Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Hydrodeoxygenation of Sorbitol into Bio-Alkanes and -Alcohols Over Phosphated Ruthenium Molybdenum Catalysts | |
Weng, Yujing1,2; Wang, Tiejun2 ; Wang, Chenguang2; Liu, Qiying2; Zhang, Yulong1; Duan, Peigao1; Wang, Longlong1; Yin, Hongxing1; Liu, Shijun2; Ma, Longlong2
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| 2018-11-07 | |
| Source Publication | CHEMCATCHEM
 |
| ISSN | 1867-3880 |
| Volume | 10Issue:21Pages:5046-5052 |
| Corresponding Author | Weng, Yujing(wyj162@mail.ustc.edu.cn) |
| Abstract | Biofuels such as renewable alkanes and higher alcohols have drawn considerable interests for the use in internal combustion engines. Especially, higher alcohols could be used as a blending agent for diesel fuels. Herein, carbon supported phosphated ruthenium-molybdenum (RuMoP) catalysts were employed in continuous trickle-bed reactor for converting sorbitol into renewable alkanes and higher alcohols. The results showed that RuMoP on an active carbon (AC) support presented a complete sorbitol conversion and high yields of alkanes and alcohols in gasoline and diesel range. Subsequently, carbon nanotube (CNT) supported RuMoP was prepared and studied in detail for comparison. RuMoP/CNT presented a low C-C bond cracking property in sorbitol conversion and high selectivity of C6 products in gas-phase (C6 alkane, 74.7 %) and oil-phase (C6 alkane and alcohols, 87.8 %). Finally, detailed characterizations (N-2-adsorption, XRD, HRTEM, XPS, NH3-TPD, Py-IR spectrums, etc.) were performed over relevant catalysts (RuMoP/C and RuMoP/CNT) for correlating their catalytic and physicochemical properties. |
| Keyword | Biomass conversion Higher alcohols Hydrodeoxygenation Bimetallic Alkanes |
| DOI | 10.1002/cctc.201801214 |
| WOS Keyword | AQUEOUS-PHASE HYDRODEOXYGENATION ; SOLVOLYSED LIGNOCELLULOSIC BIOMASS ; SELECTIVE HYDROGENATION ; CARBIDE CATALYSTS ; CONVERSION ; CARBON ; RU ; NANOPARTICLES ; EFFICIENT ; CELLULOSE |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | Scientific and Technological Research Projects of Henan Province[182102210319] ; Henan Polytechnic University[B2018-42] ; Outstanding Youth Foundation for Scientific and Technological Innovation in Henan Province[184100510013] ; National Natural Science Foundation of China[51536009] ; National key research plan[2018YFB0604500] ; Chinese Academy of Sciences one hundred talented plans |
| WOS Research Area | Chemistry |
| Funding Organization | Scientific and Technological Research Projects of Henan Province ; Henan Polytechnic University ; Outstanding Youth Foundation for Scientific and Technological Innovation in Henan Province ; National Natural Science Foundation of China ; National key research plan ; Chinese Academy of Sciences one hundred talented plans |
| WOS Subject | Chemistry, Physical |
| WOS ID | WOS:000449951500034 |
| Publisher | WILEY-V C H VERLAG GMBH |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/24233 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Weng, Yujing |
| Affiliation | 1.Henan Polytech Univ, Henan Key Lab Coal Green Convers, Jiaozuo 454003, Henan, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Weng, Yujing,Wang, Tiejun,Wang, Chenguang,et al. Hydrodeoxygenation of Sorbitol into Bio-Alkanes and -Alcohols Over Phosphated Ruthenium Molybdenum Catalysts[J]. CHEMCATCHEM,2018,10(21):5046-5052. |
| APA | Weng, Yujing.,Wang, Tiejun.,Wang, Chenguang.,Liu, Qiying.,Zhang, Yulong.,...&Ma, Longlong.(2018).Hydrodeoxygenation of Sorbitol into Bio-Alkanes and -Alcohols Over Phosphated Ruthenium Molybdenum Catalysts.CHEMCATCHEM,10(21),5046-5052. |
| MLA | Weng, Yujing,et al."Hydrodeoxygenation of Sorbitol into Bio-Alkanes and -Alcohols Over Phosphated Ruthenium Molybdenum Catalysts".CHEMCATCHEM 10.21(2018):5046-5052. |
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