Synthesis and Configurational Character Study of Novel Structural Isomers Based on Pyrene-Imidazole

doi:10.3390/molecules24122293

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	Synthesis and Configurational Character Study of Novel Structural Isomers Based on Pyrene-Imidazole
	Liu, Yu-Long 1,2; Yang, Liu 1; Guo, You-Quan 3; Xu, Guo-Qiang 1; Qu, Bin 1,2; Fu, Ying 1
	2019-06-02
发表期刊	MOLECULES
ISSN	1420-3049
卷号	24 期号:12 页码:11
通讯作者	Fu, Ying(fuying@neau.edu.cn)
摘要	Isomers provide more possibilities for the structure of organic compounds. Molecular structures determine their corresponding properties, therefore the intrinsic relationship between structure and properties of isomers is of great research value. Isomers with a stable structure and excellent performance possess more potential for development and application. In this paper, we design and synthesize structural isomers with different molecular symmetries based on the asymmetric structure of imidazole and the symmetrical structure of pyrene. Isomers with stable molecular structures can be obtained by a simple and efficient one-pot reaction, involving axisymmetric configuration and centrosymmetric configuration. Using this click-like reaction, the structure of target molecules is controllable and adjustable. Furthermore, the effect of molecular configurations on molecular stacking of crystal is studied. The variation of the optical and thermal properties, the optimized structures, and orbital distributions of isomers depends on different molecular geometry with different symmetry, which are revealed by crystallographic analysis. This present strategy provides an efficient synthetic method for the design and synthesis of structural isomers based on pyrene-imidazole.
关键词	one-pot reaction pyrene-imidazole structural isomer molecular symmetry crystal structure
DOI	10.3390/molecules24122293
关键词[WOS]	ISOMERICALLY PURE ; HIGHLY EFFICIENT ; DEEP-BLUE ; FLUORESCENCE ; PERFORMANCE ; DERIVATIVES ; CRYSTAL ; PACKING ; CONFORMATION
收录类别	SCI
语种	英语
资助项目	Natural Science Foundation of Heilongjiang Province[LH2019B002] ; Postdoctoral Science Foundation of Heilongjiang Province[LBH-Z17014] ; CAS Key Laboratory of Renewable Energy[Y907k71001]
WOS研究方向	Biochemistry & Molecular Biology ; Chemistry
项目资助者	Natural Science Foundation of Heilongjiang Province ; Postdoctoral Science Foundation of Heilongjiang Province ; CAS Key Laboratory of Renewable Energy
WOS类目	Biochemistry & Molecular Biology ; Chemistry, Multidisciplinary
WOS记录号	WOS:000473816900099
出版者	MDPI
引用统计	被引频次：4[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/25279
专题	中国科学院广州能源研究所
通讯作者	Fu, Ying
作者单位	1.Northeast Agr Univ, Coll Sci, Dept Appl Chem, Harbin 150030, Heilongjiang, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Heilongjiang Vocat Coll Biol Sci & Technol, Harbin 150025, Heilongjiang, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Liu, Yu-Long,Yang, Liu,Guo, You-Quan,et al. Synthesis and Configurational Character Study of Novel Structural Isomers Based on Pyrene-Imidazole[J]. MOLECULES,2019,24(12):11.
APA	Liu, Yu-Long,Yang, Liu,Guo, You-Quan,Xu, Guo-Qiang,Qu, Bin,&Fu, Ying.(2019).Synthesis and Configurational Character Study of Novel Structural Isomers Based on Pyrene-Imidazole.MOLECULES,24(12),11.
MLA	Liu, Yu-Long,et al."Synthesis and Configurational Character Study of Novel Structural Isomers Based on Pyrene-Imidazole".MOLECULES 24.12(2019):11.