Gas fuel production derived from pine sawdust pyrolysis catalyzed on alumina

doi:10.1002/apj.2456

GIEC OpenIR

	Gas fuel production derived from pine sawdust pyrolysis catalyzed on alumina
	Liu, Peng 1; Wang, Yue 1; Zhou, Zhengzhong 1; Yuan, Haoran1,2 ; Zheng, Tao 2
	2020-03-20
发表期刊	ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING
ISSN	1932-2135
页码	11
通讯作者	Zhou, Zhengzhong(zhouzhengzhong@cczu.edu.cn) ; Yuan, Haoran(yuanhaoran81@gmail.com)
摘要	Pyrolysis gas release behaviour, including hydrogen, CH4, CO and CO2 from pine pyrolysis, is collected from fixed bed reactor and analyzed by gas chromatography (GC). Pyrolysis tar composition is monitored using GC coupled with a mass spectrometer (GC-MS). The gas generation mechanism of catalytic pyrolysis on alumina is elaborated. The carbon structure of char is quantitatively determined by carbon-13 nuclear magnetic resonance (C-13-NMR) using curve-fitting methods. The results show influence of alumina on gas fuel production is mainly embodied in absorption and catalytic effect. Steam reforming reaction to gas fuel is accelerated with alumina added during pine pyrolysis. Alumina addition accelerates the decomposition of carbonate and side chains of aromatic ring in lignin below 500 degrees C and prolong the residence time of second pyrolysis. The CH4 release rate reaches to peak value at 500 degrees C during pyrolysis. The H-2 increases from 98.95 to 120.19 ml/g with mass ratio of 1/4 (alumina/pine). The CO release rate has a certain increment with the alumina added. These data are the foundation for putting forward a new direction for the reuse of organic and industrial solid wastes enriched with alumina to achieve the goal on energy regeneration.
关键词	alumina carbon structure catalytic pyrolysis gas fuel production
DOI	10.1002/apj.2456
关键词[WOS]	BIOMASS PYROLYSIS ; LIGNOCELLULOSIC BIOMASS ; BIO-OIL ; NICKEL ; GASIFICATION ; TAR ; HEMICELLULOSE ; TEMPERATURE ; CELLULOSE ; REACTOR
收录类别	SCI
语种	英语
资助项目	Changzhou applied basic research plan[CJ20190081] ; National Natural Science Foundation of China[51906021] ; National Natural Science Foundation of China[51703014] ; Natural Science Foundation of Colleges in Jiangsu Province[19KJB480005] ; Changzhou University[ZMF17020034] ; Research Foundation for Advanced Talents of Jiangsu University[19KJB480005] ; Research Foundation for Advanced Talents of Jiangsu University[16JDG022] ; National Key R&D Program of China[2018YFC1901203]
WOS研究方向	Engineering
项目资助者	Changzhou applied basic research plan ; National Natural Science Foundation of China ; Natural Science Foundation of Colleges in Jiangsu Province ; Changzhou University ; Research Foundation for Advanced Talents of Jiangsu University ; National Key R&D Program of China
WOS类目	Engineering, Chemical
WOS记录号	WOS:000520765900001
出版者	WILEY
引用统计	被引频次：7[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/26840
专题	中国科学院广州能源研究所
通讯作者	Zhou, Zhengzhong; Yuan, Haoran
作者单位	1.Changzhou Univ, Inst Urban & Rural Min, Natl Local Joint Engn Res Ctr Biomass Refining &, 21 Gehu Middle Rd, Changzhou 213164, Jiangsu, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou, Peoples R China
推荐引用方式 GB/T 7714	Liu, Peng,Wang, Yue,Zhou, Zhengzhong,et al. Gas fuel production derived from pine sawdust pyrolysis catalyzed on alumina[J]. ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING,2020:11.
APA	Liu, Peng,Wang, Yue,Zhou, Zhengzhong,Yuan, Haoran,&Zheng, Tao.(2020).Gas fuel production derived from pine sawdust pyrolysis catalyzed on alumina.ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING,11.
MLA	Liu, Peng,et al."Gas fuel production derived from pine sawdust pyrolysis catalyzed on alumina".ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING (2020):11.