Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Efficient and Selective Oxidation of 5-Hydroxymethylfurfural into 2, 5-Diformylfuran Catalyzed by Magnetic Vanadium-Based Catalysts with Air as Oxidant | |
Lai, Jinhua1; Zhou, Shuolin1; Cheng, Feng1; Guo, Dongwen1; Liu, Xianxiang1,2; Xu, Qiong1; Yin, Dulin1 | |
2020-05-01 | |
发表期刊 | CATALYSIS LETTERS |
ISSN | 1011-372X |
卷号 | 150期号:5页码:1301-1308 |
通讯作者 | Liu, Xianxiang(lxx@hunnu.edu.cn) ; Yin, Dulin(dulinyin@126.com) |
摘要 | In this study, a new kind of magnetic vanadium-based catalyst was successfully prepared and employed to produce 2, 5-diformylfuran (DFF) in the liquid phase through selective oxidation of biomass-derived 5-hydroxymethylfurfur (HMF) with air as oxidant. It was found that magnetic Fe3O4 nanoparticles supported NH4 center dot V3O8 showed excellent catalytic performance with the achievement of 95.5% HMF conversion along with 82.9% selectivity to DFF under optimal reaction conditions. More importantly, the catalyst could be readily separated from the reaction mixture by a permanent magnet, and recycled several times without the loss of its catalytic activity. Graphic The NH4 center dot V3O8/Fe3O4 catalyst showed high activity for selective oxidation of 5-hydroxymethylfurfural into 2, 5-diformylfuran. |
关键词 | 5-Hydroxymethylfurfural 2 5-Diformylfuran Selective oxidation Magnetic catalyst Biomass transformation |
DOI | 10.1007/s10562-019-03041-w |
关键词[WOS] | AEROBIC OXIDATION ; VPO CATALYSTS ; H-BETA ; 2,5-DIFORMYLFURAN ; DERIVATIVES ; CONVERSION ; CARBON |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Physical |
WOS记录号 | WOS:000523031800009 |
出版者 | SPRINGER |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/26722 |
专题 | 中国科学院广州能源研究所 |
通讯作者 | Liu, Xianxiang; Yin, Dulin |
作者单位 | 1.Hunan Normal Univ, Natl & Local Joint Engn Lab New Petrochem Mat & F, Key Lab Assembly & Applicat Organ Funct Mol Hunan, Changsha 410081, Peoples R China 2.Chinese Acad Sci, CAS Key Lab Renewable Energy, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China |
推荐引用方式 GB/T 7714 | Lai, Jinhua,Zhou, Shuolin,Cheng, Feng,et al. Efficient and Selective Oxidation of 5-Hydroxymethylfurfural into 2, 5-Diformylfuran Catalyzed by Magnetic Vanadium-Based Catalysts with Air as Oxidant[J]. CATALYSIS LETTERS,2020,150(5):1301-1308. |
APA | Lai, Jinhua.,Zhou, Shuolin.,Cheng, Feng.,Guo, Dongwen.,Liu, Xianxiang.,...&Yin, Dulin.(2020).Efficient and Selective Oxidation of 5-Hydroxymethylfurfural into 2, 5-Diformylfuran Catalyzed by Magnetic Vanadium-Based Catalysts with Air as Oxidant.CATALYSIS LETTERS,150(5),1301-1308. |
MLA | Lai, Jinhua,et al."Efficient and Selective Oxidation of 5-Hydroxymethylfurfural into 2, 5-Diformylfuran Catalyzed by Magnetic Vanadium-Based Catalysts with Air as Oxidant".CATALYSIS LETTERS 150.5(2020):1301-1308. |
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