Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Facile assembly of cellulose-derived 3D-graphene/lithium hydroxide monohydrate nanocomposite for low-temperature chemical heat storage | |
Yang, Xixian1; Li, Shijie3,4; Zhang, Shiyi5; Chen, Xin1; Peng, Shuai2 | |
2019-05-01 | |
发表期刊 | CELLULOSE |
ISSN | 0969-0239 |
卷号 | 26期号:8页码:4815-4825 |
通讯作者 | Yang, Xixian(yangxixian@yeah.net) ; Chen, Xin(451807924@qq.com) ; Peng, Shuai(gwzps211@126.com) |
摘要 | Commonly used nanocarbon composite materials are routinely synthesized from petroleum-based resources. To avoid their bad impact on the environment, using cellulose-based materials as the promising resources is a better choice due to its easy acquisition and rich reserves. In this study, microcrystalline cellulose was selected as the carbon precursor to synthesize novel cellulose-derived 3D-graphene/LiOHH2O nanomaterials for chemical heat storage to improve the efficiency of thermal energy utilization. The characterization and performance test results show that LiOHH2O particles (5-20nm) were highly dispersed on the 3D graphene carbon skeleton. These materials had excellent heat storage densities and thermal conductivities due to a completely new, hydrophilic, nano-reactive interface on 3D graphene. Among the materials, 3D-GF-VC-LiOHH2O (Ascorbic acid-modified 3D-graphene/LiOHH2O) exhibited the best heat storage and thermal conductivity properties. It achieved a thermal conductivity of 2.6W/mK, which was 1.5 times that obtained with pure LiOHH2O, and its heat storage density (2157kJ/kg) was 3.3 times that of pure LiOHH2O (661kJ/kg). The activation energy could decrease to 27.5kJ/mol. Moreover, the heat storage temperature range of LiOHH2O was clearly expanded by introduction of 3D graphene. Hence, the addition of cellulose-derived 3D graphene is a very efficient means by which the design of chemical heat storage materials can be improved. [GRAPHICS] . |
关键词 | Cellulose 3D graphene Chemical heat storage Lithium hydroxide monohydrate Nanoparticles |
DOI | 10.1007/s10570-019-02409-w |
关键词[WOS] | PHASE-CHANGE MATERIALS ; CARBON NANOTUBES ; THERMAL-CONDUCTIVITY ; PROMISING CANDIDATE ; ACTIVATION-ENERGY ; LITHIUM HYDROXIDE ; NANOCELLULOSE ; COMPOSITES ; DENSITY ; DECOMPOSITION |
收录类别 | SCI |
语种 | 英语 |
资助项目 | National Science Foundation of China[51406209] ; Research Foundation of Education Bureau of Hubei Province, China[B2017067] |
WOS研究方向 | Materials Science ; Polymer Science |
项目资助者 | National Science Foundation of China ; Research Foundation of Education Bureau of Hubei Province, China |
WOS类目 | Materials Science, Paper & Wood ; Materials Science, Textiles ; Polymer Science |
WOS记录号 | WOS:000467057500011 |
出版者 | SPRINGER |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/24958 |
专题 | 中国科学院广州能源研究所 |
通讯作者 | Yang, Xixian; Chen, Xin; Peng, Shuai |
作者单位 | 1.Foshan Univ, Sch Environm & Chem Engn, Foshan 528000, Peoples R China 2.Wuhan Text Univ, Hubei Prov Engn Lab Clean Prod & High Value Utili, Wuhan 430073, Hubei, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Chinese Acad Sci, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 5.South China Univ Technol, Sch Chem & Chem Engn, Key Lab Fuel Cell Technol Guangdong Prov, Guangzhou 510640, Guangdong, Peoples R China |
推荐引用方式 GB/T 7714 | Yang, Xixian,Li, Shijie,Zhang, Shiyi,et al. Facile assembly of cellulose-derived 3D-graphene/lithium hydroxide monohydrate nanocomposite for low-temperature chemical heat storage[J]. CELLULOSE,2019,26(8):4815-4825. |
APA | Yang, Xixian,Li, Shijie,Zhang, Shiyi,Chen, Xin,&Peng, Shuai.(2019).Facile assembly of cellulose-derived 3D-graphene/lithium hydroxide monohydrate nanocomposite for low-temperature chemical heat storage.CELLULOSE,26(8),4815-4825. |
MLA | Yang, Xixian,et al."Facile assembly of cellulose-derived 3D-graphene/lithium hydroxide monohydrate nanocomposite for low-temperature chemical heat storage".CELLULOSE 26.8(2019):4815-4825. |
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