A novel catalyst with variable active sites for the direct hydrogenation of waste oils into jet fuel

doi:10.1016/j.apcatb.2019.118114

GIEC OpenIR

	A novel catalyst with variable active sites for the direct hydrogenation of waste oils into jet fuel
	Li, Ming 1,2,3,4; Fu, Junying 1,2,3; Xing, Shiyou 6; Yang, Lingmei1,2,3 ; Zhang, Xufeng 1,2,3; Lv, Pengmei1,2,3,5 ; Wang, Zhongming1,2,3 ; Yuan, Zhenhong1,2,3
	2020
发表期刊	APPLIED CATALYSIS B-ENVIRONMENTAL
ISSN	0926-3373
卷号	260 页码:14
通讯作者	Lv, Pengmei(lvpm@ms.giec.ac.cn)
摘要	A series of novel NiO-LiZSM-5 catalysts with variable active sites was prepared to enhance the hydrogenation of waste oils into jet fuel components (C8-C16) by producing more olefins. In the early stage of the reaction, nickel oxide particles, as strong Lewis acid sites, promoted the cracking process of long-chain olefins into propylene and ethylene, which are the precursors of aromatics and iso-paraffins. As the reaction progressed, the nickel oxide was gradually reduced to nickel by H-2 in the system, and the strong Lewis acid sites were transformed into metal centres, which enhanced the hydrogenation performance of the catalyst. The jet fuel components converted from oleic acid by the catalyst could reach 80.42 mol%, which was approximately 10 mol% greater than that of the traditional Ni-ZSM-5 catalyst. Furthermore, four waste oils were efficiently converted into jet fuel by this catalytic system, the most effective content of jet fuel reached 91.7 mol%.
关键词	Lithium ion exchange Acid sites Metal centres ZSM-5 Jet fuel
DOI	10.1016/j.apcatb.2019.118114
关键词[WOS]	DIESEL-RANGE ALKANES ; BIODIESEL PRODUCTION ; FATTY-ACIDS ; OLEIC-ACID ; QUANTITATIVE CONVERSION ; SELECTIVE OXIDATION ; HYDROCARBON FUELS ; CARBON DEPOSITION ; PYROLYSIS OIL ; NONEDIBLE OIL
收录类别	SCI
语种	英语
资助项目	Guangdong Special Support Program[2017TX04Z109] ; Natural Science Foundation of Guangdong Province[2016A030308004] ; Natural Science Foundation of Guangdong Province[2018A030310078] ; National Natural Science Foundation of China[21576260] ; National Natural Science Foundation of China Youth[51806225] ; National Natural Science Foundation of China Youth[51606201] ; Special Funds of Applied Science and Technology Research of Guangdong Province[2015B020241002]
WOS研究方向	Chemistry ; Engineering
项目资助者	Guangdong Special Support Program ; Natural Science Foundation of Guangdong Province ; National Natural Science Foundation of China ; National Natural Science Foundation of China Youth ; Special Funds of Applied Science and Technology Research of Guangdong Province
WOS类目	Chemistry, Physical ; Engineering, Environmental ; Engineering, Chemical
WOS记录号	WOS:000496894300022
出版者	ELSEVIER
引用统计	被引频次：34[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/26097
专题	中国科学院广州能源研究所
通讯作者	Lv, Pengmei
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 5.Collaborat Innovat Ctr Biomass Energy, Zhengzhou 450002, Henan, Peoples R China 6.Univ Utrecht, Debye Inst Nanomat Sci, Inorgan Chem & Catalysis, Univ Weg 99, NL-3584 CG Utrecht, Netherlands
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Li, Ming,Fu, Junying,Xing, Shiyou,et al. A novel catalyst with variable active sites for the direct hydrogenation of waste oils into jet fuel[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2020,260:14.
APA	Li, Ming.,Fu, Junying.,Xing, Shiyou.,Yang, Lingmei.,Zhang, Xufeng.,...&Yuan, Zhenhong.(2020).A novel catalyst with variable active sites for the direct hydrogenation of waste oils into jet fuel.APPLIED CATALYSIS B-ENVIRONMENTAL,260,14.
MLA	Li, Ming,et al."A novel catalyst with variable active sites for the direct hydrogenation of waste oils into jet fuel".APPLIED CATALYSIS B-ENVIRONMENTAL 260(2020):14.