Hydrodeoxygenation of Sorbitol into Bio-Alkanes and -Alcohols Over Phosphated Ruthenium Molybdenum Catalysts

doi:10.1002/cctc.201801214

GIEC OpenIR

	Hydrodeoxygenation of Sorbitol into Bio-Alkanes and -Alcohols Over Phosphated Ruthenium Molybdenum Catalysts
	Weng, Yujing 1,2; Wang, Tiejun2 ; Wang, Chenguang 2; Liu, Qiying2 ; Zhang, Yulong 1; Duan, Peigao 1; Wang, Longlong 1; Yin, Hongxing 1; Liu, Shijun 2; Ma, Longlong2
	2018-11-07
发表期刊	CHEMCATCHEM
ISSN	1867-3880
卷号	10 期号:21 页码:5046-5052
通讯作者	Weng, Yujing(wyj162@mail.ustc.edu.cn)
摘要	Biofuels such as renewable alkanes and higher alcohols have drawn considerable interests for the use in internal combustion engines. Especially, higher alcohols could be used as a blending agent for diesel fuels. Herein, carbon supported phosphated ruthenium-molybdenum (RuMoP) catalysts were employed in continuous trickle-bed reactor for converting sorbitol into renewable alkanes and higher alcohols. The results showed that RuMoP on an active carbon (AC) support presented a complete sorbitol conversion and high yields of alkanes and alcohols in gasoline and diesel range. Subsequently, carbon nanotube (CNT) supported RuMoP was prepared and studied in detail for comparison. RuMoP/CNT presented a low C-C bond cracking property in sorbitol conversion and high selectivity of C6 products in gas-phase (C6 alkane, 74.7 %) and oil-phase (C6 alkane and alcohols, 87.8 %). Finally, detailed characterizations (N-2-adsorption, XRD, HRTEM, XPS, NH3-TPD, Py-IR spectrums, etc.) were performed over relevant catalysts (RuMoP/C and RuMoP/CNT) for correlating their catalytic and physicochemical properties.
关键词	Biomass conversion Higher alcohols Hydrodeoxygenation Bimetallic Alkanes
DOI	10.1002/cctc.201801214
关键词[WOS]	AQUEOUS-PHASE HYDRODEOXYGENATION ; SOLVOLYSED LIGNOCELLULOSIC BIOMASS ; SELECTIVE HYDROGENATION ; CARBIDE CATALYSTS ; CONVERSION ; CARBON ; RU ; NANOPARTICLES ; EFFICIENT ; CELLULOSE
收录类别	SCI
语种	英语
资助项目	Scientific and Technological Research Projects of Henan Province[182102210319] ; Henan Polytechnic University[B2018-42] ; Outstanding Youth Foundation for Scientific and Technological Innovation in Henan Province[184100510013] ; National Natural Science Foundation of China[51536009] ; National key research plan[2018YFB0604500] ; Chinese Academy of Sciences one hundred talented plans
WOS研究方向	Chemistry
项目资助者	Scientific and Technological Research Projects of Henan Province ; Henan Polytechnic University ; Outstanding Youth Foundation for Scientific and Technological Innovation in Henan Province ; National Natural Science Foundation of China ; National key research plan ; Chinese Academy of Sciences one hundred talented plans
WOS类目	Chemistry, Physical
WOS记录号	WOS:000449951500034
出版者	WILEY-V C H VERLAG GMBH
引用统计	被引频次：13[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/24233
专题	中国科学院广州能源研究所
通讯作者	Weng, Yujing
作者单位	1.Henan Polytech Univ, Henan Key Lab Coal Green Convers, Jiaozuo 454003, Henan, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Weng, Yujing,Wang, Tiejun,Wang, Chenguang,et al. Hydrodeoxygenation of Sorbitol into Bio-Alkanes and -Alcohols Over Phosphated Ruthenium Molybdenum Catalysts[J]. CHEMCATCHEM,2018,10(21):5046-5052.
APA	Weng, Yujing.,Wang, Tiejun.,Wang, Chenguang.,Liu, Qiying.,Zhang, Yulong.,...&Ma, Longlong.(2018).Hydrodeoxygenation of Sorbitol into Bio-Alkanes and -Alcohols Over Phosphated Ruthenium Molybdenum Catalysts.CHEMCATCHEM,10(21),5046-5052.
MLA	Weng, Yujing,et al."Hydrodeoxygenation of Sorbitol into Bio-Alkanes and -Alcohols Over Phosphated Ruthenium Molybdenum Catalysts".CHEMCATCHEM 10.21(2018):5046-5052.