Hydrodeoxygenation of lignin-derived phenolic compounds into aromatic hydrocarbons under low hydrogen pressure using molybdenum oxide as catalyst

doi:10.1016/j.cattod.2018.03.068

GIEC OpenIR

	Hydrodeoxygenation of lignin-derived phenolic compounds into aromatic hydrocarbons under low hydrogen pressure using molybdenum oxide as catalyst
	Zhang, Xinghua1,2,3 ; Tang, Jiejie 1; Zhang, Qi1,2,3 ; Liu, Qiying1,2,3 ; Li, Yuping1,2,3 ; Chen, Lungang 1,2,3; Wang, Chenguang 1,2,3; Ma, Longlong1,2,3
	2019
发表期刊	CATALYSIS TODAY
ISSN	0920-5861
卷号	319 页码:41-47
通讯作者	Zhang, Xinghua(zhangxh@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn)
摘要	MoO3 catalyst was prepared by calcination using (NH4)(6)Mo7O24 center dot 4H(2)O as precursor and was characterized by XRD, XPS, H-2-TPR and low temperature N-2 adsorption. Hydrodeoxygenation of phenol was conducted to investigate the catalytic performance of MoO3 catalyst at lower H-2 pressure. Effects of reaction temperature, reaction time and N-2 partial pressure on the phenol conversion and product distribution were tested carefully. MoO3 catalyst was found to preferentially produce arenes with high selectivity, while at lengthened reaction time cyclohexane selectivity was increased gradually. Oxygen vacancy site of MoO3 (Mo5+) was deemed to be the active center in the hydrodeoxygenation of phenol, which accounts for the cleavage of C-AR-OH to benzene. In addition, MoO3 catalyzed HDO reactions were further tested using different phenolic compounds as reactants. Experimental results suggest MoO3 catalyst can be widely applied in the conversion of diverse lignin-derived phenolic compounds conversion to aromatic hydrocarbons.
关键词	MoO3 Phenol Hydrodeoxygenation Vacancy sites Aromatic hydrocarbons
DOI	10.1016/j.cattod.2018.03.068
关键词[WOS]	NOBLE-METAL CATALYSTS ; MODEL COMPOUNDS ; BIO-OIL ; PYROLYSIS ; CHEMICALS ; MOO3 ; DEPOLYMERIZATION ; VALORIZATION ; FUELS ; DECOMPOSITION
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51576198] ; National Natural Science Foundation of China[51536009] ; Science and Technology Planning Project of Guangdong Province[2014A01016020] ; National Key Technology RD Program[2015BAD15B06] ; Youth Innovation Promotion Association CAS[2015288]
WOS研究方向	Chemistry ; Engineering
项目资助者	National Natural Science Foundation of China ; Science and Technology Planning Project of Guangdong Province ; National Key Technology RD Program ; Youth Innovation Promotion Association CAS
WOS类目	Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS记录号	WOS:000447156200006
出版者	ELSEVIER SCIENCE BV
引用统计	被引频次：56[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/24132
专题	中国科学院广州能源研究所
通讯作者	Zhang, Xinghua; Ma, Longlong
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Zhang, Xinghua,Tang, Jiejie,Zhang, Qi,et al. Hydrodeoxygenation of lignin-derived phenolic compounds into aromatic hydrocarbons under low hydrogen pressure using molybdenum oxide as catalyst[J]. CATALYSIS TODAY,2019,319:41-47.
APA	Zhang, Xinghua.,Tang, Jiejie.,Zhang, Qi.,Liu, Qiying.,Li, Yuping.,...&Ma, Longlong.(2019).Hydrodeoxygenation of lignin-derived phenolic compounds into aromatic hydrocarbons under low hydrogen pressure using molybdenum oxide as catalyst.CATALYSIS TODAY,319,41-47.
MLA	Zhang, Xinghua,et al."Hydrodeoxygenation of lignin-derived phenolic compounds into aromatic hydrocarbons under low hydrogen pressure using molybdenum oxide as catalyst".CATALYSIS TODAY 319(2019):41-47.