Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Ni supported on the CaO modified attapulgite as catalysts for hydrogen production from glycerol steam reforming | |
Feng, P.1; Huang, K.2; Xu, Q.1,2; Qi, W.3; Xin, S.4; Wei, T.1; Liao, L.1; Yan, Y.1 | |
2020-03-18 | |
发表期刊 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY |
ISSN | 0360-3199 |
卷号 | 45期号:15页码:8223-8233 |
通讯作者 | Xu, Q.(xuqingli@ecust.edu.cn) ; Qi, W.(qiwei@ms.giec.ac.cn) |
摘要 | The Ni catalyst supported on CaO-modified attapulgite (CaO-ATP) were synthesized by wet impregnation method at a constant Ni metal loading (10 wt%). The catalyst was tested by carrying out a glycerin steam reforming reaction under the following conditions: 400-800 degrees C, W/G is 3, GHSV is 1 h(-1). Ni-CaO-ATP exhibited the highest hydrogen yield (85.30%) and glycerol conversion (93.71%) at 600 degrees C. The catalysts were characterized by N-2 adsorption/desorption, BET, XRD, H-2-TPR, TG and SEM. The results show that ATP has good resistance to carbon deposition. As an attapulgite modifier of Ni-CaO-ATP, CaO promotes the dispersion of the active component nickel species, which would promote the water gas shift reaction, leading to the improving of hydrogen yield. In addition, the addition of Ca would further enhance the inhibition of carbon deposition and prolong the life of the Ni -CaO-ATP catalyst. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved. |
关键词 | Hydrogen Steam reforming Attapulgite Ni catalysts CaO |
DOI | 10.1016/j.ijhydene.2020.01.013 |
关键词[WOS] | RU-BASED CATALYSTS ; NI/ATTAPULGITE CATALYSTS ; BIODIESEL PRODUCTION ; BIO-OIL ; TEMPERATURE ; ETHANOL ; PRETREATMENT ; GENERATION ; ACID ; CO |
收录类别 | SCI |
语种 | 英语 |
资助项目 | National Natural Science Foundation of China[21376084] ; Guangxi Key Laboratory of Bio-refinery[GXKLB19-03] ; Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development[Y909kn1001] |
WOS研究方向 | Chemistry ; Electrochemistry ; Energy & Fuels |
项目资助者 | National Natural Science Foundation of China ; Guangxi Key Laboratory of Bio-refinery ; Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development |
WOS类目 | Chemistry, Physical ; Electrochemistry ; Energy & Fuels |
WOS记录号 | WOS:000523643400019 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/27050 |
专题 | 中国科学院广州能源研究所 |
通讯作者 | Xu, Q.; Qi, W. |
作者单位 | 1.East China Univ Sci & Technol, Res Ctr Biomass Energy, Key Lab Coal Gasificat & Energy Chem Engn, Minist Educ, Shanghai, Peoples R China 2.Guangxi Acad Sci, Natl Engn Res Ctr Nonfood Biorefinery, Guangxi Key Lab Biorefinery, Nanning, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou, Peoples R China 4.Jianghan Univ, Hubei Key Lab Ind Fume & Dust Pollut Control, Wuhan, Peoples R China |
推荐引用方式 GB/T 7714 | Feng, P.,Huang, K.,Xu, Q.,et al. Ni supported on the CaO modified attapulgite as catalysts for hydrogen production from glycerol steam reforming[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2020,45(15):8223-8233. |
APA | Feng, P..,Huang, K..,Xu, Q..,Qi, W..,Xin, S..,...&Yan, Y..(2020).Ni supported on the CaO modified attapulgite as catalysts for hydrogen production from glycerol steam reforming.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,45(15),8223-8233. |
MLA | Feng, P.,et al."Ni supported on the CaO modified attapulgite as catalysts for hydrogen production from glycerol steam reforming".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 45.15(2020):8223-8233. |
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