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A review on evolution of nitrogen-containing species during selective pyrolysis of waste wood-based panels
Zhan, Hao1,2,5; Zhuang, Xiuzheng3,5; Song, Yanpei3,5; Liu, Jianguo3; Li, Sheng1,2,5; Chang, Guozhang4; Yin, Xiuli3; Wu, Chuangzhi3,5; Wang, Xinming1,2,5
2019-10-01
Source PublicationFUEL
ISSN0016-2361
Volume253Pages:1214-1228
Corresponding AuthorZhan, Hao(zhanhao@ms.giec.ac.cn)
AbstractWaste wood-based panels (WWPs) are typical industrial biowastes with a huge annual production in the world, especially in China, which can be potentially utilized via selective pyrolysis. For a better understanding of clean and efficient resource utilization of WWPs, this study comprehensively provides a state-of-the-art overview of their selective pyrolysis in terms of pyrolysis mechanisms, formation characteristics and properties of pyrolysis products. It was noted that WWPs displayed a dual characteristic of excellent fuel quality and high fuel-N content due to co-existence of abundant lignocellulosic components and adhesives (referring to urea-formaldehyde resin, UFR). Pyrolysis of WWPs was intrinsically regarded as the interactions between lignocellulosic components and UFR under oxygen-free thermal conditions, leading to distinctive properties of pyrolysis products, especially referring to N-containing species. For pyrolytic gas, they were environmentally harmful but formed selectively to pyrolysis temperature. Subsequently, thermal pre-treatment at low temperatures was capable to favor their clean thermal utilization by reducing or regulating original fuel-N in WWPs. On the contrary, N-containing species in bio-oil and activated carbon were both economically valuable. Specifically, nitrogen compounds in bio-oil could manifest its excellent anti-bacterial/fungicidal and high value-added properties; nitrogen functionalities in activated carbon could guarantee its better adsorption capability and electrochemical performance. Hence, based on a new concept of role change of fuel-N from harmful to valuable species, by promoting its preferential conversion into solid/liquid phases, poly-generation of N-poor pyrolytic gas, N-enriched bio-oil and N-doped activated carbon from selective pyrolysis would be a promising technique for clean and efficient utilization of WWPs.
KeywordWaste wood-based panels N-containing species Pyrolytic gas Bio-oil Activated carbon Selective pyrolysis
DOI10.1016/j.fuel.2019.05.122
WOS KeywordMEDIUM-DENSITY FIBERBOARD ; UREA-FORMALDEHYDE RESIN ; ENRICHED ACTIVATED CARBON ; LOW-TEMPERATURE PYROLYSIS ; DOPED POROUS CARBON ; PARTICLE BOARD ; MELAMINE-FORMALDEHYDE ; CATALYTIC CONVERSION ; THERMAL-DECOMPOSITION ; BIOMASS PYROLYSIS
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[41530641] ; National Natural Science Foundation of China[51676195] ; Special Program for Key Basic Research of the Natural Science Foundation of Guangdong Province[2017B030308002] ; Postdoctoral Science Foundation of China[2018M643221]
WOS Research AreaEnergy & Fuels ; Engineering
Funding OrganizationNational Natural Science Foundation of China ; Special Program for Key Basic Research of the Natural Science Foundation of Guangdong Province ; Postdoctoral Science Foundation of China
WOS SubjectEnergy & Fuels ; Engineering, Chemical
WOS IDWOS:000471841600118
PublisherELSEVIER SCI LTD
Citation statistics
Cited Times:46[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/25270
Collection中国科学院广州能源研究所
Corresponding AuthorZhan, Hao
Affiliation1.Chinese Acad Sci, State Key Lab Organ Geochem, Guangzhou Inst Geochem, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Guangdong Key Lab Environm Protect & Resources Ut, Guangzhou Inst Geochem, Guangzhou 510640, Guangdong, Peoples R China
3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
4.Qingdao Univ Sci & Technol, State Key Lab Base Ecochem Engn, Coll Chem Engn, Qingdao 266042, Shandong, Peoples R China
5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhan, Hao,Zhuang, Xiuzheng,Song, Yanpei,et al. A review on evolution of nitrogen-containing species during selective pyrolysis of waste wood-based panels[J]. FUEL,2019,253:1214-1228.
APA Zhan, Hao.,Zhuang, Xiuzheng.,Song, Yanpei.,Liu, Jianguo.,Li, Sheng.,...&Wang, Xinming.(2019).A review on evolution of nitrogen-containing species during selective pyrolysis of waste wood-based panels.FUEL,253,1214-1228.
MLA Zhan, Hao,et al."A review on evolution of nitrogen-containing species during selective pyrolysis of waste wood-based panels".FUEL 253(2019):1214-1228.
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