Selective Conversion of Cellulose to Hydroxyacetone and 1-Hydroxy-2-Butanone with Sn-Ni Bimetallic Catalysts

doi:10.1002/cssc.201900172

GIEC OpenIR

	Selective Conversion of Cellulose to Hydroxyacetone and 1-Hydroxy-2-Butanone with Sn-Ni Bimetallic Catalysts
	Wang, Haiyong 1,2,3,4; Zhu, Changhui 1,2,3,4; Liu, Qiying1,2,3,5 ; Tan, Jin 1,2,3; Wang, Chenguang 1,2,3; Liang, Zheng 1,2,3; Ma, Longlong1,2,3
	2019-05-21
发表期刊	CHEMSUSCHEM
ISSN	1864-5631
卷号	12 期号:10 页码:2154-2160
通讯作者	Liu, Qiying(liuqy@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn)
摘要	The high-value-added chemicals hydroxyacetone (HA) and 1-hydroxy-2-butanone (HB) were produced from agricultural waste over a Ni3Sn4-SnOx catalyst. The Sn-Ni intermetallic compound and SnOx acted as the active sites for HA and HB production by selectively cleaving the target C-C and C-O bonds. Approximately 70% of the total HA and HB yield was obtained by selective hydrogenolysis of cellulose. This strategy expands the application of cellulose towards renewable production of high-value C-3 and C-4 keto-alcohols from cellulosic biomass.
关键词	biomass cellulose hydroxyacetone intermetallic keto-alcohols
DOI	10.1002/cssc.201900172
关键词[WOS]	ETHYLENE-GLYCOL ; PLATFORM MOLECULES ; AEROBIC OXIDATION ; BIOMASS ; CHEMICALS ; GLYCEROL ; POLYOLS ; HYDROGENOLYSIS ; EFFICIENT ; SORBITOL
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51576199] ; National Natural Science Foundation of China[51536009] ; DNL Cooperation Fund, CAS[DNL180302] ; Natural Science Foundation of Guangdong Province[2017A030308010] ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N092]
WOS研究方向	Chemistry ; Science & Technology - Other Topics
项目资助者	National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; Natural Science Foundation of Guangdong Province ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program
WOS类目	Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology
WOS记录号	WOS:000472806800008
出版者	WILEY-V C H VERLAG GMBH
引用统计	被引频次：33[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/25264
专题	中国科学院广州能源研究所
通讯作者	Liu, Qiying; Ma, Longlong
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 5.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Wang, Haiyong,Zhu, Changhui,Liu, Qiying,et al. Selective Conversion of Cellulose to Hydroxyacetone and 1-Hydroxy-2-Butanone with Sn-Ni Bimetallic Catalysts[J]. CHEMSUSCHEM,2019,12(10):2154-2160.
APA	Wang, Haiyong.,Zhu, Changhui.,Liu, Qiying.,Tan, Jin.,Wang, Chenguang.,...&Ma, Longlong.(2019).Selective Conversion of Cellulose to Hydroxyacetone and 1-Hydroxy-2-Butanone with Sn-Ni Bimetallic Catalysts.CHEMSUSCHEM,12(10),2154-2160.
MLA	Wang, Haiyong,et al."Selective Conversion of Cellulose to Hydroxyacetone and 1-Hydroxy-2-Butanone with Sn-Ni Bimetallic Catalysts".CHEMSUSCHEM 12.10(2019):2154-2160.