Engn & Energy, Zhengzhou 450001, Peoples R China
5.Shaanxi Univ Technol, Sch Chem & Environm Sci, Inst Theoret & Computat Chem, Shaanxi Key Lab Catalysis, Hanzhong 723000, Peoples R China
第一作者单位中国科学院广州能源研究所
推荐引用方式
GB/T 7714
Wang, Chenguang,Liu, Yong,Cui, Zhibing,et al. In Situ Synthesis of Cu Nanoparticles on Carbon for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol by Using Pomelo Peel as the Carbon Source[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2020,8(34):12944-12955.
APA Wang, Chenguang.,Liu, Yong.,Cui, Zhibing.,Yu, Xiaohu.,Zhang, Xinghua.,...&Ma, Longlong.(2020).In Situ Synthesis of Cu Nanoparticles on Carbon for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol by Using Pomelo Peel as the Carbon Source.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,8(34),12944-12955.
MLA Wang, Chenguang,et al."In Situ Synthesis of Cu Nanoparticles on Carbon for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol by Using Pomelo Peel as the Carbon Source".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 8.34(2020):12944-12955.
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