Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Water sorption properties of functionalized MIL-101(Cr)-X (X = -NH2, -SO3H, H, -CH3, -F) based composites as thermochemical heat storage materials | |
Shi, Weina1,2; Zhu, Yanqing2; Shen, Cong2; Shi, Jifu3; Xu, Gang2; Xiao, Xiudi2; Cao, Runqiang4 | |
2019-09-01 | |
发表期刊 | MICROPOROUS AND MESOPOROUS MATERIALS |
ISSN | 1387-1811 |
卷号 | 285页码:129-136 |
通讯作者 | Zhu, Yanqing(zhuyq@ms.giec.ac.cn) ; Xu, Gang() ; Xiao, Xiudi() |
摘要 | Thermochemical heat storage based on inorganic salt hydrates is a promising approach to relieve the heat energy supply and demand conflicts, but there exist lots of defects of pure salts when applied to the thermochemical. This paper attempted to use functionalized Metal-Organic Frameworks (MOFs) as the porous matrices to improve the heat storage performance of inorganic salt hydrates. A series of MOFs/CaCl2 composites based on MIL-101(Cr)-X (X = -NH2, -SO3H, H, -CH3, -F) were successfully synthesized and fully characterized by combining multiple techniques (i.e. powder X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray analysis, N-2 adsorption-desorption, Fourier transform infrared spectroscopy, thermogravimetric and differential scanning calorimetry). The water sorption properties of the series of MOFs/CaCl2 composites were studied during the hydration process, and a continuous adsorption/desorption experiment was also performed to investigate the cycle stability of the MOFs/CaCl2 composites. The results show that the hydrophilic MOFs based composites have higher water sorption capacity (0.6 g(H2O)/g(sample) for MIL-101(Cr)-SO3H/CaCl2) accompanied with higher heat storage density (1274 J/g for MIL-101(Cr)-SO3H/CaCl2). Moreover, the series of MOFs all presented excellent cycle performance with little loss after continuous 17 adsorption/desorption cycles. |
关键词 | Thermochemical energy storage Metal-organic frameworks MIL-101(Cr) Framework functionalization Calcium chloride |
DOI | 10.1016/j.micromeso.2019.05.003 |
关键词[WOS] | THERMAL-ENERGY STORAGE ; METAL-ORGANIC FRAMEWORKS ; PHASE-CHANGE ; SILICA-GEL ; DENSITY ; CACL2 ; TRANSFORMATION ; NANOPARTICLES ; PERFORMANCE ; STABILITY |
收录类别 | SCI |
语种 | 英语 |
资助项目 | National Key R&D Program of China[2018YFD0700200] ; Project of Science and Technology Service Network initiative, Chinese Academy of Sciences[KFJ-STS-QYZD-004] ; Major Science and Technology Project of Tibet Autonomous Region[ZD20170017] ; Youth Innovation Promotion Association CAS[2017400] ; Special Plan of Guangdong Province[2015TQ01N714] ; Natural Science Foundation of Guangdong Province[2018A0303130146] ; Project of Science and Technology of Guangzhou |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
项目资助者 | National Key R&D Program of China ; Project of Science and Technology Service Network initiative, Chinese Academy of Sciences ; Major Science and Technology Project of Tibet Autonomous Region ; Youth Innovation Promotion Association CAS ; Special Plan of Guangdong Province ; Natural Science Foundation of Guangdong Province ; Project of Science and Technology of Guangzhou |
WOS类目 | Chemistry, Applied ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
WOS记录号 | WOS:000471081000015 |
出版者 | ELSEVIER SCIENCE BV |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/25258 |
专题 | 中国科学院广州能源研究所 |
通讯作者 | Zhu, Yanqing; Xu, Gang; Xiao, Xiudi |
作者单位 | 1.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 230027, Anhui, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China 3.Jinan Univ, Dept Phys, Siyuan Lab, Guangzhou 510632, Guangdong, Peoples R China 4.Panzhihua Univ, Panzhihua 617000, Peoples R China |
第一作者单位 | 中国科学院广州能源研究所 |
推荐引用方式 GB/T 7714 | Shi, Weina,Zhu, Yanqing,Shen, Cong,et al. Water sorption properties of functionalized MIL-101(Cr)-X (X = -NH2, -SO3H, H, -CH3, -F) based composites as thermochemical heat storage materials[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2019,285:129-136. |
APA | Shi, Weina.,Zhu, Yanqing.,Shen, Cong.,Shi, Jifu.,Xu, Gang.,...&Cao, Runqiang.(2019).Water sorption properties of functionalized MIL-101(Cr)-X (X = -NH2, -SO3H, H, -CH3, -F) based composites as thermochemical heat storage materials.MICROPOROUS AND MESOPOROUS MATERIALS,285,129-136. |
MLA | Shi, Weina,et al."Water sorption properties of functionalized MIL-101(Cr)-X (X = -NH2, -SO3H, H, -CH3, -F) based composites as thermochemical heat storage materials".MICROPOROUS AND MESOPOROUS MATERIALS 285(2019):129-136. |
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