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Ultrafast Glycerol Conversion to Lactic Acid over Magnetically Recoverable Ni-NiOx@C Catalysts
Xiu, Zhongxun2,4,5; Wang, Haiyong2,3,4; Cai, Chiliu2,3,4; Li, Changzhi1; Yan, Long2,3,4; Wang, Chenguang2,3,4; Li, Wenzhi6; Xin, Haosheng2,3,4,7; Zhu, Changhui2,3,4,7; Zhang, Qi2,3,4; Liu, Qiying1,2,3; Ma, Longlong2,3,4
2020-05-27
Source PublicationINDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN0888-5885
Volume59Issue:21Pages:9912-9925
Corresponding AuthorLi, Changzhi(licz@dicp.ac.cn) ; Liu, Qiying(liuqy@ms.giec.ac.cn)
AbstractLactic acid (LA), a key platform chemical from biomass, is an ideal feedstock for biodegradable plastic synthesis. The conversion of glycerol to LA was investigated over graphiticcarbon-layer-encapsulated Ni-NiOx core/shell (Ni-NiOx@C) catalysts, which were prepared by controlled oxidation from pristine Ni@C. The oxidation temperature greatly influenced the percentage of NiOx and thus the amount of Lewis acid. In the conversion of glycerol, the catalyst oxidized at 200 degrees C provided hitherto the highest LA formation rate (5.67 mol/(m(3).g(cat).s)), which is at least 15 times faster than those obtained over the reported Cu and noble metal catalysts under comparable reaction conditions. The excellent performance of Ni-NiOx@C was attributed to the synergistic effect of the homogenous base, metallic Ni, and acidic NiOx sites, which accelerates the bond cleavage of alpha-C-H and C-O and promotes ultrafast formation of LA within 30 min.
DOI10.1021/acs.iecr.0c01145
WOS KeywordSELECTIVE OXIDATION ; CARBON ; DEHYDROGENATION ; HYDROGENOLYSIS ; NANOPARTICLES ; SITES ; PRETREATMENT ; LIGNIN ; NICKEL ; GROWTH
Indexed BySCI
Language英语
Funding ProjectNational Key R&D Program of China[2018YFB1501402] ; National Natural Science Foundation of China[51976220] ; National Natural Science Foundation of China[51536009] ; National Natural Science Foundation of China[51876209] ; Natural Science Foundation of Guangdong Province[2017A030308010] ; DNL Cooperation Fund, CAS[DNL180302] ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N092]
WOS Research AreaEngineering
Funding OrganizationNational Key R&D Program of China ; National Natural Science Foundation of China ; Natural Science Foundation of Guangdong Province ; DNL Cooperation Fund, CAS ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program
WOS SubjectEngineering, Chemical
WOS IDWOS:000537733800017
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:23[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/27212
Collection中国科学院广州能源研究所
Corresponding AuthorLi, Changzhi; Liu, Qiying
Affiliation1.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Peoples R China
4.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China
5.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China
6.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Lab Basic Res Biomass Convers & Utilizat, Hefei 230026, Peoples R China
7.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Xiu, Zhongxun,Wang, Haiyong,Cai, Chiliu,et al. Ultrafast Glycerol Conversion to Lactic Acid over Magnetically Recoverable Ni-NiOx@C Catalysts[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2020,59(21):9912-9925.
APA Xiu, Zhongxun.,Wang, Haiyong.,Cai, Chiliu.,Li, Changzhi.,Yan, Long.,...&Ma, Longlong.(2020).Ultrafast Glycerol Conversion to Lactic Acid over Magnetically Recoverable Ni-NiOx@C Catalysts.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,59(21),9912-9925.
MLA Xiu, Zhongxun,et al."Ultrafast Glycerol Conversion to Lactic Acid over Magnetically Recoverable Ni-NiOx@C Catalysts".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 59.21(2020):9912-9925.
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