One-pot hydrodeoxygenation of biomass furan derivatives into decane under mild conditions over Pd/C combined with phosphotungstic acid

doi:10.1039/d0gc00428f

GIEC OpenIR

	One-pot hydrodeoxygenation of biomass furan derivatives into decane under mild conditions over Pd/C combined with phosphotungstic acid
	Li, Song 1,2,3,4; Yan, Long 1,2,3; Liu, Qiying1,2,3 ; Liu, Jianguo 1,2,3; Liu, Qiyu 5; Fan, Wei 5; Zhao, Xuelai 6; Zhang, Xinghua1,2,3 ; Wang, Chenguang 1,2,3; Ma, Longlong1,2,3 ; Zhang, Qi1,2,3
	2020-05-07
发表期刊	GREEN CHEMISTRY
ISSN	1463-9262
卷号	22 期号:9 页码:2889-2900
通讯作者	Yan, Long(yanlong@ms.giec.ac.cn) ; Zhang, Qi(zhangqi@ms.giec.ac.cn)
摘要	One-pot hydrodeoxygenation (HDO) of biomass furan derivatives into long-chain alkanes remains unclear owing to the complicated reactions at high temperatures. Here, Pd/C combined with phosphotungstic acid (HPW), a strong Bronsted solid acid promoter, was developed to produce decane under mild conditions through the one-pot HDO of delta-furfurylidenelevulinic acid (FDLA). A 93.16% sum yield of alkanes including 89.53% yield of decane was obtained under 3 MPa H-2 at 170 degrees C for 4 h. The ring-opening and HDO of furans are accomplished at preheating stage, which enable to clarify the complicated reaction pathway. In addition, experimental validations and catalytic characterizations confirm that the synergistic effect of active acid-metal sites plays a critical role in the generation of alkanes via the formation and hydrogenolysis of lactone intermediates to aldehyde/alcohol. This work provides guidance for the one-pot HDO of biomass furan derivatives via the combination of metal catalyst and strong Bronsted solid acid under mild conditions.
DOI	10.1039/d0gc00428f
关键词[WOS]	FUEL RANGE ALKANES ; LEVULINIC ACID ; HETEROPOLY ACID ; BIFUNCTIONAL CATALYSTS ; LIQUID ALKANES ; CONVERSION ; CELLULOSE ; PLATFORM ; DIESEL ; DEOXYGENATION
收录类别	SCI
语种	英语
资助项目	National Key R&D Program of China[2017YFE0106600] ; National Natural Science Foundation of China[51876209] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA21060102] ; Natural Science Foundation of Guangdong Province[2017A030308010]
WOS研究方向	Chemistry ; Science & Technology - Other Topics
项目资助者	National Key R&D Program of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Natural Science Foundation of Guangdong Province
WOS类目	Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology
WOS记录号	WOS:000533979200022
出版者	ROYAL SOC CHEMISTRY
引用统计	被引频次：25[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/27135
专题	中国科学院广州能源研究所
通讯作者	Yan, Long; Zhang, Qi
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 5.Univ Massachusetts, Dept Chem Engn, 159 Goessman Lab,686 N Pleasant St, Amherst, MA 01003 USA 6.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 233022, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Li, Song,Yan, Long,Liu, Qiying,et al. One-pot hydrodeoxygenation of biomass furan derivatives into decane under mild conditions over Pd/C combined with phosphotungstic acid[J]. GREEN CHEMISTRY,2020,22(9):2889-2900.
APA	Li, Song.,Yan, Long.,Liu, Qiying.,Liu, Jianguo.,Liu, Qiyu.,...&Zhang, Qi.(2020).One-pot hydrodeoxygenation of biomass furan derivatives into decane under mild conditions over Pd/C combined with phosphotungstic acid.GREEN CHEMISTRY,22(9),2889-2900.
MLA	Li, Song,et al."One-pot hydrodeoxygenation of biomass furan derivatives into decane under mild conditions over Pd/C combined with phosphotungstic acid".GREEN CHEMISTRY 22.9(2020):2889-2900.