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Continuous Production of 5-Hydroxymethylfurfural from Monosaccharide over Zirconium Phosphates
Zhu, Changhui1,2,3,4; Cai, Chiliu1,2,3; Liu, Qiying1,2,3; Li, Wenzhi5; Tan, Jin1,2,3; Wang, Chenguang1,2,3; Chen, Lungang1,2,3; Zhang, Qi1,2,3; Ma, Longlong1,2,3
2018-10-24
发表期刊CHEMISTRYSELECT
ISSN2365-6549
卷号3期号:39页码:10983-10990
通讯作者Liu, Qiying(liuciy@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn)
摘要5-hydroxymethylfurfural (HMF), an important platform compound produced from lignocellulosic biomass, is widely applied in petrochemical industry for downstream synthesis of medical supplies or intermediate of the other important chemicals by the typical catalytic processes. A continuous production route was developed to yield HMF from monosaccharides by using zirconium phosphate (ZrP) with different Zr/P ratios as catalysts. Its physicochemical properties were then characterized by Brunauer-Emmett-Teller (BET), X-ray powder diffraction (XRD), X-ray photoelectron spectra (XPS), Fourier transform infrared spectroscopy (FT-IR), pyridine adsorbed Fourier transform infrared spectroscopy (Py-FT-IR), X-ray fluorescence (XRF) and temperature programmed desorption of ammonia (NH3-TPD) techniques. A mixed phase containing monosaccharide in aqueous and dimethyl sulfoxide (DMSO) phase was applied in the fixed bed to keep the continuous production. The optimized reaction conditions were applied to maximized HMF yield by varying the processing parameters. The highest HMF yield of 56.3% was obtained when using fructose as the feedstock under the reaction condition of 120 degrees C, 180min, N-2 pressure 2MPa and DMSO: fructose solution of 9:1 over ZrP with the P/Zr with molar ratio of 2. Comparatively, the glucose conversion of 72% with the HMF yield of 32% were gained under the same conditions using glucose as the feedstock. It is deduced that the ZrP catalysts simultaneously possessing Bronsted/Lewis acid showed synergy in glucose dehydration to HMF. The ZrP catalyst showed good stability and no obvious deactivation was observed after 30h of time-on-stream, due to the primary structure and acidic properties of catalyst can be kept during the reaction. Finally, it is generally efficient for some C-6 sugars dehydration to HMF with the Bronsted/Lewis acid synergy of ZrP.
关键词dehydration fixed bed 5-hydroxymethylfurfural monosaccharide zirconium phosphate
DOI10.1002/slct.201801880
关键词[WOS]IONIC LIQUID ; SOLID ACID ; D-FRUCTOSE ; HETEROGENEOUS ZIRCONIUM ; CONVERSION ; DEHYDRATION ; BIOMASS ; CATALYSTS ; GLUCOSE ; HMF
收录类别SCI
语种英语
资助项目National Science Foundation of China[51536009] ; National Science Foundation of China[51576199] ; Natural Science Foundation of Guangdong Province[2017 A030308010] ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01 N092]
WOS研究方向Chemistry
项目资助者National Science Foundation of China ; Natural Science Foundation of Guangdong Province ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000449032600023
出版者WILEY-V C H VERLAG GMBH
引用统计
被引频次:8[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/24159
专题中国科学院广州能源研究所
通讯作者Liu, Qiying; Ma, Longlong
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
5.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 230026, Anhui, Peoples R China
第一作者单位中国科学院广州能源研究所
推荐引用方式
GB/T 7714
Zhu, Changhui,Cai, Chiliu,Liu, Qiying,et al. Continuous Production of 5-Hydroxymethylfurfural from Monosaccharide over Zirconium Phosphates[J]. CHEMISTRYSELECT,2018,3(39):10983-10990.
APA Zhu, Changhui.,Cai, Chiliu.,Liu, Qiying.,Li, Wenzhi.,Tan, Jin.,...&Ma, Longlong.(2018).Continuous Production of 5-Hydroxymethylfurfural from Monosaccharide over Zirconium Phosphates.CHEMISTRYSELECT,3(39),10983-10990.
MLA Zhu, Changhui,et al."Continuous Production of 5-Hydroxymethylfurfural from Monosaccharide over Zirconium Phosphates".CHEMISTRYSELECT 3.39(2018):10983-10990.
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