Tandem Conversion of Fructose to 2,5-Dimethylfuran with the Aid of Ionic Liquids

doi:10.1021/acssuschemeng.9b02614

GIEC OpenIR

	Tandem Conversion of Fructose to 2,5-Dimethylfuran with the Aid of Ionic Liquids
	Zhu, Changhui 1,2,3,4; Wang, Haiyong 1,2,3,4; Cai, Chilu 1,2,3; Bi, Kang 6; Cai, Bijuan 5; Song, Xiangbo 1,2,3,4; Liu, Qiying1,2,3,7 ; Ma, Longlong1,2,3
	2019-10-07
发表期刊	ACS SUSTAINABLE CHEMISTRY & ENGINEERING
ISSN	2168-0485
卷号	7 期号:19 页码:16026-16040
通讯作者	Liu, Qiying(liuqy@ms.giec.ac.cn)
摘要	Biomass-derived 2,5-dimethylfuran (DMF) is an ideal, renewable gasoline additive, and its production with high productivity is highly desirable. A continuous production route was developed to yield DMF from fructose via a tandem strategy, where dehydration catalysts (HY zeolite and niobium phosphate) assisted by 1-butyl-3-methylimidazolium chloride ([BMim] Cl) and hydro-deoxygenation (HDO) catalyst Cu-Ru/C were integrated into one reaction system with gamma-butyrolactone (GBL) as the mobile phase. Optimum conditions, such as temperature, H-2 pressure, weight hourly space velocity, and [BMim]Cl concentration, were investigated systematically, with an initial HDO study by using 5-hydroxymethylfurfural (HMF) as substrate and subsequent tandem dehydration and HDO to produce DMF with fructose as substrate. Among the conditions, the highest yield of DMF at 55.2% was gained by niobium phosphate and Cu-Ru/C, with the aid of [BMim] Cl in a fixed bed. Meanwhile, [BMim]Cl facilitated fructose dehydration to HMF and also mediated HDO of the resultant HMF by stabilization, which was clarified by H-1 NMR and FTIR spectroscopy. Finally, the fact that carbon deposit led to catalyst deactivation was examined thoroughly via a series of characterization techniques. This work achieved continuous DMF production from fructose and laid a foundation for future possible amplification of DMF.
关键词	Fructose [BMim]Cl Dehydration 2,5-Dimethylfuran Hydrodeoxygenation
DOI	10.1021/acssuschemeng.9b02614
关键词[WOS]	ONE-POT PRODUCTION ; NIOBIUM PHOSPHATE ; SELECTIVE HYDRODEOXYGENATION ; 5-HYDROXYMETHYLFURFURAL HMF ; LIGNOCELLULOSIC BIOMASS ; EFFICIENT PRODUCTION ; BIPHASIC SOLVENT ; CATALYSTS ; DEHYDRATION ; GLUCOSE
收录类别	SCI
语种	英语
资助项目	National Key R&D Program of China[2018YFB1501402] ; National Science Foundation of China[51576199] ; National Science Foundation of China[51536009] ; Natural Science Foundation of Guangdong Province[2017A030308010] ; DNL Cooperation Fund, CAS[DNL180302] ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N092]
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Engineering
项目资助者	National Key R&D Program of China ; National Science Foundation of China ; Natural Science Foundation of Guangdong Province ; DNL Cooperation Fund, CAS ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program
WOS类目	Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical
WOS记录号	WOS:000489986400023
出版者	AMER CHEMICAL SOC
引用统计	被引频次：15[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/25965
专题	中国科学院广州能源研究所
通讯作者	Liu, Qiying
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 5.South China Agr Univ, Coll Mat & Energy, Guangzhou 510642, Guangdong, Peoples R China 6.Shandong Prov Met Engn Co Ltd, Jinan 250101, Shandong, Peoples R China 7.Univ Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Zhu, Changhui,Wang, Haiyong,Cai, Chilu,et al. Tandem Conversion of Fructose to 2,5-Dimethylfuran with the Aid of Ionic Liquids[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2019,7(19):16026-16040.
APA	Zhu, Changhui.,Wang, Haiyong.,Cai, Chilu.,Bi, Kang.,Cai, Bijuan.,...&Ma, Longlong.(2019).Tandem Conversion of Fructose to 2,5-Dimethylfuran with the Aid of Ionic Liquids.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,7(19),16026-16040.
MLA	Zhu, Changhui,et al."Tandem Conversion of Fructose to 2,5-Dimethylfuran with the Aid of Ionic Liquids".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 7.19(2019):16026-16040.