Catalytic Production of Oxygenated and Hydrocarbon Chemicals From Cellulose Hydrogenolysis in Aqueous Phase

doi:10.3389/fchem.2020.00333

GIEC OpenIR

	Catalytic Production of Oxygenated and Hydrocarbon Chemicals From Cellulose Hydrogenolysis in Aqueous Phase
	Xin, Haosheng 1,2,3,4; Hu, Xiaohong 1,2,3,4; Cai, Chiliu1,2,3 ; Wang, Haiyong 1,2,3; Zhu, Changhui 1,2,3,4; Li, Song 1,2,3,4; Xiu, Zhongxun 5; Zhang, Xinghua1,2,3 ; Liu, Qiying1,2,3,6 ; Ma, Longlong1,2,3
	2020-05-05
发表期刊	FRONTIERS IN CHEMISTRY
ISSN	2296-2646
卷号	8 页码:20
通讯作者	Liu, Qiying(liuqy@ms.giec.ac.cn)
摘要	As the most abundant polysaccharide in lignocellulosic biomass, a clean and renewable carbon resource, cellulose shows huge capacity and roused much attention on the methodologies of its conversion to downstream products, mainly including platform chemicals and fuel additives. Without appropriate treatments in the processes of cellulose decompose, there are some by-products that may not be chemically valuable or even truly harmful. Therefore, higher selectivity and more economical and greener processes would be favored and serve as criteria in a correlational study. Aqueous phase, an economically accessible and immensely potential reaction system, has been widely studied in the preparation of downstream products of cellulose. Accordingly, this mini-review aims at making a related summary about several conversion pathways of cellulose to target products in aqueous phase. Mainly, there are four categories about the conversion of cellulose to downstream products in the following: (i) cellulose hydrolysis hydrogenation to saccharides and sugar alcohols, like glucose, sorbitol, mannose, etc.; (ii) selective hydrogenolysis leads to the cleavage of the corresponding glucose C-C and C-O bond, like ethylene glycol (EG), 1,2-propylene glycol (PG), etc.; (iii) dehydration of fructose and further oxidation, like 5-hydroxymethylfurfural (HMF), 2,5-furandicarboxylic acid (FDCA), etc.; and (iv) production of liquid alkanes via hydrogenolysis and hydrodeoxygenation, like pentane, hexane, etc. The representative products were enumerated, and the mechanism and pathway of mentioned reaction are also summarized in a brief description. Ultimately, the remaining challenges and possible further research objects are proposed in perspective to provide researchers with a lucid research direction.
关键词	cellulose hydrolysis hydrogenolysis biorefinery catalysis aqueous phase
DOI	10.3389/fchem.2020.00333
关键词[WOS]	ONE-POT CONVERSION ; HOT COMPRESSED WATER ; ETHYLENE-GLYCOL ; BIMETALLIC CATALYSTS ; BIOMASS CONVERSION ; ZINC-CHLORIDE ; IONIC LIQUID ; LIGNOCELLULOSIC BIOMASS ; GLUCOSE ISOMERIZATION ; HIGH-TEMPERATURE
收录类别	SCI
语种	英语
资助项目	National Key R&D Program of China[2018YFB1501402] ; National Science Foundation of China[51976220] ; National Science Foundation of China[51576199] ; Natural Science Foundation of Guangdong Province[2017A030308010] ; DNL Cooperation Fund, CAS[DNL180302] ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences[XDA21060102]
WOS研究方向	Chemistry
项目资助者	National Key R&D Program of China ; National Science Foundation of China ; Natural Science Foundation of Guangdong Province ; DNL Cooperation Fund, CAS ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000536363500001
出版者	FRONTIERS MEDIA SA
引用统计	被引频次：16[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/27132
专题	中国科学院广州能源研究所
通讯作者	Liu, Qiying
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou, Peoples R China 4.Univ Chinese Acad Sci, Beijing, Peoples R China 5.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou, Peoples R China 6.Dalian Natl Lab Clean Energy, Dalian, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Xin, Haosheng,Hu, Xiaohong,Cai, Chiliu,et al. Catalytic Production of Oxygenated and Hydrocarbon Chemicals From Cellulose Hydrogenolysis in Aqueous Phase[J]. FRONTIERS IN CHEMISTRY,2020,8:20.
APA	Xin, Haosheng.,Hu, Xiaohong.,Cai, Chiliu.,Wang, Haiyong.,Zhu, Changhui.,...&Ma, Longlong.(2020).Catalytic Production of Oxygenated and Hydrocarbon Chemicals From Cellulose Hydrogenolysis in Aqueous Phase.FRONTIERS IN CHEMISTRY,8,20.
MLA	Xin, Haosheng,et al."Catalytic Production of Oxygenated and Hydrocarbon Chemicals From Cellulose Hydrogenolysis in Aqueous Phase".FRONTIERS IN CHEMISTRY 8(2020):20.