Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Catalytic Hydrogenolysis of Biomass-derived Polyhydric Compounds to C-2-C-3 Small-Molecule Polyols: A Review | |
Cai, Chiliu1,2,3![]() ![]() ![]() ![]() | |
2019 | |
Source Publication | CURRENT ORGANIC CHEMISTRY
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ISSN | 1385-2728 |
Volume | 23Issue:20Pages:2180-2189 |
Corresponding Author | Liu, Qiying(liugy@ms.giec.ac.cn) |
Abstract | Biomass energy has attracted much attention because of its clean and renewable characteristics. At present, C-2-C-3 polyols such as glycerol, 1,2-propanediol, and ethylene glycol, widely used as platforms for downstream chemicals or directly used as chemicals in diversified industries, mainly depend on the petrochemical industry. In terms of the feedstock for C-2-C-3 polyol production, the C-3-derived glycerol is a side product during biodiesel synthesis, whereas the C-5-derived xylitol and C-6-derived sorbitol can be mainly obtained by hydrolysis-hydrogenation of hemicellulose and cellulose from lignocellulosic biomass, respectively. In this review, we summarize the catalysts and catalysis for selective hydrogenolysis of these polyhydric compounds to C-2-C-3 polyols and introduce the reaction pathways for the target polyol formation based on the C-3, C-5, and C-6 polyhydric alcohol hydrogenolysis. Finally, state-of-the-art technologies are described and the remaining challenges and further prospects are presented in view of the technical aspects. |
Keyword | Hydrogenolysis pathway catalyst polyols C-2-C-3 polyols cellulose biomass |
DOI | 10.2174/1385272823666190913185618 |
WOS Keyword | LAYERED DOUBLE HYDROXIDE ; SELECTIVE HYDROGENOLYSIS ; ETHYLENE-GLYCOL ; TRANSFER HYDROGENATION ; PROPYLENE-GLYCOL ; SORBITOL HYDROGENOLYSIS ; GLYCEROL HYDROGENOLYSIS ; PHASE HYDROGENOLYSIS ; PLATFORM MOLECULES ; CU/SIO2 CATALYST |
Indexed By | SCI |
Language | 英语 |
Funding Project | Natural Science Foundation of Guangdong Province[2017A030308010] ; National Natural Science Foundation of China[51576199] ; National Key Research and Development Project[2018YFB1501402] |
WOS Research Area | Chemistry |
Funding Organization | Natural Science Foundation of Guangdong Province ; National Natural Science Foundation of China ; National Key Research and Development Project |
WOS Subject | Chemistry, Organic |
WOS ID | WOS:000504405200005 |
Publisher | BENTHAM SCIENCE PUBL LTD |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.giec.ac.cn/handle/344007/26121 |
Collection | 中国科学院广州能源研究所 |
Corresponding Author | Liu, Qiying |
Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
Recommended Citation GB/T 7714 | Cai, Chiliu,Zhu, Changhui,Wang, Haiyong,et al. Catalytic Hydrogenolysis of Biomass-derived Polyhydric Compounds to C-2-C-3 Small-Molecule Polyols: A Review[J]. CURRENT ORGANIC CHEMISTRY,2019,23(20):2180-2189. |
APA | Cai, Chiliu.,Zhu, Changhui.,Wang, Haiyong.,Xin, Haosheng.,Xiu, Zhongxun.,...&Ma, Longlong.(2019).Catalytic Hydrogenolysis of Biomass-derived Polyhydric Compounds to C-2-C-3 Small-Molecule Polyols: A Review.CURRENT ORGANIC CHEMISTRY,23(20),2180-2189. |
MLA | Cai, Chiliu,et al."Catalytic Hydrogenolysis of Biomass-derived Polyhydric Compounds to C-2-C-3 Small-Molecule Polyols: A Review".CURRENT ORGANIC CHEMISTRY 23.20(2019):2180-2189. |
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