A sustainable system for maleic acid synthesis from biomass-derived sugar

doi:10.1002/jctb.6260

GIEC OpenIR

	A sustainable system for maleic acid synthesis from biomass-derived sugar
	Yu, Qiang 1,2; Bai, Ruxue 1,3; Wang, Fan 1,3; Zhang, Qinghua 4; Sun, Yongming1 ; Zhang, Yu1 ; Qin, Lei1 ; Wang, Zhongming1 ; Yuan, Zhenhong1
	2019-11-29
发表期刊	JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY
ISSN	0268-2575
页码	7
通讯作者	Zhang, Yu(zhangyu@ms.giec.ac.cn) ; Qin, Lei(qinlei@ms.giec.ac.cn)
摘要	BACKGROUND The preparation of maleic acid from the oxidation of renewable furfural has attracted significant attention, but research regarding the direct transformation of biomass-derived sugar to maleic acid is rare. The research regarding the direct transformation of xylose to maleic acid would further promote its industrial applications. RESULTS The direct synthesis of maleic acid from xylose was investigated based on a sustainable system of deep eutectic solvents (DESs). Four DESs were screened to evaluate their abilities for the dehydration of xylose. Hydrogen peroxide (H2O2) was then loaded to realize the oxidation of furfural without the separation of intermediates. A good maleic acid yield of 20.8%, along with 5.0% of fumaric acid, based on the xylose content were obtained under the initial xylose loading of 50 mM, a tin(IV) chloride (SnCl4)-xylose molar ratio of 4:1, in a monophase choline chloride (ChCl)-formic acid (Fa) (molar ratio of 1:6) system at 120 degrees C for 2 h. Then, 4 mL of H2O2 per mmol furfural was loaded for a further 10 min at 120 degrees C. CONCLUSION This ChCl-Fa-SnCl4-H2O2 system possesses a higher oxidation selectivity to maleic acid with no furanone and succinic acid. Moreover, it was interesting that ChCl and SnCl4 could be recovered through natural recrystallization. (c) 2019 Society of Chemical Industry
关键词	deep eutectic solvents biomass maleic acid furfural
DOI	10.1002/jctb.6260
关键词[WOS]	DEEP EUTECTIC SOLVENT ; XYLOSE ISOMERIZATION ; SELECTIVE OXIDATION ; AEROBIC OXIDATION ; PHASE OXIDATION ; ORGANIC-ACIDS ; CONVERSION ; XYLAN ; ANHYDRIDE ; TRANSFORMATION
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51876206] ; Natural Science Foundation of Guangdong Province[2018A030313012] ; Young Top-notch Talent of Guangdong Province, China[2016TQ03N647] ; Pearl River S&T Nova Program of Guangzhou, China[201610010110] ; DNL Cooperation Fund, Chinese Academy of Sciences (CAS)[DNL180305] ; Outstanding Youth Talent Funding Program of Jiangxi Province, China[20171BCB23044] ; Guangdong Key Laboratory for Innovative Development and Utilization of Forest Plant Germplasm, South China Agricultural University ; Youth Innovation Promotion Association, CAS[2015289]
WOS研究方向	Biotechnology & Applied Microbiology ; Chemistry ; Engineering
项目资助者	National Natural Science Foundation of China ; Natural Science Foundation of Guangdong Province ; Young Top-notch Talent of Guangdong Province, China ; Pearl River S&T Nova Program of Guangzhou, China ; DNL Cooperation Fund, Chinese Academy of Sciences (CAS) ; Outstanding Youth Talent Funding Program of Jiangxi Province, China ; Guangdong Key Laboratory for Innovative Development and Utilization of Forest Plant Germplasm, South China Agricultural University ; Youth Innovation Promotion Association, CAS
WOS类目	Biotechnology & Applied Microbiology ; Chemistry, Multidisciplinary ; Engineering, Environmental ; Engineering, Chemical
WOS记录号	WOS:000499302300001
出版者	WILEY
引用统计	被引频次：14[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/25905
专题	中国科学院广州能源研究所
通讯作者	Zhang, Yu; Qin, Lei
作者单位	1.Chinese Acad Sci, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou Inst Energy Convers, Guangzhou, Guangdong, Peoples R China 2.Dalian Natl Lab Clean Energy, Dalian, Peoples R China 3.Univ Chinese Acad Sci, Beijing, Peoples R China 4.Jiangxi Agr Univ, Jiangxi Engn Lab Dev & Utilizat Agr Microbial Res, Coll Biosci & Biotechnol, Nanchang, Jiangxi, Peoples R China
推荐引用方式 GB/T 7714	Yu, Qiang,Bai, Ruxue,Wang, Fan,et al. A sustainable system for maleic acid synthesis from biomass-derived sugar[J]. JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY,2019:7.
APA	Yu, Qiang.,Bai, Ruxue.,Wang, Fan.,Zhang, Qinghua.,Sun, Yongming.,...&Yuan, Zhenhong.(2019).A sustainable system for maleic acid synthesis from biomass-derived sugar.JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY,7.
MLA	Yu, Qiang,et al."A sustainable system for maleic acid synthesis from biomass-derived sugar".JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY (2019):7.