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Production of bio-jet fuel from corncob by hydrothermal decomposition and catalytic hydrogenation: Lab analysis of process and techno-economics of a pilot-scale facility
Li, Yuping1; Zhao, Cong; Chen, Lungang; Zhang, Xinghua; Zhang, Qi; Wang, Tiejun; Qiu, Songbai; Tan, Jin; Li, Kai; Wang, Chenguang; Ma, Longlong1
2018-10-01
Source PublicationAPPLIED ENERGY
ISSN0306-2619
Volume227Pages:128-136
Corresponding AuthorLi, Yuping(liyp@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn)
AbstractProcess design and techno-economic analysis of a pilot bio-jet fuel production facility were investigated using Aspen plus software and net present value method (NPV). This process include two-step hydrothermal decomposition of corncob to furfural (steam stripping of hemicellulose) and Levulinic acid (LA, acidic hydrolysis of cellulose), oxygenated precursor production via aldol condensation reaction of furfural and LA, and the subsequent hydro-processing for oxygen removal. Lab experiments on the major area of the process were carried out. The yields of furfural, LA, oxygenated precursor and bio-jet fuel-range hydrocarbons (C-8-C-15) were 59.5% (based on hemicellulose), 34.4% (based on cellulose), 75% (based on furfural and LA input) and 51 wt% (based on precursor) respectively. These values were used as the input information for the process simulation of a first-of-a-kind pilot facility for 1.3 ML/a bio-jet fuel production using this pioneering technology. The mass and energy analysis from Aspen plus model shows that the bio-jet fuel yield was 0.125 tonne/tonne dried corncob. 31.0% of carbon atoms and 47.6% of potential energy from carbohydrate compounds of corncob leave as bio-jet fuel. The estimated consumption of water, steam and electricity is relatively high of 12.3 kg, 63.7 kg and 1.22 KW h respectively due to small simulation scale and lack of process optimization. The total capital cost was ca. $3.96 MM for the 1.3 ML/a facility, of which 28% of equipment investment is spent for oxygenated precursor production. The total operation expense (OPEX) is $1.18/L bio-jet fuel, including variable and fixed costs. Expenses on corncob, catalytic catalyst and H-2 contribute 23%, 19% and 16% respectively. Single point sensitivity analysis of the major breakdown of OPEX shows that catalyst lifetime is the priority factor. Economy of scale of minimum selling price of bio-jet fuel (MSPB) for different capacity facilities (1.3 ML/a, 6.5 ML/a and 13 ML/a) was investigated using different discount and tax rates, of which the lowest MSPB was $0.74/L with a subsidy of $0.31/L at 10% discount rate.
KeywordCorncob hydrothermal decomposition Bio-jet fuel production Catalytic conversion Techno-economic analysis Pilot facility
DOI10.1016/j.apenergy.2017.07.133
WOS KeywordLEVULINIC ACID ; BIOMASS ; CONVERSION ; BIOFUELS ; LIGNOCELLULOSE ; HYDROLYSIS ; CHEMICALS ; ALKANES ; PHASE ; US
Indexed BySCI
Language英语
Funding ProjectNational Natural Research Foundation of China[51536009] ; National Natural Research Foundation of China[51276183] ; National Natural Research Foundation of China[51561145010] ; STS program of Chinese Academy of Sciences[KFJ-EW-STS-138]
WOS Research AreaEnergy & Fuels ; Engineering
Funding OrganizationNational Natural Research Foundation of China ; STS program of Chinese Academy of Sciences
WOS SubjectEnergy & Fuels ; Engineering, Chemical
WOS IDWOS:000445987200014
PublisherELSEVIER SCI LTD
Citation statistics
Cited Times:24[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/24004
Collection中国科学院广州能源研究所
Corresponding AuthorLi, Yuping; Ma, Longlong
Affiliation1.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
2.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China
Recommended Citation
GB/T 7714
Li, Yuping,Zhao, Cong,Chen, Lungang,et al. Production of bio-jet fuel from corncob by hydrothermal decomposition and catalytic hydrogenation: Lab analysis of process and techno-economics of a pilot-scale facility[J]. APPLIED ENERGY,2018,227:128-136.
APA Li, Yuping.,Zhao, Cong.,Chen, Lungang.,Zhang, Xinghua.,Zhang, Qi.,...&Ma, Longlong.(2018).Production of bio-jet fuel from corncob by hydrothermal decomposition and catalytic hydrogenation: Lab analysis of process and techno-economics of a pilot-scale facility.APPLIED ENERGY,227,128-136.
MLA Li, Yuping,et al."Production of bio-jet fuel from corncob by hydrothermal decomposition and catalytic hydrogenation: Lab analysis of process and techno-economics of a pilot-scale facility".APPLIED ENERGY 227(2018):128-136.
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