Catalytic Hydrogenolysis of Biomass-derived Polyhydric Compounds to C-2-C-3 Small-Molecule Polyols: A Review

doi:10.2174/1385272823666190913185618

GIEC OpenIR

	Catalytic Hydrogenolysis of Biomass-derived Polyhydric Compounds to C-2-C-3 Small-Molecule Polyols: A Review
	Cai, Chiliu1,2,3 ; Zhu, Changhui 1,2,3,4; Wang, Haiyong 1,2,3,4; Xin, Haosheng 1,2,3,4; Xiu, Zhongxun 1,2,3,4; Wang, Chenguang 1,2,3; Zhang, Qi1,2,3 ; Liu, Qiying1,2,3 ; Ma, Longlong1,2,3
	2019
发表期刊	CURRENT ORGANIC CHEMISTRY
ISSN	1385-2728
卷号	23 期号:20 页码:2180-2189
通讯作者	Liu, Qiying(liugy@ms.giec.ac.cn)
摘要	Biomass energy has attracted much attention because of its clean and renewable characteristics. At present, C-2-C-3 polyols such as glycerol, 1,2-propanediol, and ethylene glycol, widely used as platforms for downstream chemicals or directly used as chemicals in diversified industries, mainly depend on the petrochemical industry. In terms of the feedstock for C-2-C-3 polyol production, the C-3-derived glycerol is a side product during biodiesel synthesis, whereas the C-5-derived xylitol and C-6-derived sorbitol can be mainly obtained by hydrolysis-hydrogenation of hemicellulose and cellulose from lignocellulosic biomass, respectively. In this review, we summarize the catalysts and catalysis for selective hydrogenolysis of these polyhydric compounds to C-2-C-3 polyols and introduce the reaction pathways for the target polyol formation based on the C-3, C-5, and C-6 polyhydric alcohol hydrogenolysis. Finally, state-of-the-art technologies are described and the remaining challenges and further prospects are presented in view of the technical aspects.
关键词	Hydrogenolysis pathway catalyst polyols C-2-C-3 polyols cellulose biomass
DOI	10.2174/1385272823666190913185618
关键词[WOS]	LAYERED DOUBLE HYDROXIDE ; SELECTIVE HYDROGENOLYSIS ; ETHYLENE-GLYCOL ; TRANSFER HYDROGENATION ; PROPYLENE-GLYCOL ; SORBITOL HYDROGENOLYSIS ; GLYCEROL HYDROGENOLYSIS ; PHASE HYDROGENOLYSIS ; PLATFORM MOLECULES ; CU/SIO2 CATALYST
收录类别	SCI
语种	英语
资助项目	Natural Science Foundation of Guangdong Province[2017A030308010] ; National Natural Science Foundation of China[51576199] ; National Key Research and Development Project[2018YFB1501402]
WOS研究方向	Chemistry
项目资助者	Natural Science Foundation of Guangdong Province ; National Natural Science Foundation of China ; National Key Research and Development Project
WOS类目	Chemistry, Organic
WOS记录号	WOS:000504405200005
出版者	BENTHAM SCIENCE PUBL LTD
引用统计	被引频次：3[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/26121
专题	中国科学院广州能源研究所
通讯作者	Liu, Qiying
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Cai, Chiliu,Zhu, Changhui,Wang, Haiyong,et al. Catalytic Hydrogenolysis of Biomass-derived Polyhydric Compounds to C-2-C-3 Small-Molecule Polyols: A Review[J]. CURRENT ORGANIC CHEMISTRY,2019,23(20):2180-2189.
APA	Cai, Chiliu.,Zhu, Changhui.,Wang, Haiyong.,Xin, Haosheng.,Xiu, Zhongxun.,...&Ma, Longlong.(2019).Catalytic Hydrogenolysis of Biomass-derived Polyhydric Compounds to C-2-C-3 Small-Molecule Polyols: A Review.CURRENT ORGANIC CHEMISTRY,23(20),2180-2189.
MLA	Cai, Chiliu,et al."Catalytic Hydrogenolysis of Biomass-derived Polyhydric Compounds to C-2-C-3 Small-Molecule Polyols: A Review".CURRENT ORGANIC CHEMISTRY 23.20(2019):2180-2189.