Selective Hydrodeoxygenation of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran over Ni Supported on Zirconium Phosphate Catalysts

doi:10.1021/acsomega.8b00609

GIEC OpenIR

	Selective Hydrodeoxygenation of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran over Ni Supported on Zirconium Phosphate Catalysts
	Zhu, Changhui 1,2,3,4; Liu, Qiying1,2,3 ; Li, Dan 1,2,3,5; Wang, Haiyong 1,2,3,5; Zhang, Caihong 1,2,3,4; Cui, Chunhua 1,2,3,5; Chen, Lungang 1,2,3; Cai, Chiliu1,2,3 ; Ma, Longlong1,2,3
	2018-07-01
发表期刊	ACS OMEGA
ISSN	2470-1343
卷号	3 期号:7 页码:7407-7417
通讯作者	Liu, Qiying(liuqy@ms.giec.ac.cn)
摘要	Crystal alpha-zirconium phosphate (alpha-ZrP) was prepared by a hydrothermal method and exfoliated into a layered structure by n-hexylamine (C6H13NH2). Ni-based catalyst (Ni/ZrP) was promoted by loading nickel on the layered alpha-ZrP via ion exchange. The catalyst was performed to catalyze hydrodeoxygenation of 5-hydroxymethylfurfural (HMF) to 2,5-dimethylfuran (DMF), and a 68.1% yield of DMF and 100% conversion of HMF were achieved at 240 degrees C, 5 MPa H-2, and 20 h. The DMF yield can still retain 52.8% after five cycles. The characteristics of the catalyst were investigated via N-2 adsorption-desorption, X-ray diffraction, field emission scanning electron microscopy, high-resolution transmission electron microscopy, pyridine-adsorbed Fourier transform infrared (FTIR) spectra, FTIR spectra, inductively coupled plasma mass spectrometry, and thermogravimetric analysis-mass spectrometry, as well as Raman spectroscopy. A pathway from HMF to DMF was found with MF as the intermediate product, and DMF production was preferable via the -CH2OH group hydrogenolysis of HMF over Lewis acidic sites of Ni/ZrP, which is caused by the zirconium vacant orbits.
DOI	10.1021/acsomega.8b00609
关键词[WOS]	AQUEOUS-PHASE HYDRODEOXYGENATION ; EFFICIENT PRODUCTION ; BIMETALLIC CATALYST ; BIOMASS ; ACID ; HYDROGENATION ; FRUCTOSE ; GASOLINE ; DIMETHYLFURAN ; DEHYDRATION
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51576199] ; National Natural Science Foundation of China[51536009] ; Natural Science Foundation of Guangdong Province[2017A030308010]
WOS研究方向	Chemistry
项目资助者	National Natural Science Foundation of China ; Natural Science Foundation of Guangdong Province
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000438908600030
出版者	AMER CHEMICAL SOC
引用统计	被引频次：50[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/25764
专题	中国科学院广州能源研究所
通讯作者	Liu, Qiying
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Key Lab New & Renewable Energy Res & De, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China 4.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China 5.Univ Sci & Technol China, Sch Nano Sci & Technol, 166 Renai Rd,Suzhou Ind Pk, Suzhou 215123, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Zhu, Changhui,Liu, Qiying,Li, Dan,et al. Selective Hydrodeoxygenation of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran over Ni Supported on Zirconium Phosphate Catalysts[J]. ACS OMEGA,2018,3(7):7407-7417.
APA	Zhu, Changhui.,Liu, Qiying.,Li, Dan.,Wang, Haiyong.,Zhang, Caihong.,...&Ma, Longlong.(2018).Selective Hydrodeoxygenation of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran over Ni Supported on Zirconium Phosphate Catalysts.ACS OMEGA,3(7),7407-7417.
MLA	Zhu, Changhui,et al."Selective Hydrodeoxygenation of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran over Ni Supported on Zirconium Phosphate Catalysts".ACS OMEGA 3.7(2018):7407-7417.