Selective hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over Co3O4 catalyst by controlled reduction

doi:10.1016/j.jechem.2018.03.008

GIEC OpenIR

	Selective hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over Co3O4 catalyst by controlled reduction
	Li, Dan 2,4; Liu, Qiying1,4 ; Zhu, Changhui 1,3,4; Wang, Haiyong 1,3,4; Cui, Chunhua 1,4; Wang, Chenguang 1,4; Ma, Longlong1,4
	2019-03-01
发表期刊	JOURNAL OF ENERGY CHEMISTRY
ISSN	2095-4956
卷号	30 页码:34-41
通讯作者	Liu, Qiying(liuqy@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn)
摘要	2,5-dimethyfuran (DMF), which is produced from 5-hydroxymethyfurfural (HMF) by hydrodeoxygenation (HDO), is a high quality fuel due to the high heating value, the high octane number and the suitable boiling point. Selective hydrogenation of HMF into liquid fuel DMF has been widely researched. In this paper, Co3O4 catalyst was prepared by co-precipitation and was reduced at different temperatures to form Co-CoOx catalysts. The characterization of catalysts was tested by XRD, TEM, XPS, TPR, BET and NH3-TPD. Co-CoOx possessed a high amount of Co metal and CoOx acidic sites, wherein Co worked as the active hydrogenation sites and CoOx acted as the acid promoter to facilitate the selective HDO of HMF to DMF. The synergistic effect of Co-CoOx is the key for HDO of HMF, obtaining 83.3% of DMF yield at 170 degrees C, 12 h and the reduction temperature of 400 degrees C. This method not only saves the catalyst cost, but also promotes the utilization of biomass energy. (C) 2018 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
关键词	HMF DMF Co3O4 catalyst Hydrogenolysis
DOI	10.1016/j.jechem.2018.03.008
关键词[WOS]	HIGH-YIELD PRODUCTION ; BIOMASS ; CONVERSION ; FUELS ; HYDRODEOXYGENATION ; TEMPERATURE ; OXIDATION ; FURAN ; TRANSFORMATION ; HYDROGENATION
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51576199] ; National Natural Science Foundation of China[51536009] ; Natural Science Fund of Guangdong Province[2017A030308010]
WOS研究方向	Chemistry ; Energy & Fuels ; Engineering
项目资助者	National Natural Science Foundation of China ; Natural Science Fund of Guangdong Province
WOS类目	Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
WOS记录号	WOS:000457878900005
出版者	ELSEVIER SCIENCE BV
引用统计	被引频次：66[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/25058
专题	中国科学院广州能源研究所
通讯作者	Liu, Qiying; Ma, Longlong
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Jiangsu, Peoples R China 3.Univ Chinese Acad Sci, Beijing 101407, Peoples R China 4.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510000, Guangdong, Peoples R China
推荐引用方式 GB/T 7714	Li, Dan,Liu, Qiying,Zhu, Changhui,et al. Selective hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over Co3O4 catalyst by controlled reduction[J]. JOURNAL OF ENERGY CHEMISTRY,2019,30:34-41.
APA	Li, Dan.,Liu, Qiying.,Zhu, Changhui.,Wang, Haiyong.,Cui, Chunhua.,...&Ma, Longlong.(2019).Selective hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over Co3O4 catalyst by controlled reduction.JOURNAL OF ENERGY CHEMISTRY,30,34-41.
MLA	Li, Dan,et al."Selective hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over Co3O4 catalyst by controlled reduction".JOURNAL OF ENERGY CHEMISTRY 30(2019):34-41.