Influences of microstructural alternations and inorganic catalysis on the thermochemical conversion of biowaste-derived hydrochar

doi:10.1016/j.fuproc.2019.106304

GIEC OpenIR

	Influences of microstructural alternations and inorganic catalysis on the thermochemical conversion of biowaste-derived hydrochar
	Zhuang, Xiuzheng 1,3,4; Song, Yanpei 1,3,4; Zhan, Hao 2,5; Yin, Xiuli1,4 ; Wu, Chuangzhi1,3,4
	2020-03-01
发表期刊	FUEL PROCESSING TECHNOLOGY
ISSN	0378-3820
卷号	199 页码:9
通讯作者	Yin, Xiuli(xlyin@ms.giec.ac.cn)
摘要	Hydrothermal carbonization (HTC) is widely recognized as an ideal pretreatment for wet feedstock, and thus an insight into the influences of HTC on feedstock is essential to its subsequent applications. In this study, the evolutions of microstructures in biowaste-derived hydrochars were explored and subsequently correlated with the changes on pyrolysis and gasification reactivities. Meanwhile, the catalytic effect of specific alkali and alkaline earth metals (AAEMs) on gasification process was also analyzed. Experimental results showed that the pore structures and specific surface area of hydrochar were improved with the increased temperatures, and hydrochar grindability was better than their original sample. However, these changes did not function in a positive way on pyrolysis or gasification as previous studies supposed, which might be inhibited by the competitively negative effects from the developed aromaticity in hydrochar. The comparison of hydrochars with and without acid washing demonstrated the self-catalysis reactions of intrinsic AAEMs in ash, but the extent was varied as the differences on its types and contents. By means of quantitatively reloading specific AAEMs in hydrochar, potassium (K) and sodium (Na), compared to iron (Fe), magnesium (Mg) and calcium (Ca), performed a relatively stronger catalytic effect on gasification process, which significantly enhanced the average gasification reactivity of sample.
关键词	Industrial biowaste Hydrothermal carbonization microstructural alternation Inorganic catalyst Thermochemical conversion
DOI	10.1016/j.fuproc.2019.106304
关键词[WOS]	CO2 GASIFICATION PROPERTIES ; STEAM GASIFICATION ; HYDROTHERMAL TREATMENT ; INDUSTRIAL BIOWASTES ; SEWAGE-SLUDGE ; SOLID-FUEL ; REACTIVITY ; BIOMASS ; COMBUSTION ; TEMPERATURE
收录类别	SCI
语种	英语
资助项目	Strategic Priority Research Program of Chinese Academy of Sciences[XDA21060600] ; Science and Technology Program of Guangdong Province[2018A050506068] ; Science and Technology Program of Guangzhou[201803030006]
WOS研究方向	Chemistry ; Energy & Fuels ; Engineering
项目资助者	Strategic Priority Research Program of Chinese Academy of Sciences ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangzhou
WOS类目	Chemistry, Applied ; Energy & Fuels ; Engineering, Chemical
WOS记录号	WOS:000513295200032
出版者	ELSEVIER
引用统计	被引频次：18[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/26448
专题	中国科学院广州能源研究所
通讯作者	Yin, Xiuli
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Geochem, State Key Lab Organ Geochem, Guangzhou 510640, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Peoples R China 5.Chinese Acad Sci, Guangzhou Inst Geochem, Guangdong Key Lab Environm Protect & Resources Ut, Guangzhou 510640, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Zhuang, Xiuzheng,Song, Yanpei,Zhan, Hao,et al. Influences of microstructural alternations and inorganic catalysis on the thermochemical conversion of biowaste-derived hydrochar[J]. FUEL PROCESSING TECHNOLOGY,2020,199:9.
APA	Zhuang, Xiuzheng,Song, Yanpei,Zhan, Hao,Yin, Xiuli,&Wu, Chuangzhi.(2020).Influences of microstructural alternations and inorganic catalysis on the thermochemical conversion of biowaste-derived hydrochar.FUEL PROCESSING TECHNOLOGY,199,9.
MLA	Zhuang, Xiuzheng,et al."Influences of microstructural alternations and inorganic catalysis on the thermochemical conversion of biowaste-derived hydrochar".FUEL PROCESSING TECHNOLOGY 199(2020):9.