Efficient transfer hydrogenation of biomass derived furfural and levulinic acid via magnetic zirconium nanoparticles: Experimental and kinetic study

doi:10.1016/j.indcrop.2020.112133

GIEC OpenIR

	Efficient transfer hydrogenation of biomass derived furfural and levulinic acid via magnetic zirconium nanoparticles: Experimental and kinetic study
	Gu, Jing 1,2,3; Zhang, Jun 1,2,3; Wang, Yazhuo1,2,3 ; Li, Denian 1,2,3; Huang, Hongyu 1,2,3; Yuan, Haoran1,2,3 ; Chen, Yong1,2,3
	2020-03-01
发表期刊	INDUSTRIAL CROPS AND PRODUCTS
ISSN	0926-6690
卷号	145 页码:11
通讯作者	Yuan, Haoran(yuanhr@ms.giec.ac.cn)
摘要	A series of magnetic zirconium nanoparticles with varied Zr/Fe molar ratios were synthesized and developed as acid - base bifunctional catalysts in the catalytic transfer hydrogenation (CTH) of biomass-derived furfural (FFR) and levulinic acid (LA) using 2-propanol as both hydrogen donor and solvent. Zirconium constituents coated on nano-sized Fe3O4 endowed the catalysts with abundant acid-base sites, moderate surface areas (94.0-187.6 m(2)/g) and pore sizes (3.42-9.51 nm), thus giving nearly 100 % yields of furfuryl alcohol (FA) and gamma-valerolactone (GVL) after 2 h of reaction. Particularly, competitive activation energy (E-a) for the CTH of FFR into FA over Zr1Fe1-300 was as low as 50.9 kJ/mol. Moreover, the easily separable nanocatalyst Zr1Fe1-150 was also applicable to CTH of various allcyl levulinates into GVL in high efficiency and could be reused for multiple cycles without obvious loss of its catalytic performance in the transfer hydrogenation of LA.
关键词	Magnetic zirconium nanoparticles Furfural Levulinic acid Furfuryl alcohol gamma-Valerolactone
DOI	10.1016/j.indcrop.2020.112133
关键词[WOS]	CATALYTIC TRANSFER HYDROGENATION ; SELECTIVE TRANSFER HYDROGENATION ; LIQUID-PHASE HYDROGENATION ; PONNDORF-VERLEY REDUCTION ; RUTHENIUM-BASED CATALYSTS ; GAMMA-VALEROLACTONE ; ETHYL LEVULINATE ; BETA ZEOLITE ; ALCOHOL ; CONVERSION
收录类别	SCI
语种	英语
资助项目	National Key R&D Program of China[2018YFC1901200] ; National Natural Science Foundation of China[51976222] ; National Natural Science Foundation of China[51976223] ; Natural Science Foundation of Guangdong Province, China[2018A030313856] ; Natural Science Foundation of Guangdong Province, China[2016A030313173] ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou)[GML2O19ZDO1O1] ; Science and Technology Planning Project of Guangzhou[201904010351]
WOS研究方向	Agriculture
项目资助者	National Key R&D Program of China ; National Natural Science Foundation of China ; Natural Science Foundation of Guangdong Province, China ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) ; Science and Technology Planning Project of Guangzhou
WOS类目	Agricultural Engineering ; Agronomy
WOS记录号	WOS:000518865400071
出版者	ELSEVIER
引用统计	被引频次：26[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/26581
专题	中国科学院广州能源研究所
通讯作者	Yuan, Haoran
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Gu, Jing,Zhang, Jun,Wang, Yazhuo,et al. Efficient transfer hydrogenation of biomass derived furfural and levulinic acid via magnetic zirconium nanoparticles: Experimental and kinetic study[J]. INDUSTRIAL CROPS AND PRODUCTS,2020,145:11.
APA	Gu, Jing.,Zhang, Jun.,Wang, Yazhuo.,Li, Denian.,Huang, Hongyu.,...&Chen, Yong.(2020).Efficient transfer hydrogenation of biomass derived furfural and levulinic acid via magnetic zirconium nanoparticles: Experimental and kinetic study.INDUSTRIAL CROPS AND PRODUCTS,145,11.
MLA	Gu, Jing,et al."Efficient transfer hydrogenation of biomass derived furfural and levulinic acid via magnetic zirconium nanoparticles: Experimental and kinetic study".INDUSTRIAL CROPS AND PRODUCTS 145(2020):11.