Biodiesel continuous esterification process experimental study and equipment design

doi:10.1007/s13399-020-00623-2

GIEC OpenIR

	Biodiesel continuous esterification process experimental study and equipment design
	Li, Huiwen1,2,3 ; Lv, Pengmei1,2,3,4 ; Wang, Zhongming1,2,3 ; Miao, Changlin 1,2,3; Yuan, Zhenhong1,2,3
	2020-02-27
发表期刊	BIOMASS CONVERSION AND BIOREFINERY
ISSN	2190-6815
页码	8
通讯作者	Miao, Changlin(miaocl@ms.giec.ac.cn)
摘要	Biodiesel is a particularly attractive renewable fuel because it can be used in existing engines, it is environmentally friendly and it is readily synthesized from animal fats and vegetable oils. Waste oil combined with heterogeneous catalysts offers exciting possibilities for improving the economics of biodiesel synthesis. The effects of methanol influx rate, reaction temperature, catalysis dosage and operation approaches on pre-esterification deacidification of trap grease were studied in a laboratory with solid acid catalysts. The results showed the maximum acid value reduction efficiency (96.73%) was obtained, and the acid value decreased sharply (from 120 to 3.92 mgKOH g(-1)) at a methanol influx rate of 0.825 mL/m in, a reaction temperature of 115 degrees C, a catalysis dosage of 2.5%, and a reaction time of 2 h using 50 g of oil. An acid value of 0.89 mgKOH g(-1) and an esterification rate of 99.26% were obtained. When the operational approach was changed to a methanol influx of 1.32 mL/min (methanol to oil molar ratio 6: 1), a reaction time of 30 min under pressure, the methanol influx rate changed to 0.825 mL/min, and then, coupled methanol recovered and purified immediately at atmospheric pressure. A continuous esterification deacidification equipment that is suitable for factory pretreatment deacidification of biodiesel produced from trap grease with a high acid value was designed according to laboratory experiments.
关键词	Biodiesel Esterification Equipment Design Trap grease
DOI	10.1007/s13399-020-00623-2
关键词[WOS]	WASTE COOKING OIL ; CRUDE JATROPHA-CURCAS ; SOLID ACID CATALYSTS ; SEED OIL ; TRANSESTERIFICATION ; OPTIMIZATION
收录类别	SCI
语种	英语
资助项目	Guangdong science project[2015B020241002] ; National Key RD Program[2017YFD0601003] ; National Natural Science Foundation of China (NSFC)[21506217]
WOS研究方向	Energy & Fuels ; Engineering
项目资助者	Guangdong science project ; National Key RD Program ; National Natural Science Foundation of China (NSFC)
WOS类目	Energy & Fuels ; Engineering, Chemical
WOS记录号	WOS:000516967400001
出版者	SPRINGER HEIDELBERG
引用统计	被引频次：2[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/26666
专题	中国科学院广州能源研究所
通讯作者	Miao, Changlin
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Peoples R China 4.Collaborat Innovat Ctr Biomass Energy, Zhengzhou 450002, Henan, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Li, Huiwen,Lv, Pengmei,Wang, Zhongming,et al. Biodiesel continuous esterification process experimental study and equipment design[J]. BIOMASS CONVERSION AND BIOREFINERY,2020:8.
APA	Li, Huiwen,Lv, Pengmei,Wang, Zhongming,Miao, Changlin,&Yuan, Zhenhong.(2020).Biodiesel continuous esterification process experimental study and equipment design.BIOMASS CONVERSION AND BIOREFINERY,8.
MLA	Li, Huiwen,et al."Biodiesel continuous esterification process experimental study and equipment design".BIOMASS CONVERSION AND BIOREFINERY (2020):8.