The Effect of Different Mixed Organic Solvents on the Properties of p(OPal-MMA) Gel Electrolyte Membrane for Lithium Ion Batteries

doi:10.3390/app8122587

GIEC OpenIR

	The Effect of Different Mixed Organic Solvents on the Properties of p(OPal-MMA) Gel Electrolyte Membrane for Lithium Ion Batteries
	Tian, Lanlan 1,2; Wang, Mengkun 1,3,4,5; Xiong, Lian1,3,4,5 ; Guo, Haijun 1,3,4,5; Huang, Chao 1,3,4,5; Zhang, Hairong 1,3,4,5; Chen, Xinde1,3,4,5
	2018-12-01
发表期刊	APPLIED SCIENCES-BASEL
ISSN	2076-3417
卷号	8 期号:12 页码:11
通讯作者	Zhang, Hairong(hairongz@gmail.com) ; Chen, Xinde(cxd_cxd@hotmail.com)
摘要	A solvent is a key factor during polymer membrane preparation, and it is directly related to application performance as a separator for lithium ion battery (LIB). In this study, different mixed solvents were employed to prepare polymer (p(OPal-MMA)) membranes by the phase inversion technique. The polymer membrane then absorbed liquid electrolytes to obtain gel electrolytes (GPEs). The surface morphologies and porosities of these membranes were investigated, and lithium ion transferences and electrochemical performances of these GPEs were also measured. The membrane displayed an interconnected three-dimensional framework structure with uniformly distributed pores when using DMF as a porogen. When combined with acetone as the component solvent, the prepared GPE displayed the largest lithium ion transference number (0.706), the highest porosity (42.6%) and ion conductivity (3.99 x 10(-3) S/cm). Even when assembled as Li/GPE/LiFePO4 cell, it exhibited the highest initial specific capacity of 167mAh/g and retained most capacity (162mAh/g) after 50 cycles. The results presented here probably provide reference for choosing an appropriate mixed solvent in fabricating polymer membranes.
关键词	lithium ion battery phase inversion mixed solvent gel polymer electrolyte
DOI	10.3390/app8122587
关键词[WOS]	SOLID POLYMER ELECTROLYTE ; CONDUCTIVITY ; PERFORMANCE ; DISPLAYS ; PMMA ; COPOLYMER ; VOLTAGE
收录类别	SCI
语种	英语
资助项目	Project of Jiangsu Province Science and Technology[BE2016125] ; tender project of HuaiAn[HAZC2018010036] ; Open Foundation of Xuyi Center of Attapulgite Applied Technology Research Development & Industrialization, Chinese Academy of Sciences[201604]
WOS研究方向	Chemistry ; Materials Science ; Physics
项目资助者	Project of Jiangsu Province Science and Technology ; tender project of HuaiAn ; Open Foundation of Xuyi Center of Attapulgite Applied Technology Research Development & Industrialization, Chinese Academy of Sciences
WOS类目	Chemistry, Multidisciplinary ; Materials Science, Multidisciplinary ; Physics, Applied
WOS记录号	WOS:000455145000255
出版者	MDPI
引用统计	被引频次：6[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/24632
专题	中国科学院广州能源研究所
通讯作者	Zhang, Hairong; Chen, Xinde
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 4.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China 5.Chinese Acad Sci, Guangzhou Inst Energy Convers, R&D Ctr Xuyi Attapulgite Appl Technol, Xuyi 211700, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Tian, Lanlan,Wang, Mengkun,Xiong, Lian,et al. The Effect of Different Mixed Organic Solvents on the Properties of p(OPal-MMA) Gel Electrolyte Membrane for Lithium Ion Batteries[J]. APPLIED SCIENCES-BASEL,2018,8(12):11.
APA	Tian, Lanlan.,Wang, Mengkun.,Xiong, Lian.,Guo, Haijun.,Huang, Chao.,...&Chen, Xinde.(2018).The Effect of Different Mixed Organic Solvents on the Properties of p(OPal-MMA) Gel Electrolyte Membrane for Lithium Ion Batteries.APPLIED SCIENCES-BASEL,8(12),11.
MLA	Tian, Lanlan,et al."The Effect of Different Mixed Organic Solvents on the Properties of p(OPal-MMA) Gel Electrolyte Membrane for Lithium Ion Batteries".APPLIED SCIENCES-BASEL 8.12(2018):11.