Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| In Situ Synthesis of Cu Nanoparticles on Carbon for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol by Using Pomelo Peel as the Carbon Source | |
Wang, Chenguang1,2; Liu, Yong3; Cui, Zhibing4; Yu, Xiaohu5; Zhang, Xinghua1,2 ; Li, Yuping1,2; Zhang, Qi1,2; Chen, Lungang1,2; Ma, Longlong1,2
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| 2020-08-31 | |
| Source Publication | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
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| ISSN | 2168-0485 |
| Volume | 8Issue:34Pages:12944-12955 |
| Corresponding Author | Chen, Lungang(chenlg1981@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn) |
| Abstract | A facile approach was developed to directly synthesize carbon-supported metal nanoparticles with pomelo peel as the carbon source and metal nitrate solution as the metal source. Fe/C, Co/C, Ni/C, and Cu/C catalysts were prepared after calcination in N-2 without further reduction. The metal nanoparticles and formation mechanism were investigated by multiple techniques such as XRD, HRTEM, XPS, FTIR spectra, SEM, and TG-MS thermal analysis. In the case of furfural hydrogenation, Cu/C catalyst exhibited the best activity and exclusive selectivity to produce furfuryl alcohol with complete conversion, and excellent selectivity can be maintained at a higher temperature of 240 degrees C. The particle size of Cu nanoparticles can be tuned by the calcination temperature and metal loading for improving catalytic activity. The excellent performance of Cu nanoparticles was also studied by density functional theory calculation, agreeing well with the experiments. |
| Keyword | furfural hydrogenation Cu nanoparticles furfuryl alcohol pomelo peel DFT |
| DOI | 10.1021/acssuschemeng.0c03505 |
| WOS Keyword | LIQUID-PHASE HYDROGENATION ; CATALYTIC TRANSFER HYDROGENATION ; BIOMASS ; NI ; CONVERSION ; TRANSFORMATION ; 2-METHYLFURAN ; ACTIVATION ; ROUTES ; METAL |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Key R&D Program of China[2019YFD1100601] ; National Natural Science Foundation of China[21878290] ; Natural Science Foundation of Guangdong Province[2017A030313073] |
| WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Engineering |
| Funding Organization | National Key R&D Program of China ; National Natural Science Foundation of China ; Natural Science Foundation of Guangdong Province |
| WOS Subject | Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical |
| WOS ID | WOS:000567778600023 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/32015 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Chen, Lungang; Ma, Longlong |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 2.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 3.Univ New Hampshire, Dept Chem Engn, Durham, NH 03824 USA 4.Zhengzhou Univ, Sch Chem Engn & Energy, Zhengzhou 450001, Peoples R China 5.Shaanxi Univ Technol, Sch Chem & Environm Sci, Inst Theoret & Computat Chem, Shaanxi Key Lab Catalysis, Hanzhong 723000, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Wang, Chenguang,Liu, Yong,Cui, Zhibing,et al. In Situ Synthesis of Cu Nanoparticles on Carbon for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol by Using Pomelo Peel as the Carbon Source[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2020,8(34):12944-12955. |
| APA | Wang, Chenguang.,Liu, Yong.,Cui, Zhibing.,Yu, Xiaohu.,Zhang, Xinghua.,...&Ma, Longlong.(2020).In Situ Synthesis of Cu Nanoparticles on Carbon for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol by Using Pomelo Peel as the Carbon Source.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,8(34),12944-12955. |
| MLA | Wang, Chenguang,et al."In Situ Synthesis of Cu Nanoparticles on Carbon for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol by Using Pomelo Peel as the Carbon Source".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 8.34(2020):12944-12955. |
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