Kinetic compensation effect in logistic distributed activation energy model for lignocellulosic biomass pyrolysis

doi:10.1016/j.biortech.2018.05.092

GIEC OpenIR

	Kinetic compensation effect in logistic distributed activation energy model for lignocellulosic biomass pyrolysis
	Xu, Di 1; Chai, Meiyun 1; Dong, Zhujun 1; Rahman, Md Maksudur 1; Yu, Xi 3; Cai, Junmeng 1,2
	2018-10-01
发表期刊	BIORESOURCE TECHNOLOGY
ISSN	0960-8524
卷号	265 页码:139-145
通讯作者	Cai, Junmeng(jmcai@sjtu.edu.cn)
摘要	The kinetic compensation effect in the logistic distributed activation energy model (DAEM) for lignocellulosic biomass pyrolysis was investigated. The sum of square error (SSE) surface tool was used to analyze two theoretically simulated logistic DAEM processes for cellulose and xylan pyrolysis. The logistic DAEM coupled with the pattern search method for parameter estimation was used to analyze the experimental data of cellulose pyrolysis. The results showed that many parameter sets of the logistic DAEM could fit the data at different heating rates very well for both simulated and experimental processes, and a perfect linear relationship between the logarithm of the frequency factor and the mean value of the activation energy distribution was found. The parameters of the logistic DAEM can be estimated by coupling the optimization method and isoconversional kinetic methods. The results would be helpful for chemical kinetic analysis using DAEM.
关键词	Logistic distribution Distributed activation energy model (DAEM) Kinetic compensation effect Biomass pyrolysis Pattern search method
DOI	10.1016/j.biortech.2018.05.092
关键词[WOS]	SOLID FUELS ; THERMOGRAVIMETRIC ANALYSIS ; MATHEMATICAL ORIGINS ; EXPERIMENTAL ERRORS ; PARAMETERS ; BEHAVIOR ; COAL ; DEVOLATILIZATION
收录类别	SCI
语种	英语
资助项目	CAS Key Laboratory of Renewable Energy[Y807k91001] ; Global Challenges Research Fund (GCRF) Networking Grant ('Pyrolysis of Municipal Organic Waste for Renewable Road Construction Materials')
WOS研究方向	Agriculture ; Biotechnology & Applied Microbiology ; Energy & Fuels
项目资助者	CAS Key Laboratory of Renewable Energy ; Global Challenges Research Fund (GCRF) Networking Grant ('Pyrolysis of Municipal Organic Waste for Renewable Road Construction Materials')
WOS类目	Agricultural Engineering ; Biotechnology & Applied Microbiology ; Energy & Fuels
WOS记录号	WOS:000439467300018
出版者	ELSEVIER SCI LTD
引用统计	被引频次：57[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/25783
专题	中国科学院广州能源研究所
通讯作者	Cai, Junmeng
作者单位	1.Shanghai Jiao Tong Univ, Sch Agr & Biol, Minist Agr, Biomass Energy Engn Res Ctr,Key Lab Urban Agr Sou, 800 Dongchuan Rd, Shanghai 200240, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Aston Univ, European Bioenergy Res Inst, Birmingham B4 7ET, W Midlands, England
推荐引用方式 GB/T 7714	Xu, Di,Chai, Meiyun,Dong, Zhujun,et al. Kinetic compensation effect in logistic distributed activation energy model for lignocellulosic biomass pyrolysis[J]. BIORESOURCE TECHNOLOGY,2018,265:139-145.
APA	Xu, Di,Chai, Meiyun,Dong, Zhujun,Rahman, Md Maksudur,Yu, Xi,&Cai, Junmeng.(2018).Kinetic compensation effect in logistic distributed activation energy model for lignocellulosic biomass pyrolysis.BIORESOURCE TECHNOLOGY,265,139-145.
MLA	Xu, Di,et al."Kinetic compensation effect in logistic distributed activation energy model for lignocellulosic biomass pyrolysis".BIORESOURCE TECHNOLOGY 265(2018):139-145.