Aromatics production from fast co-pyrolysis of lignin and waste cooking oil catalyzed by HZSM-5 zeolite

doi:10.1016/j.apenergy.2020.114629

GIEC OpenIR

	Aromatics production from fast co-pyrolysis of lignin and waste cooking oil catalyzed by HZSM-5 zeolite
	Fan, Liangliang 1,2; Ruan, Roger 3,4; Li, Jun 1,2; Ma, Longlong5,6 ; Wang, Chenguang 5,6; Zhou, Wenguang 1,2
	2020-04-01
发表期刊	APPLIED ENERGY
ISSN	0306-2619
卷号	263 页码:11
通讯作者	Wang, Chenguang(wangcg@ms.giec.ac.cn) ; Zhou, Wenguang(wgzhou@ncu.edu.cn)
摘要	Lignin and waste cooking oil are wastes from paper and food industries, respectively. In this work, the catalytic fast co-pyrolysis of lignin and waste cooking oil for the production of aromatics in a pyroprobe was investigated with an aim to improve the utilization of lignin waste and waste cooking oil. Furthermore, lignin-derived monomers, including phenol, o-cresol, and guaiacol, were also used as model feedstock for the catalytic co-pyrolysis in order to study the mechanism underlying aromatic formation. The mechanistic study helped lay theoretical foundation for the industrial application of the co-pyrolysis process. The effects of catalyst and waste cooking oil addition on co-pyrolysis product fractional yield and selectivity were studied. High amount of waste cooking oil in the feedstock with appropriate catalyst-to-feedstock ratio (3:1) contributed to high peak-area yields of the total detected compounds and aromatics. The alkylation and demethoxylation of phenols were enhanced at high ratios of catalyst to feedstock and waste cooking oil to lignin. When the ratio of waste cooking oil to lignin was 1:1, the highest mono-aromatic selectivity (82.6%) and synergistic extent (52.1%) for mono-aromatic production were obtained. The catalytic co-pyrolysis of the lignin-derived monomers and waste cooking oil showed that guaiacol was the most active compound to be converted to aromatics, followed by o-cresol, and phenol. The reaction mechanism underlying the formation of aromatics from the synergistic conversion of aliphatics and phenolics was elaborated.
关键词	Lignin Waste cooking oil Catalytic co-pyrolysis Aromatics Lignin-derived model compounds Catalytic mechanism
DOI	10.1016/j.apenergy.2020.114629
关键词[WOS]	LOW-DENSITY POLYETHYLENE ; BIO-OIL ; LIGNOCELLULOSIC BIOMASS ; MICROWAVE PYROLYSIS ; PARTICLE-SIZE ; SOYBEAN OIL ; HYDRODEOXYGENATION ; PLASTICS ; FUEL ; HYDROCARBONS
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51906096] ; National Natural Science Foundation of China[21466022] ; National Natural Science Foundation of China[21766019] ; Key Research and Development Program of Jiangxi Province[20161BBF60057] ; Key Research and Development Program of Jiangxi Province[20171BBF60023] ; Key Research and Development Program of Jiangxi Province[GCXZ2014-124]
WOS研究方向	Energy & Fuels ; Engineering
项目资助者	National Natural Science Foundation of China ; Key Research and Development Program of Jiangxi Province
WOS类目	Energy & Fuels ; Engineering, Chemical
WOS记录号	WOS:000520402600012
出版者	ELSEVIER SCI LTD
引用统计	被引频次：67[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/26849
专题	中国科学院广州能源研究所
通讯作者	Wang, Chenguang; Zhou, Wenguang
作者单位	1.Nanchang Univ, Sch Resources Environm & Chem Engn, Minist Educ, 999 Xuefu Ave, Nanchang 330031, Jiangxi, Peoples R China 2.Nanchang Univ, Key Lab Poyang Lake Environm & Resource Utilizat, Minist Educ, 999 Xuefu Ave, Nanchang 330031, Jiangxi, Peoples R China 3.Univ Minnesota, Ctr Biorefining, 1390 Eckles Ave, St Paul, MN 55108 USA 4.Univ Minnesota, Dept Bioprod & Biosyst Engn, 1390 Eckles Ave, St Paul, MN 55108 USA 5.Chinese Acad Sci, Key Lab Renewable Energy, 2 Nengyuan R, Guangzhou 510640, Guangdong, Peoples R China 6.Chinese Acad Sci, Guangzhou Inst Energy Convers, 2 Nengyuan R, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式 GB/T 7714	Fan, Liangliang,Ruan, Roger,Li, Jun,et al. Aromatics production from fast co-pyrolysis of lignin and waste cooking oil catalyzed by HZSM-5 zeolite[J]. APPLIED ENERGY,2020,263:11.
APA	Fan, Liangliang,Ruan, Roger,Li, Jun,Ma, Longlong,Wang, Chenguang,&Zhou, Wenguang.(2020).Aromatics production from fast co-pyrolysis of lignin and waste cooking oil catalyzed by HZSM-5 zeolite.APPLIED ENERGY,263,11.
MLA	Fan, Liangliang,et al."Aromatics production from fast co-pyrolysis of lignin and waste cooking oil catalyzed by HZSM-5 zeolite".APPLIED ENERGY 263(2020):11.