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Hyper-cross-linked polymer based carbonaceous materials as efficient catalysts for ethyl levulinate production from carbohydrates
Gu, Jing1,2,3; Zhang, Jun1,2,3; Li, Denian1,2,3; Yuan, Haoran1,2,3; Chen, Yong1,2,3
2019-07-17
Source PublicationJOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY
ISSN0268-2575
Pages11
Corresponding AuthorYuan, Haoran(yuanhr@ms.giec.ac.cn)
AbstractBACKGROUND Catalytic upgrading of biomass into various alkyl levulinates has gained wide attention recently. Particularly, ethyl levulinate (EL) shows great potential as gasoline additive and substitute of biodiesel fuels. RESULTS Hyper-cross-linked organic polymer based carbonaceous materials with large surface areas and strong Br phi nsted acidity were synthesized and developed as highly efficient solid acids for the direct transformation of biomass derived carbohydrates into biofuel candidate ethyl levulinate (EL). Controllable Brunauer-Emmett-Teller (BET) surface area and proper acid density of as-prepared carbonaceous materials were demonstrated to be crucial for the successful synthesis of EL. Among the catalysts, alpha,alpha '-dichloro-p-xylene derived hyper-cross-linked organic carbocatalyst (HDS-3.6) exhibited the best results for EL formation with the optimal yield of 70.3% at a temperature of 423 K, which was comparable with those of frequently-used solid acids such as commercial Amberlyst-15 and metal oxides. The presence of dimethyl sulfoxide (DMSO) in the catalytic system facilitated the production of intermediates 5-hydroxymethylfurfural (HMF) and 5-ethoxymethylfurfural. Notably, the hyper-cross-linked organic polymers with abundant Br phi nsted acid sites were much more effective in the catalytic synthesis of levulinate esters from ketoses. CONCLUSION The prepared hyper-cross-linked organic polymers were efficient and robust catalysts to produce various biomass derived alkyl levulinates with high activity and stability. (c) 2019 Society of Chemical Industry
Keywordhyper-cross-linked polymer solid acids carbohydrate ethyl levulinate
DOI10.1002/jctb.6107
WOS KeywordSOLID-ACID ; METHYL LEVULINATE ; CONVERSION ; BIOMASS ; CELLULOSE ; ESTERIFICATION ; GLUCOSE ; TRANSFORMATION ; PERFORMANCE ; BIODIESEL
Indexed BySCI
Language英语
Funding ProjectNational Key R&D Program of China[2018YFC1901200] ; National Natural Science Foundation of China[51606202] ; National Natural Science Foundation of China[51806226] ; Natural Science Foundation of Guangdong Province, China[2018A030313856] ; Science and Technology Planning Project of Guangdong Province[2013B090800026] ; Frontier Key Projects of Chinese Academy of Sciences[QYZDY-SSW-JSC038]
WOS Research AreaBiotechnology & Applied Microbiology ; Chemistry ; Engineering
Funding OrganizationNational Key R&D Program of China ; National Natural Science Foundation of China ; Natural Science Foundation of Guangdong Province, China ; Science and Technology Planning Project of Guangdong Province ; Frontier Key Projects of Chinese Academy of Sciences
WOS SubjectBiotechnology & Applied Microbiology ; Chemistry, Multidisciplinary ; Engineering, Environmental ; Engineering, Chemical
WOS IDWOS:000476140200001
PublisherWILEY
Citation statistics
Cited Times:26[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/25355
Collection中国科学院广州能源研究所
Corresponding AuthorYuan, Haoran
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou, Guangdong, Peoples R China
2.CAS Key Lab Renewable Energy, Guangzhou, Guangdong, Peoples R China
3.Guangdong Prov Key Lab New & Renewable EnergyRes, Guangzhou, Guangdong, Peoples R China
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Gu, Jing,Zhang, Jun,Li, Denian,et al. Hyper-cross-linked polymer based carbonaceous materials as efficient catalysts for ethyl levulinate production from carbohydrates[J]. JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY,2019:11.
APA Gu, Jing,Zhang, Jun,Li, Denian,Yuan, Haoran,&Chen, Yong.(2019).Hyper-cross-linked polymer based carbonaceous materials as efficient catalysts for ethyl levulinate production from carbohydrates.JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY,11.
MLA Gu, Jing,et al."Hyper-cross-linked polymer based carbonaceous materials as efficient catalysts for ethyl levulinate production from carbohydrates".JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY (2019):11.
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